CAS 1489-69-6 MFCD00012261-Cyclopropanecarboxaldehyde 环丙烷甲醛 TAO{mole}

Cyclopropanecarboxaldehyde 环丙烷甲醛

CAS 1489-69-6 MFCD00012261

化学结构图

SMILES: O=CC1CC1

化学属性

Mol. Formula	C4H6O
Mol. Weight	70.09
Density	0.938 g/mL at 25 °C(lit.)
Refractive index	n20/D 1.4298(lit.)
Boiling Point	99.5°C at 760 mmHg
Flash Point	7°C
TSCA	Yes
Stability	对空气敏感

别名和识别编码

Chemical Name	Cyclopropanecarboxaldehyde
Synonym	Cyclopropanecarbaldehyde {LY} Cyclopropanecarbaldehyde {} {LY} Cyclopropanecarbaldehyde {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropanecarbaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL Number	MFCD00012261
CAS Number	1489-69-6
EC Number	000-000-0
Beilstein Registry Number	906781
PubChem Substance ID	123114
Alfabeta Name	CYCLOPROPANECARBALDEHYDE
Chemical Name Translation	环丙烷甲醛
InChIKey	JMYVMOUINOAAPA-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00007968
InChI	InChI=1S/C4H6O/c5-3-4-1-2-4/h3-4H,1-2H2
Canonical SMILES	O=CC1CC1

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产品应用

用于制备环化四丙基四氢萘酮，需经过对映体选择性的钯催化的环加成反应。也是合成中引入环丙基的常用试剂。

安全信息

Signal word Danger Warning

GHS Symbol

WGK Germany3

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S20 When using do not eat or drink 使用时，不得进食，饮水；

Risk Statements

R34 Causes burns 会导致灼伤
R11 Highly flammable 非常易燃
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P242 Use only non-sparking tools. 只能使用无火花工具。
P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P330+P331
P302+P361+P354
P303+P361+P353
P304+P340
P305+P351+P338
P305+P354+P338
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P316
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P370+P378
P403+P235
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSGZ1005000

Packing GroupII

UN Number UN2924 2924 UN 2924 3/PG 2

Storage condition -20°C, stored under nitrogen {LY} -20°C, stored under nitrogen Air Sensitive Refrigerator {} {LY} -20°C, stored under nitrogen {} {} {LY} -20°C, stored under nitrogen {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nit

Hazard Codes F,C F;C

Warnings IRRITANT

Hazard Class3

其他信息

环丙甲醛价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 c1707 环丙甲醛 Cyclopropanecarboxaldehyde 5G 973元 2014/06/02 c1707 环丙甲醛 Cyclopropanecarboxaldehyde 1G 320元 2010/06/21 366820050 环丙甲醛 Cyclopropanecarboxaldehyde 98% 5 GR 1398元
下游产品:1-(环丙甲基)哌嗪 --> N-Boc-4-(环丙甲基)哌嗪
Sigma Aldrich:1489-69-6(sigmaaldrich)
检测方法:GC
敏感性:Air Sensitive
用途一:用于制备环化四丙基四氢萘酮，需经过对映体选择性的钯催化的环加成反应。也是合成中引入环丙基的常用试剂。
MSDS 信息:Cyclopropanecarboxaldehyde(1489-69-6).msds
MOL 文件:1489-69-6.mol
Acros Organics:环丙烷甲醛 Cyclopropanecarboxaldehyde, 98%(1489-69-6)
存储注意事项:氮气保护
上游原料:二氯甲烷 --> 硫酸镁 --> 三乙胺 --> 次氯酸钠 --> 草酰氯 --> 磷酸二氢钾 --> 溴化钾 --> 氯铬酸吡啶盐 --> 2,2,6,6-四甲基哌啶氧化物 --> 羟甲基环丙烷 --> 溴代环丙烷
Alfa Aesar:环丙甲醛,98% Cyclopropanecarboxaldehyde, 98%(1489-69-6)
TCI Shanghai:环丙甲醛 Cyclopropanecarboxaldehyde,>;97.0%(GC)(1489-69-6)