4-Bromochlorobenzene 4-溴氯苯

CAS 106-39-8 MFCD00000600

化学结构图

106-39-8
SMILES: Clc1ccc(Br)cc1

化学属性

Mol. FormulaC6H4BrCl
Mol. Weight191.45
Density1.651
Flash Point>100°(212°F)
TSCAYes
Melting Point64-67°C
Boiling Point196°C at 760 mmHg
Solubility不溶
Refractive index1.5531
Appearance 从醇中析出的针状体结晶。熔点68℃,沸点196℃。溶于醚、苯、氯仿及热醇,不溶于水,相对密度1.576(71/4℃),折光率1.5531(70℃)。

别名和识别编码

Chemical Name4-Bromochlorobenzene
Synonym 1-Bromo-4-chlorobenzene {LY} 1-Bromo-4-chlorobenzene {} {LY} 1-Bromo-4-chlorobenzene {} {} {LY} 1-Bromo-4-chlorobenzene {} {} {} {LY} 1-Bromo-4-chlorobenzene {} {} {} {} {LY} 1-Bromo-4-chlorobenzene {} {} {} {} {} {LY} 1-Bromo-4-chlorobenzene {} {} {} {} {} {} {LY} 1-Bromo-4-chlorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-4-chlorobenzene {} {} {} {} {} {} {} {} {LY} 1-Bromo-4-chlorobenzene {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-4-chlorobenzene {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-4-chlorobenzene {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-4-chlorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-4-chlorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-4-chlorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-4-chlorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromo-4-chlorobenzene {} {} {} {} {} {} {} {}
CAS Number106-39-8
EC Number203-392-3
Beilstein Registry Number1099014
MDL NumberMFCD00000600
Reaxys-RN1099014
PubChem Substance ID7806
Chemical Name Translation4-溴氯苯
LabNetwork Molecule IDLN00194145
InChIInChI=1S/C6H4BrCl/c7-5-1-3-6(8)4-2-5/h1-4H
Canonical SMILESClC1=CC=C(Br)C=C1
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分类

  • {SNA} Alphabetical Index of Analytical Standards, Chemical Class, A-B, Alpha Sort, Analytical Standards,
  • {SNA} Aryl, Building Blocks, C6, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • 8000 Series Solidwaste Methods, A-B, Alpha Sort, Alphabetic, Analytical Standards, Analytical/Chromatography, B, BI - BZ, Bromo, Chemical Class, Chloro, Chromatography, EPA, Environmental Standards, Halogenated,

产品应用

  • 有机合成中间体。

相关文献及参考

  • Short: II/27B
  • Beilstein:5,209
  • Short: II/27C

安全信息

Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H370 Causes damage to organs 导致器官损伤
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
Hazard Codes Xi,Xn,T Xn T Xi
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
WGK Germany3
Signal word Danger Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
RTECSCY9006000
UN Number UN2811 UN 1230 3/PG 2
Packing GroupIII
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 用途二:有机合成中间体。
  • Acros Organics:对氯溴苯 4-Bromochlorobenzene, 99%(106-39-8)
  • Sigma Aldrich:106-39-8(sigmaaldrich)
  • Alfa Aesar:1-溴-4-氯苯,98+% 1-Bromo-4-chlorobenzene, 98+%(106-39-8)
  • 图谱信息:4-溴氯苯(106-39-8)红外图谱(IR2) 4-溴氯苯(106-39-8)Raman光谱 4-溴氯苯(106-39-8)核磁图( 13 CNMR) 4-溴氯苯(106-39-8)质谱(MS) 4-溴氯苯(106-39-8)红外图谱(IR1) 4-溴氯苯(106-39-8)核磁图( 1 HNMR)
  • 方法一:由氯苯溴化而得。将氯苯与铁粉加热至80℃,滴加溴素,在90-100℃反应2.5h。稍冷后放入水中,过滤、洗涤,粗品用乙醇重结晶,即得成品。
  • Hazard Note:Irritant
  • 海关编码:29036990
  • 从醇中析出的针状体结晶。溶于醚;苯;氯仿及热醇,不溶于水
  • 下游产品:4-(4-氯苄氧基)吡啶 --> 4-氯-N-甲基苯胺
  • MOL 文件:106-39-8.mol
  • 用途一:用作溶剂,也用于有机合成
  • 4-溴氯苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30026124 4-溴氯苯;对溴氯苯;对氯溴苯 25g 50元 2011/04/16 B0571 1-溴-4-氯苯 1-Bromo-4-chlorobenzene 25G 146元 2011/04/16 B0571 1-溴-4-氯苯 1-Bromo-4-chlorobenzene 500G 873元
  • TCI Shanghai:1-氯-4-溴苯 1-Bromo-4-chlorobenzene,>;99.0%(GC)(106-39-8)
  • MSDS 信息:4-Bromochlorobenzene(106-39-8).msds
  • 从醇中析出的针状体结晶。溶于醚;苯;氯仿及热醇,不溶于水,

系列性分类


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