Copper(I) Bromide-Dimethyl Sulfide 溴化亚铜二甲硫醚
CAS 54678-23-8 MFCD00043295
化学结构图
SMILES: CSC.[Cu]Br
化学属性
| Mol. Formula | CuBr · CH3SCH3 |
|---|---|
| Mol. Weight | 205.58 |
| Melting Point | 132°C |
| Density | 1.422 |
| TSCA | No |
| Appearance | off-white to light-green pwdr. |
| Stability | moisture sensitive |
别名和识别编码
| Chemical Name | Copper(I) Bromide-Dimethyl Sulfide |
|---|---|
| Synonym | Bromo[thiobis[methane]]copper {LY} Bromo[thiobis[methane]]copper {} {LY} Bromo[thiobis[methane]]copper {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromo[thiobis[methane]]copper {} {} {} {} {} {} {} {} {} |
| Beilstein Registry Number | 4386581 |
| PubChem Substance ID | 2724234 |
| CAS Number | 54678-23-8 |
| EC Number | 259-292-5 |
| MDL Number | MFCD00043295 |
| Chemical Name Translation | 溴化亚铜二甲硫醚 |
| InChIKey | PMHQVHHXPFUNSP-UHFFFAOYSA-M |
| LabNetwork Molecule ID | LN00222683 |
| InChI | InChI=1S/C2H6S.BrH.Cu/c1-3-2;;/h1-2H3;1H;/q;;+1/p-1 |
| Canonical SMILES | CSC.[Cu]Br |
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分类
- Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper, Copper Salts, Materials Science, Metal and Ceramic Science, Salts
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper, Copper Salts, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, 材料科学
相关文献及参考
- 1. Org. Synth. 83 , 80, (2006)
- Rossiter, B. E. et al.B. E.; Swingle, N. M. Chem. Rev. 92 , 771, (1992)
- Robert, T.; Velder, J.; Schmalz, H.-G. Angew. Chem. Int. Ed. Engl. 47 , 7718, (2008)
- Pacheco B.; Piguel, S. et al. Org. Lett. 12 , 4038, (2010) 摘要
- Fieser 6 ,225 / Fieser 8 ,117 / Fieser 10 ,104 / Fieser 15 ,100 / Fieser 16 ,96
- Aldrich MSDS 1 , 485:C / Corp MSDS 1 (1), 911:B / FT-IR 1 (2), 1248:B / FT-IR 2 (3), 4517:C / RegBook 1 (2), 3079:E / Structure Index 1 , 488:C:4
安全信息
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
