CAS 109-92-2 MFCD00009248-Ethyl vinyl ether 乙烯基乙醚 TAO{mole}

Ethyl vinyl ether 乙烯基乙醚

CAS 109-92-2 MFCD00009248

化学结构图

SMILES: C=COCC

化学属性

Mol. Formula	C4H8O
Mol. Weight	72.11
Density	0.753 g/mL at 25 °C(lit.)
Refractive index	1.3750 to 1.3780
Boiling Point	36°C
Melting Point	-116 °C(lit.)
Flash Point	-45°C(lit.)
TSCA	Yes
Solubility	微溶于水，溶于丙酮、苯、四氯化碳等多数有机溶剂。
Stability	对热、空气敏感
pH	:A

别名和识别编码

Chemical Name	Ethyl vinyl ether
MDL Number	MFCD00009248
CAS Number	109-92-2
EC Number	203-718-4
Beilstein Registry Number	1,433
Synonym	1-Ethoxyethene 1-Ethoxyethylene 2-Ethoxyethylen Agrisynth EVE CH2=CHOC2H5 ETHOXYETHYLENE ETHYL VINYL ETHER EVE Ethene, ethoxy Ethene, ethoxy- Ethene,ethoxy- Ethenyl ethyl ether Ethenylethylether Ether, ethyl vinyl Ether, ethyl vinyl (inhibited) Ether, vinyl ethyl Ethoxyethene Ethoxyethylene Ethyl Vinyl Ether {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID	8023
Reaxys-RN	605351
Chemical Name Translation	乙烯基乙醚
Wiswesser Line Notation	2O1U1
LabNetwork Molecule ID	LN01287807
InChI	InChI=1S/C4H8O/c1-3-5-4-2/h3H,1,4H2,2H3

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产品应用

A useful vinyl ether for proteomics research and organic synthesis.

安全信息

Signal word Danger Warning

GHS Symbol

WGK Germany1

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S33 Take precautionary measures against static discharges 对静电采取预防措施；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S3/7 Keep container tightly closed in a cool place 将容器严格密闭保存在阴凉处；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S29 Do not empty into drains 不要排入下水道；
S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R12 Extremely flammable 极端易燃
R19 May form explosive peroxides 可能生成易爆的过氧化物质
R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥

Precautionary statements

P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P501 Dispose of contents/container to..… 处理内容物/容器.....
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P332+P313
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P337+P313
P302+P352+P332+P313+P362+P364
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P303+P361+P353
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H335 May cause respiratory irritation 可能导致呼吸道刺激
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H319 Causes serious eye irritation 严重刺激眼睛
H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)

RTECSKO0710000

Packing GroupI

UN Number 1302 UN 1302 3/PG 1 UN1302

Hazard Codes F;Xi F+,Xi,F F+,Xi

Storage condition +4°C 0-10 0-10°C 4 4℃ Refrigerator 储存温度2-8℃ 密封2-4℃保存。

Hazard Class3

Warnings 危化品目录(2015)

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 8160 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >20 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 11/15/1971

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 16000 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 31,343,1949

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 324 gm/m3/15M
TOXIC EFFECTS :
   Behavioral - general anesthetic
REFERENCE :
   ANESAV Anesthesiology.  (Lippincott/Harper, Journal Fulfillment Dept., 2350
   Virginia Ave., Hagerstown, MD 21740)  V.1-    1940- Volume(issue)/page/year:
   11,455,1950

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        :

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 17900 ppm
REFERENCE :
   ANESAV Anesthesiology.  (Lippincott/Harper, Journal Fulfillment Dept., 2350
   Virginia Ave., Hagerstown, MD 21740)  V.1-    1940- Volume(issue)/page/year:
   50,426,1979

