CAS 102-82-9 MFCD00009431-Tributylamine (剧毒品，不能销售)三正丁胺 TAO{mole}

Tributylamine (剧毒品，不能销售)三正丁胺

CAS 102-82-9 MFCD00009431

化学结构图

SMILES: CCCCN(CCCC)CCCC

化学属性

Mol. Formula	[CH3(CH2)3]3N
Mol. Weight	185.35
Density	0.778 g/mL at 25 °C(lit.)
Refractive index	n20/D 1.428(lit.)
Autoignition Point	410 °F
Vapor Density	6.38 (vs air)
Boiling Point	216 °C(lit.)
Vapor Pressure	0.3 mmHg ( 20 °C)
Melting Point	-70 °C(lit.)
Flash Point	71°(159°F)
Solubility	不溶于水，溶于醇、醚。
TSCA	Yes
Stability	易吸潮

别名和识别编码

Chemical Name	Tributylamine
CAS Number	102-82-9
EC Number	203-058-7
Beilstein Registry Number	1698872
MDL Number	MFCD00009431
Synonym	ai3-15424 tris-n-butylamine 三丁胺, N,N-二丁基-1-丁胺,N,N-二丁基-1-丁胺,三正丁基胺 TRIBUTYLAMINE PURE Tributilamina TNBA N-Dibutyl-1-butanamine n,n-dibutyl-1-butanamin N,N-二丁基-1-丁胺 tributylamine tributylamine,[liquid] 三丁基胺三丁胺 Tris[N-butylamine] TRI-N-BUTYLAMINE Tri-n-butylamine 1-Butanamine,N,N-dibutyl- tris(1-butyl)amine tri(n-butyl)amine amine,tributyl Tris-n-butylamine tris(1n-butyl)amine (n-C4H9)3N 1-Butanamine, N,N-dibutyl- N,N-Dibutyl-1-butanamine N,N-DIBUTYL-1-BUTANAMINE 三丁胺;N,N-二丁基-1-丁胺;N,N-二丁基-1-丁胺;三正丁基胺三正丁基胺三正丁胺 TRIBUTYLAMINE TRIBUTYLAMINE REAGENTPLUSTM >=99% TBA
Merck Number	9618
PubChem Substance ID	57653405
Reaxys-RN	1698872
Chemical Name Translation	(剧毒品，不能销售)三正丁胺
Wiswesser Line Notation	4N4&4

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

生产医药、农药、染料、矿物浮选剂、乳化剂以及精细化学品的中间体等。

安全信息

Signal word Danger

GHS Symbol

WGK Germany3

Safety Statements

S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
S20 When using do not eat or drink 使用时，不得进食，饮水；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
S4 Keep away from living quarters 远离生活区；
S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；

Risk Statements

R51/53
R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R22 Harmful if swallowed 吞咽有害
R23/24 Toxic by inhalation and in contact with skin 吸入及皮肤接触都有毒
R24 Toxic in contact with skin 与皮肤接触有毒
R26 Very toxic by inhalation 吸入极毒
R38 Irritating to skin 刺激皮肤

Precautionary statements

P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P304+P340+P310
P273 Avoid release to the environment. 避免释放到环境中。
P304+P340
P302+P350
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P352
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P337+P313
P403+P233
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
P302+P352+P310
P301+P312+P330
P332+P313
P501 Dispose of contents/container to..… 处理内容物/容器.....
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
P301+P310+P330
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P405 Store locked up. 上锁保管。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。

RTECSYA0350000

Hazard Codes T+ T,N

UN Number 2542 UN2542 UN 2542 6.1/PG 2

Packing GroupII

Storage condition Store at RT. 充氩保存 Hygroscopic

Hazard statements

H310+H330
H315 Causes skin irritation 会刺激皮肤
H302 Harmful if swallowed 吞食有害
H227 Combustible liquid 可燃液体

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Class6.1

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 615 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 42(12),36,1977

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 107 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - excitement
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 28(11),50,1984

TYPE OF TEST            : LCL

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 114 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 42(12),36,1977

TYPE OF TEST            : LD50 - Lethal dose, 50 pe

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 888 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - excitement
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Z

Restrict 剧毒 {} 剧毒化学品

其他信息

无色至微黄色液体，有类似氨的气味,不溶于水，水中溶解度:0.386 g/l (25°C)；易吸湿。溶于大多数有机溶剂，极溶于醇、醚。
MSDS 信息:三正丁胺(102-82-9).msds
毒性分级:中毒
三正丁胺价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 81013227 三正丁胺 250ml 18.6元 2011/04/16 T0357 三丁胺 Tributylamine 25ML 102元 2011/04/16 T0357 三丁胺 Tributylamine 500ML 284元
图谱信息:三正丁胺(102-82-9)Raman光谱三正丁胺(102-82-9)红外图谱(IR1) 三正丁胺(102-82-9)质谱(MS) 三正丁胺(102-82-9)核磁图( 13 CNMR) 三正丁胺(102-82-9)红外图谱(IR2)
外观性质:无色液体，有类似氨的气味。
储运特性:库房通风低温干燥; 与酸、氧化剂分开存放
用途一:用作萃取剂和溶剂
TCI Shanghai:三丁胺 Tributylamine,>;98.0%(GC)(T)(102-82-9)
F:10
爆炸物危险特性:与空气混合可爆
MOL 文件:102-82-9.mol
海关编码:29211980
Alfa Aesar:三正丁基胺,98% Tri-n-butylamine, 98%(102-82-9)
用途三:全氟三丁胺、四丁基氯化铵、四丁基溴化铵等精细化学品的原料。
可燃性危险特性:可燃
Sigma Aldrich:102-82-9(sigmaaldrich)
灭火剂:干粉、二氧化碳、抗醇泡沫
敏感性:Hygroscopic
上游原料:正丁胺 --> 二正丁胺 --> 酸性白土
蒸气压:0.3 mm Hg ( 20 °C)
类别:腐蚀物品
下游产品:正丁胺 --> (1R,2R)-双[(2-甲氧基苯基)苯基磷]乙烷 --> 二正丁胺 --> 聚胞苷酸 --> 四丁基硫酸氢铵 --> 灭草松 --> 水胺硫磷 --> 异丙氧磷 --> 全氟三丁胺
Acros Organics:三丁胺 Tributylamine, 99%(102-82-9)
蒸气密度:6.38 (vs air)
急性毒性:口服-大鼠 LD50: 114 毫克/公斤; 口服-小鼠 LD50: 114 毫克/公斤
方法一:将丁醇、氨、氢气按配比通入填充铜镍酸性白土催化剂的反应塔中，在200℃左右反应，将反应气体冷凝，得到含一丁胺、二丁胺、三丁胺的混合物，通过精馏分离出三个产品。
用途四:生产医药、农药、染料、矿物浮选剂、乳化剂以及精细化学品的中间体等。
不溶于水，水中溶解度:0.386 g/l (25°C)；易吸湿。溶于大多数有机溶剂，极溶于醇、醚。
用途二:用于石油添加剂、溶剂、医药中间体、杀虫剂、乳化剂、塑料增塑剂、矿物浮选剂及表面活性剂等