D-(+)-Sucrose 蔗糖

CAS 57-50-1 MFCD00006626

化学结构图

57-50-1
SMILES: OCC1OC(OC2(CO)OC(CO)C(O)C2O)C(O)C(O)C1O

化学属性

Mol. FormulaC12H22O11
Mol. Weight342
Melting Point185-187
Density1.580
TSCAYes
SolubilitySoluble in water. Slightly soluble in alcohol, methanol
Stability对湿度敏感
Appearance 25 白色结晶性无臭固体,有甜味。相对密度(d )1.587,熔点170~186℃(分解)。易溶于水,不溶于乙醚。 4
Refractive index66.5 ° (C=26, H2O)

别名和识别编码

Chemical NameD-(+)-Sucrose
CAS Number57-50-1
Synonym ######## (a-D-Glucosido)-ß-D-fructofuranosid (alpha-D-Glucosido)-beta-D-fructofuranoside Amerfond B-D-呋喃果糖基- D(+)-Saccharose D(+)-蔗糖 D-(+)-Saccharose Rock candy SACCHAROSE SUCROSE Saccharose Sucralox Sucrose beta-d-fructofuranose-(2-1)-alpha-d-glucopyranoside {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} ß-D-Fructofuranosyl a-D-glucopyranoside α-D-Glucopyranoside, β-D-fructofuranosyl- α-D-吡喃葡糖基-β-D-呋喃果糖 α-D-吡喃葡萄糖基β-D-呋喃果糖苷 β-D-呋喃果糖基-α-D-吡喃葡糖 β-D-呋喃果糖基-α-D-吡喃葡糖;α-D-吡 β-D-呋喃果糖基-α-D-吡喃葡糖;α-D-吡喃葡糖基-β-D-呋喃果糖;D(+)蔗糖;甜菜糖; β-D-呋喃果糖基-a-D-吡喃葡萄苷;白砂糖 甜菜糖
PubChem Substance ID5988
EC Number200-334-9
Beilstein Registry Number90825
MDL NumberMFCD00006626
Reaxys-RN90825
Merck Number8881
Chemical Name Translation蔗糖
Wiswesser Line NotationT6OTJ CQ DQ EQ F1Q BO- BT5OTJ B1Q CQ DQ E1Q -GLU,FRUC
LabNetwork Molecule IDLN01349622
InChIInChI=1S/C12H22O11/c13-1-4-6(16)8(18)9(19)11(21-4)23-12(3-15)10(20)7(17)5(2-14)22-12/h4-11,13-20H,1-3H2/t4-,5-,6-,7-,8+,9-,10+,11-,12+/m1/s1
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分类

  • {SNA} Acacia,
  • {SNA} Carbohydrates, Carbohydrates A to Z, Carbohydrates P-Z, Core Bioreagents, Disaccharide, Miscellaneous Reagents and Supplements, Research Essentials, 生化试剂, 碳水化合物, 细胞培养,
  • {SNA} Carbohydrate Chemistry,
  • {SNA} Carbohydrates, Carbohydrates A to Z, Carbohydrates P-Z, Carbohydrates for Protein Stabilization, Core Bioreagents, Density Gradient Media, Disaccharide, Polyhydric alcohols, Reagents for Protein Stabilization, Research Essentials, 生化试剂, 碳水化合物, 细胞生物学, 蛋白质及衍生物,

产品应用

  • 试剂蔗糖用于1-萘酚的测定,也用于钙、镁分离及生物培养基的制备。
  • 细胞培养级用于蔗糖梯度纯化病毒和蛋白质。
  • 植物细胞培养级用于植物细胞中的冷冻保护。
  • 分子生物学级用于不连续蔗糖密度梯度的等密度离心法,如:从膜结合核糖体中分离mRNA。

