Benzylamine 苄胺

CAS 100-46-9 MFCD00008106

化学结构图

100-46-9
SMILES: NCc1ccccc1

化学属性

Mol. FormulaC7H9N
Mol. Weight107
Refractive indexn20/D 1.543(lit.)
Boiling Point184°C
Density0.982
Melting Point10
Flash Point60°C(lit.)
TSCAYes
Solubility与水混溶,可混溶于乙醇、乙醚。
Stability对光敏感
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical NameBenzylamine
Synonym phenylmethylamine benzylamine Benzenemethanamine 苄胺
CAS Number100-46-9
PubChem Substance ID87563450
EC Number202-854-1
Beilstein Registry Number12,1013
MDL NumberMFCD00008106
Reaxys-RN741984
Merck Number1125
Chemical Name Translation苄胺
LabNetwork Molecule IDLN00195244
InChIInChI=1S/C7H9N/c8-6-7-4-2-1-3-5-7/h1-5H,6,8H2
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分类

  • {SNA} Amines, B, Bioactive Small Molecules, Building Blocks, C7, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks,
  • {SNA} Amines, Amides and Derivatives, Analytical Reagents, Analytical/Chromatography, B, Bioactive Small Molecules, Derivatization Reagents, Derivatization Reagents HPLC, Fluorescence, UV-VIS, 细胞生物学
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Amines, Amides and Derivatives, Derivatization Reagents, Derivatization Reagents HPLC, Fluorescence, UV-VIS, 分析/色谱, 分析试剂
  • {SNA} Am

产品应用

  • 在显微微晶分析中用以测定钼酸盐、钒酸盐、钨酸盐、钍、锆、铈、镧、镨和钕的沉淀剂。有机分析用于区别各类羧酸(与羧酸酯类反应生成N-苄胺衍生物,按熔点的不同来区别各种羧酸),金属有机化合物的定性试验。

相关文献及参考

  • Short: II/27B
  • Short: II/5
  • Merck:14,1125 Beilstein:12,1013
  • Merck:14,1125

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H302+H312
  • H312 Harmful in contact with skin 皮肤接触有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes C
RTECSDP1488500
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
UN Number 2734 UN2735
Storage condition 密封保存。 密封避光保存。 Air Sensitive
Packing GroupII
Hazard Class8/3
Warnings 危化品目录(2015)
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   USXXAM United States Patent Document.  (U.S. Patent Office, Box 9,
   Washington, DC 20231)  Volume(issue)/page/year: #3816470

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 39(4),86,1974

Restrict -

其他信息

  • 呈强碱性。对二氧化碳敏感。能与水、醇及醚等混溶。易溶于丙酮,溶于苯。有毒,致死量(兔,经口)250mg/kg。有腐蚀性。有催泪性。对人的皮肤及粘膜有刺激性。

系列性分类