Restrict 危险品

其他信息

乙烯基乙醚价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 E0193 乙烯基乙醚(含稳定剂氢氧化钾) Ethyl Vinyl Ether (stabilized with KOH) 50
下游产品:(1-甲基-3-三氟甲基-1H-吡唑-4-基)甲胺 --> 1-甲基-3-三氟甲基-1H-吡唑-4-羧酸 --> 1-苯基-3-三氟甲基-1H-吡唑-5-羧酸 --> 3-溴-7-(三氟甲基)咪唑并[1,2-a]嘧啶 --> (1-叔丁基-3-三氟甲基-1H-吡唑-4-基)甲醇 --> (1-甲基-3-三氟甲基-1H-吡唑-4-基)甲醇 --> 1-甲基-3-三氟甲基-1H-吡唑-4-胺 --> 1-叔丁基-3-三氟甲基-1H-吡唑-4-胺 --> 1-甲基-3-三氟甲基-1H-吡唑-4-羧酸乙酯 --> 1-叔丁基-3-三氟甲基-1H-吡唑-4-羧酸乙酯 --> 1-苯基-3-三氟甲基-4-溴-1H-吡唑 --> 1-叔丁基-3-三氟甲基-1H-吡唑-4-羧酸 --> 2-肼基-4-三氟甲基嘧啶 --> 1-苯基-3-三氟甲基吡唑 --> 2-甲基-5-三氟甲基-2H-吡唑-3-羧酸 --> 2-氯-4-三氟甲基嘧啶 --> 米力农 --> 1-叔丁基-3-三氟甲基-1H-吡唑-5-羧酸 --> 1-苯基-5-三氟甲基-1H-吡唑-4-醛 --> 1-甲基-3-三氟甲基-4-溴-1H-吡唑 --> 磺胺嘧啶 --> 1-叔丁基-3-三氟甲基-4-溴-1H-吡唑 --> 戊二醛 --> 3-氯-5-氟苯胺 --> 1-甲基-3-三氟甲基-1H-吡唑 --> 1-苯基-5-三氟甲基-4-溴-1H-吡唑 --> 1-甲基
TCI Shanghai:乙烯基乙醚(含
{
检测方法:GC
海关编码:29091900
乙烯基乙醚价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 E0193 乙烯基乙醚(含稳定剂氢氧化钾) Ethyl Vinyl Ether (stabilized with KOH) 500ML 550元 2014/06/02 E0193 乙烯基乙醚(含稳定剂氢氧化钾) Ethyl Vinyl Ether (s
MOL 文件:109-92-2.mol
Sigma Aldrich:109-92-2(sigma
{Chemica
刺激数据:皮肤- 兔子 500 毫克轻度
MSDS 信息:乙烯基乙醚(109-92-2).msds
Acros Organics:乙烯基乙基醚 Ethyl vinyl ether, stabi
爆炸物危险特性:与空气混合可爆
类别:易燃液体
图谱信息:乙烯基乙醚(109-92-2)Raman光谱乙烯基乙醚(109-92-2)红外图谱(IR2) 乙烯基乙醚(109-92-2)核磁图( 13 CNMR) 乙烯基乙醚(109-92-2)质谱(MS) 乙烯基乙醚(109-92-2)核磁图( 1 HNMR) 乙烯基乙醚(109-92-2)红外图谱(IR1)
用途一:医药上用作麻醉剂、镇痛剂，也用作精细化学品的中间体
用途一
可燃性危险特
方法一:由电石发生乙炔，乙炔再与乙醇在氢氧化钾催化剂存在下，经加压反应制得。
乙烯基乙醚价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 E0193 乙烯基乙醚(含稳定剂氢氧化钾) Ethyl Vinyl Ether (stabilized with KOH) 500ML 550元 2014/06/02 E0193 乙烯基乙醚(含稳定剂氢氧化钾) Ethyl Vinyl Ether (stabilized with KOH) 25ML 175元 2010/06/21 119080010 乙烯基乙醚 Ethyl vinyl ether 99%, stabilized 1 LT 671元
图谱信息:乙烯基乙醚(109-92-2)Raman光谱乙烯基乙