Potassium Nitrate 硝酸钾

CAS 7757-79-1 MFCD00011409

化学结构图

7757-79-1
SMILES: O=[N+]([O-])[O-].[K+]

化学属性

Mol. FormulaKNO3
Mol. Weight101.10
Melting Point334 °C(lit.)
Density1.0
SolubilitySoluble in water, glycerol, and liquid ammonia.
TSCAYes
Boiling Point400° dec.
Flash Point400°C
Stability易吸潮

别名和识别编码

Chemical NamePotassium Nitrate
Synonym Collo-Bo E 252 FILLING SOLUTION FOR CYANIDE OR SULFIDE ELECTRODE FILLING SOLUTION FOR FLUORIDE ELECTRODE FILLING SOLUTION FOR SALT BRIDGES AND DOUBLE-JUNCTION ELECTRODES Filling solution for chloride combination electrode (10% KNO3, trace AgCl, KCl) Filling solution for cyanide or sulfide electrode (10% KNO3, trace AgCl, KCl) KNO3 KNO3 (potassium nitrate) Kalisalpeter Kaliumnitrat Kaliumsalz der Salpetersäure NITRATE NITROGEN NITRATE NITROGEN STANDARD NITRIC ACID POTASSIUM SALT Niter Niter Nitre Nitric acid, potassium salt Saltpeter Nitre Nitric acid Potassium salt Nitric acid potassium salt (1:1) Nitric acid, potassium salt POTASSIUM ICP
CAS Number7757-79-1
PubChem Substance ID24434
EC Number231-818-8
MDL NumberMFCD00011409
Merck Number14,7648
Beilstein Registry Number2384789
Chemical Name Translation硝酸钾
Wiswesser Line Notation.KA..N-O3
InChIInChI=1S/K.NO3/c;2-1(3)4/q+1;-1
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分类

  • {SNA} Molecular Biology, Optimization Reagents, Protein Structural Analysis, Proteomics, X-Ray Crystallography
  • {SNA} Chemical Synthesis, Inorganic Salts, K, Materials Science, Metal and Ceramic Science, Potassium, Potassium Salts, Salts, Synthetic Reagents, Ultra-High Purity Materials
  • {S
  • {SNA} Analytical/Chrom
  • {SNA} Analytical/Chroma
  • {SNA} Chemical Synthesis, Inorganic Salts, Potassium, Synthetic Reagents
  • {SNA} Chemical Synthesis, Essential Chemicals, Inorganic Salts, Potassium, Potassium Salts, Research Essentials, Salts, Synthetic Reagents

产品应用

  • A naturally occurring mineral source of nitrogen.

相关文献及参考

  • In combination with BF3 etherate, aromatic rings are nitrated: Synthesis, 1087 (1992).
  • In the presence of hydrated BF3, alkyl nitrates free of the nitrite can be prepared: Synthesis, 207 (1993).
  • In combination with SO2Cl2, aromatic thiols are converted to sulfonyl chlorides: Chem. Lett., 1483 (1992).
  • Merck: 14,7648
  • Short: II/5
  • Short: III/29a
  • Short: II/25A

安全信息

GHS Symbol
WGK Germany1
Hazard Codes 5.1 O,Xi,Xn O
Hazard statements
  • H272 May intensify fire; oxidizer 可能加剧火势;氧化剂。
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Eyeshields, Gloves Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSTT3700000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P203
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P221 Take any precaution to avoid mixing with combustibles/… 采取一切防范措施,避免与可燃物混合/...
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P317
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P307+P311
  • P308+P313
  • P308+P316
  • P309+P311
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P318
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Safety Statements
  • S17 Keep away from combustible material 远离可燃物料;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S7 Keep container tightly closed 保存在严格密闭容器中;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S41 In case of fire and/or explosion do not breathe fumes 着火和/或爆炸时,不要吸入烟雾;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
UN Number UN 3264 8/PG 3 UN1486
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
  • R22 Harmful if swallowed 吞咽有害
Storage condition Store at RT. Hygroscopic 充氩保存 密封阴凉干燥保存。
Packing GroupIII
Hazard Class5.1
Restrict {} {} {} 易制爆危险化学品 易制爆
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Mammal - cat
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
   Ger. Dem. Rep.)  Volume(issue)/page/year: 4,1289,1935

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3750 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NYKZAU Nippon Yakurigaku Zasshi.  Japanese Journal of Pharmacology. (Nippon
   Yakuri Gakkai, c/o Kyoto Daigaku Igakubu Yakurigaku Kyoshitsu, Konoe-cho,
   Yoshida, Sakyo-ku, Kyoto 606, Japan) V.40-    1944- Volume(issue)/page/year:
   81,469,1983

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1901 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SOVEA7 Southwestern Veterinarian.  (College of Veterinary Medicine, Texas A
   & M Univ., College Station, TX 77843)  V.1-    1948-
   Volume(issue)/page/year: 27,246,1974

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 5 pph
REFERENCE :
   JGMIAN Journal of General Microbiology.  (Soc. for General Microbiology,
   Journal Sales, 62 London Rd., Reading, RG1 5AS, UK)  V.1-    1947-
   Volume(issue)/page/year: 8,45,1953

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 22 gm/kg
SEX/DURATION            : female 1-22 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - other measures of fertility
REFERENCE :
   JANSAG Journal of Animal Science.  (American Soc. of Animal Science, 309 W.
   Clark St., Champaign, IL 61820)  V.1-    1942-  Volume(issue)/page/year:
   15,1291,1956

