CAS 464-48-2 MFCD00064148-(-)-Camphor (1S,4S)-1,7,7-三甲基双环[2.2.1]庚烷-2-酮 TAO{mole}

(-)-Camphor (1S,4S)-1,7,7-三甲基双环[2.2.1]庚烷-2-酮

CAS 464-48-2 MFCD00064148

化学结构图

SMILES: CC1(C)[C@H]2CC[C@]1(C)C(=O)C2

化学属性

Mol. Formula	C10H16O
Mol. Weight	152
Density	5.24
Flash Point	65°(149°F)
TSCA	Yes
Boiling Point	204
Melting Point	175.0 to 180.0 deg-C
Autoignition Point	870 °F
Vapor Density	5.24 (vs air)
Vapor Pressure	4 mmHg ( 70 °C)
Refractive index	-44 ° (C=20, EtOH)

别名和识别编码

Chemical Name	(-)-Camphor
Synonym	L-2-Bornanone (1s,4s)-(-)-campho L-(-)-樟脑 l-Camphor 2-Camphanone (1S)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one 1,7,7-trimethylnorcamphor CAMPHOR, -(1S)-(-)- Caladryl (1S)-(-)-CAMPHOR L-(-)-CAMPHOR 1,7,7-三甲基二环[2.2.1]庚烷-2-酮 L-(-)-1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPTAN-2-ONE 卡氟 (1S)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one (1S)-CAMPHOR radian b 左旋樟脑 1-(-)CAMPHOR L-(-)-2-KETO-1,7,7-TRIMETHYLNORCAMPHANONE Bicyclo(2.2.1)heptan-2-one, 1,7,7-trimethyl-, (1S)- (-)-CAMPHOR (-)-Alcanfor (-)-樟脑 (1S)-1,7,7-三甲基二环[2.2.1]庚烷-2-酮 l-(-)-Camphor L(-)-樟脑
CAS Number	464-48-2
PubChem Substance ID	444294
EC Number	207-354-7
Beilstein Registry Number	7(4)213
MDL Number	MFCD00064148
Reaxys-RN	2500713
Merck Number	1732
Chemical Name Translation	(1S,4S)-1,7,7-三甲基双环[2.2.1]庚烷-2-酮
Wiswesser Line Notation	L55 A CVTJ A1 A1 B1
LabNetwork Molecule ID	LN00241903
InChI	InChI=1S/C10H16O/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7H,4-6H2,1-3H3/t7-,10+/m0/s1

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品牌质保精细包装现货库存一流品牌服务

产品应用

手性中间体，用于合成高效的增香剂、脱硫剂。

安全信息

GHS Symbol

WGK Germany1

Hazard Codes

Hazard statements

H228 Flammable solid 易燃固体
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激
H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷

Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

RTECSEX1250000

Precautionary statements

P203
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P301+P312+P330
P302+P350
P302+P352
P302+P352+P332+P313+P362+P364
P304+P340
P305+P351+P338
P305+P351+P338+P337+P313
P318
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P332+P313
P332+P317
P337+P313
P337+P317
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P370+P378
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word {} {} {} {} {} {} {} {} {TCI}

UN Number 2717 UN 2717 4.1/PG 3 UN2717

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；

Risk Statements

R11 Highly flammable 非常易燃
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性

Packing GroupIII

Hazard Class4.1

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 800 ug/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 1,445,1909

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 320 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02534

其他信息

爆炸物危险特性:蒸汽遇高温, 明火, 氧化剂可爆炸
储运特性:库房低温通风干燥; 与食品原料, 氧化剂分开存放; 防明火, 高温
蒸气压:4 mm Hg ( 70 °C)
Sigma Aldrich:464-48-2(sigmaaldrich)
可燃性危险特性:遇高温, 明火, 氧化剂易燃; 热分解辛辣刺激烟雾
TCI Shanghai:樟脑 (-)-Camphor,>;96.0%(GC)(464-48-2)
灭火剂:水雾, 二氧化碳, 泡沫, 干粉
MOL 文件:464-48-2.mol
急性毒性:口服-大鼠 LDL0: 0.8 毫克/公斤; 腹腔-小鼠 LD50: 320 毫克/公斤
左旋樟脑价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 C1251 (-)-樟脑 (-)-Camphor 5G 390元 2010/06/21 108190500 左旋樟脑 L(-)-Camphor , tech. 50 GR 3720元 2010/06/21 108190100 左旋樟脑 L(-)-Camphor , tech. 10 GR 942元
蒸气密度:5.24 (vs air)
Acros Organics:L(-)-樟脑 L(-)-Camphor, tech.(464-48-2)
用途一:手性中间体，用于合成高效的增香剂、脱硫剂。
Alfa Aesar:(1S)-(-)-樟脑,99% (1S)-(-)-Camphor, 99%(464-48-2)
类别:易燃固体
毒性分级:剧毒