相关文献及参考

  • Cull, M. and McHenry, C.S., Preparation of extracts from prokaryotes. Meth. Enzymol. 182 , 147, (1990)
  • Gerner, C., et al., Similarity between nuclear matrix proteins of various cells revealed by an improved isolation method. J. Cell. Biochem. 71 , 363, (1998) 摘要
  • Merck:14,8881
  • Merck:14,8881 Beilstein:31,424
  • Short: II/27B
  • Watanabe, T., et al.: Biosci. Biotech. Biochem., 72, 3167 (2008),
  • You, Y., et al.: J. Agric. Food Chem., 57, 709 (2009),
  • [1]. Duca FA, et al. Effect of diet on preference and intake of sucrose in obese prone and resistant rats. PLoS One. 2014 Oct 20;9(10):e111232.

安全信息

WGK Germany2
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
RTECSWN6500000
Signal word Warning
GHS Symbol
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
Storage condition Store at RT. 密封保存。
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - domestic
DOSE/DURATION           : 40 gm/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - respiratory stimulation
   Gastrointestinal - hypermotility, diarrhea
REFERENCE :
   NAREA4 Nutrition Abstracts and Reviews.  (Slough, UK)  V.1-46, 1931-76.
   Volume(issue)/page/year: 30,503,1960

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 29700 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - cyanosis
   Gastrointestinal - hypermotility, diarrhea
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   7,609,1965

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 14000 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PCJOAU Pharmaceutical Chemistry Journal (English Translation).  Translation
   of KHFZAN. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013)  No.1-
   1967-  Volume(issue)/page/year: 15,139,1981

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 300 mg/L
REFERENCE :
   PMRSDJ Progress in Mutation Research.  (Elsevier Science Pub. Co., Inc., 52
   Vanderbilt Ave., New York, NY 10017)  V.1-    1981- Volume(issue)/page/year:
   1,502,1981

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 10 gm/L
REFERENCE :
   ATSUDG Archives of Toxicology, Supplement.  (Springer-Verlag New York, Inc.,
   Service Center, 44 Hartz Way, Secaucus, NJ 07094)  No.1-    1978-
   Volume(issue)/page/year: 4,41,1980

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 600 ug/plate
REFERENCE :
   PMRSDJ Progress in Mutation Research.  (Elsevier Science Pub. Co., Inc., 52
   Vanderbilt Ave., New York, NY 10017)  V.1-    1981- Volume(issue)/page/year:
   1,343,1981

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 275 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 189,15,1987

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1548 gm/kg
SEX/DURATION            : female 21 day(s) pre-mating
                          female 1-22 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - Central Nervous System
REFERENCE :
   IJMDAI Israel Journal of Medical Sciences.  (POB 1435, Jerusalem 91013,
   Israel)  V.1-    1965-  Volume(issue)/page/year: 16,789,1980

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - species unspecified
DOSE                    : 54810 mg/kg
SEX/DURATION            : female 15-35 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 30,203,1984

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 683 gm/kg
SEX/DURATION            : lactating female 21 day(s) post-birth
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight
   gain)
REFERENCE :
   AJCNAC American Journal of Clinical Nutrition.  (American Soc. for Clinical
   Nutrition, Inc., 9650 Rockville Pike, Bethesda, MD 20814)  V.2-    1954-
   Volume(issue)/page/year: 28,1416,1975

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 683 gm/kg
SEX/DURATION            : female 1-21 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specif

