CAS 859-65-4 MFCD00014088-1-Phenyl-2-(Triphenylphosphoranylidene)Ethanone (苯甲酰基亚甲基)三苯基磷烷 TAO{mole}

1-Phenyl-2-(Triphenylphosphoranylidene)Ethanone (苯甲酰基亚甲基)三苯基磷烷

CAS 859-65-4 MFCD00014088

化学结构图

SMILES: O=C(C=P(c1ccccc1)(c1ccccc1)c1ccccc1)c1ccccc1

化学属性

Mol. Formula	C26H21OP
Mol. Weight	380.42
Melting Point	183-186 °C
TSCA	No
Boiling Point	550.9°C at 760 mmHg

别名和识别编码

Chemical Name	1-Phenyl-2-(Triphenylphosphoranylidene)Ethanone
MDL Number	MFCD00014088
CAS Number	859-65-4
Synonym	1-Phenyl-2-(triphenylphosphoranylidene)ethanone {LY} 1-Phenyl-2-(triphenylphosphoranylidene)ethanone {} {LY} 1-Phenyl-2-(triphenylphosphoranylidene)ethanone {} {} {LY} 1-Phenyl-2-(triphenylphosphoranylidene)ethanone {} {} {} {LY} 1-Phenyl-2-(triphenylphosphoranylidene)ethanone {} {} {} {} {LY} 1-Phenyl-2-(triphenylphosphoranylidene)ethanone {} {} {} {} {} {} {} {} {} {} {LY} 1-Phenyl-2-(triphenylphosphoranylidene)ethanone {} {} {} {} {} {} {LY} 1-Phenyl-2-(triphenylphosphoranylidene)ethanone {} {} {} {} {} {} {} {LY} 1-Phenyl-2-(triphenylphosphoranylidene)ethanone {} {} {} {} {} {} {} {} {LY} 1-Phenyl-2-(triphenylphosphoranylidene)ethanone {} {} {} {} {} {} {} {} {} {LY} 1-Phenyl-2-(triphenylphosphoranylidene)ethanone {} {} {} {} {} {} {} {} {} {} {LY} 1-Phenyl-2-(triphenylphosphoranylidene)ethanone {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Phenyl-2-(triphenylphosphoranylidene)ethanone {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Phenyl-2-(triphenylphosphoranylidene)et
EC Number	212-727-2
Beilstein Registry Number	620285
Reaxys-RN	620285
PubChem Substance ID	70073
Chemical Name Translation	(苯甲酰基亚甲基)三苯基磷烷
InChIKey	MZRSAJZDYIISJW-UHFFFAOYSA-N
Wiswesser Line Notation	RV1UPR&R&R
LabNetwork Molecule ID	LN00518714
Canonical SMILES	C1=CC=C(C=C1)C(=O)C=P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4
InChI	InChI=1S/C26H21OP/c27-26(22-13-5-1-6-14-22)21-28(23-15-7-2-8-16-23,24-17-9-3-10-18-24)25-19-11-4-12-20-25/h1-21H

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品牌质保精细包装现货库存一流品牌服务

安全信息

RTECSAN0540000

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S37 Wear suitable gloves 戴适当手套；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Storage condition 2-8°C, stored under nitrogen, away from moisture {LY} 2-8°C, stored under nitrogen, away from moisture Air Sensitive Refrigerator {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {} {} {}

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 32 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#01350

GHS Symbol

Signal word Warning

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P352
P304+P340
P305+P351+P338
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P332+P313
P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P501a

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

其他信息

Alfa Aesar:（苯甲酰基亚甲基）三苯基磷烷,98+% (Benzoylmethylene)triphenylphosphorane, 98+%(859-65-4)
Sigma Aldrich:859-65-4(sigmaaldrich)
TCI Shanghai:2-(三苯基亚正膦基)苯乙酮 2-(Triphenylphosphoranylidene)acetophenone,>;98.0%(T)(859-65-4)
图谱信息:(苯甲酰甲烯)三苯基磷烷(859-65-4)红外图谱(IR1) (苯甲酰甲烯)三苯基磷烷(859-65-4)质谱(MS) (苯甲酰甲烯)三苯基磷烷(859-65-4)红外图谱(IR2)
(苯甲酰甲烯)三苯基磷烷价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 T2002 2-(三苯基亚正膦基)苯乙酮 2-(Triphenylphosphoranylidene)acetophenone 5G 1020元 2010/05/25 A12184 （苯甲酰基亚甲基）三苯基磷烷, 98+% (Benzoylmethylene)triphenylphosphorane, 98+% 5g 273元 2010/05/25 A12184 （苯甲酰基亚甲基）三苯基磷烷, 98+% (Benzoylmethylene)triphenylphosphorane, 98+% 25g 986元
敏感性:Air Sensitive
MOL 文件:859-65-4.mol