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE                    : 6505 mg/kg
SEX/DURATION            : female 23-27 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - abortion
REFERENCE :
   SOVEA7 Southwestern Veterinarian.  (College of Veterinary Medicine, Texas A
   & M Univ., College Station, TX 77843)  V.1-    1948-
   Volume(issue)/page/year: 27,246,1974

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE                    : 15 gm/kg
SEX/DURATION            : female 24 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - stillbirth
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volum

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 598 mg/kg
SEX/DURATION            : female 1-22 day(s) after conception
                          lactating female 5 day(s) post-birth
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - behavioral
REFERENCE :
   APHHDU Acta Physiologica Hungarica.  (Kultura, POB 149, H-1389 Budapest,
   Hungary)  V.61-    1983-  Volume(issue)/page/year: 74,69,1989

其他信息

  • 类别:氧化剂
  • 图谱信息:硝酸钾(7757-79-1)红外图谱(IR1)
  • 上游原料:硝酸 --> 碳酸钾 --> 氢氧化钾 --> 氯化钠 --> 氯化铵 --> 碳酸氢铵 --> 氯化钾 --> 硝酸钠 --> 硝酸铵
  • 方法二:将硝酸钠和氯化钾溶于水进行复分解反应,有沉淀生成,过滤后蒸发浓缩;当溶液相对密度达1.45~1.49(45~48°Bé)、温度达119℃时,首先析出氯化钠;经真空过滤滤去氯化钠,滤液用10%~1
  • 下游产品:间硝基苯甲醛 --> 复合肥 --> 6-氨基-2-N-BOC-1,2,3,4-四氢-异喹啉 --> 钨酸钠 --> 4-乙烯基吡啶 --> 8-氨基异喹啉 --> 1-氟-4-(三氟甲基硫代)苯 --> 3,8-二氨基-5-甲基-6-苯基溴化菲啶盐 --> NPK复合肥 --> 硫酸庆大霉素 --> 8-溴异喹啉 --> 2-溴-5-甲基磺酰硝基苯 --> 3-硝基-4-甲基吡啶 --> 三氟羧草醚 --> 3-甲基-2,4-二氯-5-硝基苯甲酸 --> 2,4-二羟基-6-甲基-5-硝基嘧啶 --> 碘酸钙 --> 氨合成催化剂 --> 7-氨基异喹啉 --> 4-氨基-3-吡啶甲醛 --> 4-硝基喹啉-N-氧化物 --> 7-甲基腺嘌呤 --> 5-氯-1-甲基-4-硝基咪唑 --> 过碘酸钾 --> 1,2-二羟基蒽醌 --> 亚硝酸钾 --> 3-氨基-2-溴-4,6-二甲基吡啶 --> 6-氨基吲哚 --> 6-硝基吲哚 --> 2,3,5-三甲基-2,5-环己二烯-1,4-二酮 --> 3-氨基-4-硝基三氟甲苯 --> 异丙基磺酰氯 --> 氨合成铁系催化剂 --> 2,4-二甲基-5-氨基吡啶 --> 2,6-二硝基苯胺 --> 碘化银 --> NCY型乙苯脱氢催化剂
  • 用途六:硝酸钾也是我国允许使用的发色剂。它在肉制品中由于细菌作用而还原成亚硝酸钾而起护色和抑菌的作用。我国规定可用于肉类制品,最大使用量0.5g/kg,残留量不得超过0.03g/kg。
  • 灭火剂:雾状水
  • 外观性质:无色透明斜方或三方晶系颗粒或白色粉末。
  • 含量分析:精确称取试样约0.4g(预经105℃干燥4h),溶入盛于500ml圆底烧瓶中的300ml水中。加德瓦达合金粉3g和40%氢氧化钠溶液15ml后,将防溅球和冷凝器与烧瓶连接。在受器中放0.1mol/L硫酸50ml,静置2h,蒸馏,至馏出液250ml,用0.1mol/L氢氧化钠滴定过量硫酸,用3滴甲基红-亚甲蓝试液(TS-150)作为指示剂。同时进行空白试验,并作必要修正。每毫升0.1mol/L硫酸相当于硝酸钾(KNO 3 )10.11mg。
  • Alfa Aesar:硝酸钾,Puratronic|r,99.997%(metalsbasis) Potassium nitrate, Puratronic, 99.997% (metals basis)(7757-79-1)
  • 急性毒性:口服- 大鼠 LD50: 3750 毫克/ 公斤
  • 硝酸钾价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 10017218 硝酸钾(*)(易制爆) 500g 15.5元 2011/08/23 10017228 硝酸钾(*)(易制爆) 500g 14元 2011/08/23 K6002901 原子吸收钾标准溶液1000mg/L 100ml 138.0
  • 防护措施:在生产中吸入硝酸钾粉尘,经过数月之后则出现鼻粘膜溃疡。饮用含有50~100mg/L硝酸钾的水,血中变性血红蛋白明显升高。对皮肤有刺激作用。 生产人员在工作时要戴口罩,以防止吸入硝酸钾粉尘,保护呼吸器官;要穿工作服,戴乳胶手套等劳保用品,以保护皮肤。
  • 所属类别三:无机化工产品: 无机盐: Cl硝酸盐
  • 使用限量:FAO/WHO(1984,mg/kg):熟洋火腿、熟猪前腿肉,500;一般干酪50(单用或与硝酸钠合用量)。 GB 2760-2001:肉制品0.50g/kg。
  • 用途三:发色剂;抗微生物剂;防腐剂;护色剂。
  • Potassium nitrate is a naturally occur

系列性分类


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