CAS 623-33-6 MFCD00012871-Glycine Ethyl Ester Hydrochloride 甘氨酸乙酯盐酸盐 TAO{mole}

Glycine Ethyl Ester Hydrochloride 甘氨酸乙酯盐酸盐

CAS 623-33-6 MFCD00012871

化学结构图

SMILES:

化学属性

Mol. Formula	C4H10ClNO2
Mol. Weight	139.58
Density	1.0
Melting Point	145-146°C
TSCA	Yes
Solubility	>1000 G/L (20 ºC)
Appearance	本品为白色结晶，m.p.145～146℃，易溶于水，易潮解。
pH	:A

别名和识别编码

Chemical Name	Glycine Ethyl Ester Hydrochloride
CAS Number	623-33-6
Synonym	Glycine ethyl ester monohydrochloride {LY} Glycine ethyl ester monohydrochloride {} {LY} Glycine ethyl ester monohydrochloride {} {} {LY} Glycine ethyl ester monohydrochloride {} {} {} {LY} Glycine ethyl ester monohydrochloride {} {} {} {} {LY} Glycine ethyl ester monohydrochloride {} {} {} {} {} {LY} Glycine ethyl ester monohydrochloride {} {} {} {} {} {} {LY} Glycine ethyl ester monohydrochloride {} {} {} {} {} {} {} {LY} Glycine ethyl ester monohydrochloride {} {} {} {} {} {} {} {} {LY} Glycine ethyl ester monohydrochloride {} {} {} {} {} {} {} {} {} {LY} Glycine ethyl ester monohydrochloride {} {} {} {} {} {} {} {} {} {} {LY} Glycine ethyl ester monohydrochloride {} {} {} {} {} {} {} {} {} {} {} {LY} Glycine ethyl ester monohydrochloride {} {} {} {} {} {} {} {} {} {} {} {} {LY} Glycine ethyl ester monohydrochloride {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Glycine ethyl ester monohydrochloride {} {} {} {} {} {} {} {}
MDL Number	MFCD00012871
EC Number	210-787-4
Beilstein Registry Number	3594034
PubChem Substance ID	87570308
Reaxys-RN	3594034
Chemical Name Translation	甘氨酸乙酯盐酸盐
Wiswesser Line Notation	Z1VO2
InChIKey	TXTWXQXDMWILOF-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00335656
Canonical SMILES	O=C(CN)OCC.Cl

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产品应用

用于医药生化试剂。

安全信息

Signal word Danger Warning

GHS Symbol

WGK Germany3

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R41 Risk of serious damage to eyes 有严重损伤眼睛的危险

Precautionary statements

P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P305+P351+P338
P337+P313

Hazard statements

H318 Causes serious eye damage 严重伤害眼睛
H319 Causes serious eye irritation 严重刺激眼睛

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

RTECSMC0525000

Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture Hygroscopic Store at RT. Store at room temperature Store at room temperature, keep dry and cool {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

Hazard Codes Xi

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 750 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

其他信息

MOL 文件:623-33-6.mol
Alfa Aesar:甘氨酸乙酯.盐酸盐,99% Glycine ethyl ester hydrochloride, 99%(623-33-6)
上游原料:乙
用途四:用于
用途一:用作农药菊酯类杀虫剂及医药中间体
下游产品:2-(3-溴-6-甲基-2-吡嗪酮-1(2H)-基)乙酸乙酯 --> 4-Boc-氨甲基-3-羟基-1-N-Boc-吡咯烷 --> Boc-1-氨基环丙基甲酸 --> 4,5,6,7-四氢-2-甲基呋喃[2,3-C]并吡啶 --> N-Boc-3-氨甲基-4-羟基吡咯烷 --> 2-(3-溴-2-吡嗪酮-1(2H)-基)乙酸乙酯 --> 1-氨基环丙烷羧酸 --> 4-羟甲基咪唑盐酸盐 --> 2-(3,4-二氢-6-甲基-2,3-二氧代吡嗪-1(2H)-基)乙酸乙酯 --> 2-(3,4-二氢-2,3-二氧代吡嗪-1(2H)-基)乙酸乙酯 --> N-Boc-3-氰基-4-羟基吡咯烷 --> 胺菊酯 --> 咪唑-4-甲酸乙酯 --> 甘氨酸甲酯盐酸盐 --> 4-甲氧甲基苄基菊酸酯 --> 阿那格雷 --> 2-[(2-噻吩甲酰基)氨基]乙酸乙酯 --> 重氮乙酸乙酯 --> 二苯亚甲基甘氨酸乙酯 --> N-FMOC-L-甘氨酸
TCI Shanghai:甘氨酸乙酯盐酸盐 Glycine Ethyl Ester Hydrochloride,>;99.0%(T)(623-33-6)
MSDS 信息:Ethyl glycinate hydrochloride(623-33-6).msds
Acros Organics:甘氨酸乙酯盐酸盐 Glycine ethyl ester hydrochloride, 99%(623-33-6)
方法一:可以用甘氨酸或氯乙酸为原料制备。分述如下。甘氨酸为原料法用干燥的氯化氢气体通入无水乙醇中，先制成氯化氢乙醇溶液，然后加入甘氨酸，加热搅拌进行酯化，反应温度控制在80～85℃，待甘氨酸全部溶解后，再搅拌几分钟，趁热将反应液移到结晶锅，冷却结晶，过滤，得甘氨酸乙酯盐酸盐。反应方程式：NH 2 CH 2 COOH+C 2 H 5 O[HCl]→NH 2 CH 2 COOC 2 H 5 ·HCl 也可以在带有搅拌的反应器中加入甘氨酸和无水乙醇，加热至60℃，通入氯化氢气体，氯化氢通到反应物完全溶解后，继续通氯化氢至重新结晶时为终点，将反应液移至结晶锅，边搅拌，边冷却结晶、过滤，用无水乙醇洗涤、干燥得甘氨酸乙酯盐酸盐。氯乙酸为原料法将氯乙酸、乌洛托品和无水乙醇加入到反应器中，在45℃时通人氨气，使pH=8～8.5，控制通氨气速度，以维持反应温度在40～65℃之间，通完氨气后在65℃保温反应1h，然后降温到30℃，开始滴加氯化氢-无水乙醇溶液。待滴加完后，在70℃反应2h，然后在62～65℃趁热过滤，分离出氯化铵结晶，滤液放置于结晶锅中，冷却到10℃，边搅拌，边结晶，结晶体过滤、干燥得甘
检测方法:T
敏感性:Hygroscopic
海关编码:29224995
图谱信息:甘氨酸乙酯盐酸盐(623-33-6)Raman光谱甘氨酸乙酯盐酸盐(623-33-6)红外图谱(IR1) 甘氨酸乙酯盐酸盐(623-33-6)红外图谱(IR2) 甘氨酸乙酯盐酸盐(623-33-6)核磁图( 13 CNMR) 甘氨酸乙酯盐酸盐(623-33-6)质谱(MS) 甘氨酸乙酯盐酸盐(623-33-6)核磁图( 1 HNMR)
易溶于水，微溶于乙醇，在200℃缓慢分解。水分溶解度: >1000 g/L (20 °C)
甘氨酸乙酯盐酸盐价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 xp620103 甘氨酸乙酯盐酸盐;盐酸甘氨酸乙酯;盐酸氨基乙酸乙酯 10g 13.5元 2011/04/16 G0102 甘氨酸乙酯盐酸盐 Glycine Ethyl Ester Hydrochloride 500G 790元 2011/04/16 G0102 甘氨酸乙酯盐酸盐 Glycine Ethyl Ester Hydrochloride 25G 166元