Hazard statements

其他信息

  • MOL 文件:57-50-1.mol
  • 用途二:蔗糖是最普通的食和糖,也用于制柠檬酸、焦糖、转化糖、透明肥皂等。蔗糖在高浓度时能抑制细菌生长,医药上可作防腐剂、抗氧剂的药片赋形剂等。1980年世界原糖产量为8710万t,其中蔗糖5200万t,甜菜糖350
  • {Chemical
  • Acros Organi
  • 参考质量标准:FCC,2000 含量[国际糖度(°Z)] 99.8~100.2 砷(GT-3) ≤lmg/kg 色度 ≤751U 重金属(Pb,GT-16) ≤5mg/kg 转化糖 ≤0,1% 铅(GT-18) ≤0.1mg/kg 干燥失重(105"C,3h) ≤0.1% 灼烧残渣(GT-5) ≤0.15% 比旋光度[α] D 20 (配26g/100ml溶液,20℃后测定) +65.9°~+66.7° GB 317—1998(白砂糖标准) 感官要求 晶粒均匀,粒度在下列范围内应不少于80℃ 粗粒:0.800~2.50mm;大粒:0.630~1.60mm;中粒:0.450~1.25mm;细粒:0.280~0.800mm。 晶粒或其水溶液味甜、无异味。 干燥松散、洁白、有光泽,无明显黑点。 其他见表02347—1。 GB 1445--2000(绵白糖标准) 表0234.7—2。
  • Acros Organics:D(+)-蔗糖 D(+
  • 用途二:蔗糖是最普通的食和糖,也用于制柠檬酸、焦糖、转化糖、透明肥皂等。蔗糖在高浓度时能抑制细菌生长,医药上可作防腐剂、抗氧剂的药片赋形剂等。1980年世界原糖产量为8710万t,其中蔗糖5200万t,甜菜糖3500万t。来自甘蔗和甜菜的蔗糖受自然条件的限制发展缓慢,世界缺糖情况较较严重。另外,各种特殊需要,促旱灾了新甜料的研究和发展,现在已经找出了许多天然甜料和合成甜料。试剂蔗糖用于1-萘酚的测定,也用于钙、镁分离及生物培养基的制备。
  • 味甜。有吸湿性。在空气中稳定。
  • {Chem
  • 图谱信息:蔗糖(57-50-1)质谱(MS) 蔗糖(57-50-1)核磁图( 1 HNMR) 蔗糖(57-50-1)核磁图( 13 CNMR) 蔗糖(57-50-1)红外图谱(IR1) 蔗糖(57-50-1)红外图谱(IR2)
  • 下游产品:乳酸 --> 富马酸 --> 色料焦糖 --> D-(-)-果糖 --> 果胶 --> D-山梨醇 --> 微晶纤维素 --> 葡聚糖 --> 酵母萃取物 --> 赤霉素 --> 铬鞣剂 --> 木糖醇 --> 盐酸赖氨酸 --> D-甘露糖醇 --> 杆菌肽 --> 三氯蔗糖 --> 叶绿素 A --> 果胶酶 --> 乳酸亚铁 --> 胃酶 --> 转化酶 --> 甘草次酸 --> 黄原胶 --> 盐基性硫酸铬(固) --> 总叶绿素 --> 叶绿素 B --> 葡聚糖酶 --> 转化糖 --> 猴茹菌浸膏
  • 易溶于水。
  • F:3
  • 图谱信息:蔗糖(57-50-1)质谱(MS) 蔗糖(57-50
  • Alfa Aesar:蔗糖,ACS Sucrose, ACS(57-50-1)
  • 海关编码:17019910
  • MSDS 信息:Saccharose(57-50-1).msds
  • 用途四:蔗糖是最普通的食和糖,也
  • 蔗糖价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 10021418 蔗糖 500g 21元 2011/08/23 1002141933 蔗糖 25kg/桶 750元 2011/08/23 10021428 蔗糖 500g 19元
  • 方法一:由甘蔗或甜菜经压榨或渗滤后澄清、蒸发、结晶而得。
  • 方法二:蔗糖大量来自甘蔗糖和甜菜,甘蔗含蔗糖约15-20%,甜菜含10-17%。其他各种果实、种子、叶、花、根中也有不同的含量。将甘蔗榨出法液或将甜菜切片用水提出糖汁,用石灰澄清法或兼用亚硫酸饱充法,除去糖汁中的杂质,过滤后将滤液真空蒸浓,再结晶分离而得粗糖,再经脱色、重结晶而得精糖。
  • 用途三:试剂蔗糖用于1-萘酚的测定,也用于钙、镁分离及生物培养基的制备。

系列性分类


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