CAS 563-80-4 MFCD00008919-3-Methyl-2-butanone 3-甲基-2-丁酮 TAO{mole}

3-Methyl-2-butanone 3-甲基-2-丁酮

CAS 563-80-4 MFCD00008919

化学结构图

SMILES: CC(=O)C(C)C

化学属性

Mol. Formula	C5H10O
Mol. Weight	86.13
Refractive index	1.3860 to 1.3900
Boiling Point	94-95
Density	0.805
Melting Point	-92
Flash Point	1°C(lit.)
TSCA	Yes
Solubility	溶于多数有机溶剂。

别名和识别编码

Chemical Name	3-Methyl-2-butanone
Synonym	2-Acetylpropane 2-isopentanone 3-Methylbutan-2-on 3-Methylbutan-2-one 3-Methylbutanone 3-methyl-2-butanone 3-methyl-butan-2-one 3-methylbutanone 3-甲-2-丁酮 3-甲基-2-丁酮 3-甲基丁酮 ISOPROPYL METHYL KETONE Isobutyl-1-methylketone Isopropyl methyl ketone; Methyl isopropyl ketone; MIPK Isopropyl-methylketon METHYL ISOPROPYL KETONE MIPK Methyl butanone-2 Methyl isopropyl ketone Methyl-iso-propyl ketone Methylisopropylketon iso-C3H7COCH3 iso-Propylmethyldetone isopropyl methyl ketone methyl(isopropyl) ketone {} {} {} {LY} 2-Acetylpropane {} {} {} {} {LY} 2-Acetylpropane {} {} {} {} {} { {} {} {} {} {} {LY} 2-Acetylpropane {} {} {} {} {} {} {LY} 2
CAS Number	563-80-4
PubChem Substance ID	11251
EC Number	209-264-3
Beilstein Registry Number	1071238
MDL Number	MFCD00008919
Reaxys-RN	1071238
Merck Number	6090
Chemical Name Translation	3-甲基-2-丁酮
Wiswesser Line Notation	1Y1&V1
LabNetwork Molecule ID	LN00224526
InChI	InChI=1S/C5H10O/c1-4(2)5(3)6/h4H,1-3H3
Canonical SMILES	CC(C(C)C)=O

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

溶剂。有机合成。塑料工业。

安全信息

GHS Symbol

WGK Germany1

Hazard statements

H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H319 Causes serious eye irritation 严重刺激眼睛
H332 Harmful if inhaled 吸入有害
H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes F

RTECSEL9100000

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P203
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P242 Use only non-sparking tools. 只能使用无火花工具。
P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P301+P310
P301+P316
P301+P317
P302+P352
P303+P361+P353
P304+P312
P304+P317
P304+P340
P305+P351+P338
P305+P351+P338+P337
P308+P313
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P317
P318
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P331 Do NOT induce vomiting.. 不要催吐。
P332+P313
P332+P317
P337+P313
P337+P317
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P370+P378
P403+P233
P403+P235
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word

Safety Statements

S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
S33 Take precautionary measures against static discharges 对静电采取预防措施；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；

Risk Statements

UN Number

Packing GroupII

Storage condition 2-8°C {LY} 2-8°C Flammables area {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

Hazard Class3

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 148 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SCCUR* Shell Chemical Company.  Unpublished Report.  (2401 Crow Canyon Rd.,
   San Romon, CA 94583)  Volume(issue)/page/year: -,7,1961

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton,
   G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82.
   Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985.
   Volume(issue)/page/year: 2C,4737,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 6350 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 16,819,1978

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5700 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 12300 ppm
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 149,339,1985

其他信息

毒性分级:中毒
Hazard Note:Highly Flammable
3-甲基-2-丁酮价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 M0173 3-甲基-2-丁酮 3-Methyl-2-butanone 25ML 104元 2014/06/02 M0173 3-甲基-2-丁酮 3-Methyl-2-butanone 500ML 445元 2010/06/21 218772500 3-甲基-2-丁酮 3-Methyl-2-butanone 98% 250 ML 461元
有丙酮气味。易溶于乙醇和乙醚，极微溶于水。易燃。中等毒，半数致死量（大鼠，经口）148mg/kg。有刺激性。
灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
爆炸物危险特性:与空气混合可爆
Sigma Aldrich:563-80-4(sigmaaldrich)
外观性质:无色液体。
类别:易燃液体
急性毒性:腹腔-大鼠 LD50: 800 毫克/ 公斤; 口服-小鼠 LD50: 2572 毫克/ 公斤
海关编码:29141990
MOL 文件:563-80-4.mol
用途二:用作溶剂，也用于塑料及有机合成
Acros Organics:甲基异丙基甲酮/3-甲基-2-丁酮 3-Methyl-2-butanone, 98%(563-80-4)
职业标准:TWA 705 毫克/立方米； STEL 880 毫克/立方米
MSDS 信息:3-甲基丁酮(563-80-4).msds
刺激数据:皮肤- 兔子 500 毫克/24小时中度; 眼睛- 兔子 500 毫克/24小时轻度
Alfa Aesar:3-甲基-2-丁酮,98% 3-Methyl-2-butanone, 98%(563-80-4)
可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生刺激烟雾
方法一:向50-60℃的叔戊醇中滴加等摩尔的溴，制得2，3-二溴异戊烷，然后加水回流3-5h至水解完全，从反应混合物中蒸出粗品3-甲基-2-丁酮，经精制得到成品，收率59%。
用途一:主要用作染料中间体，并可用于医药、农药、纺织、油漆、选矿等行业
储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
TCI Shanghai:3-甲基-2-丁酮 3-Methyl-2-butanone,>;99.0%(GC)(563-80-4)
上游原料:氧 --> 异丁醛 --> 2-甲基-2-丁醇 --> 2,3-二溴-2-甲基丁烷
图谱信息:3-甲基-2-丁酮(563-80-4)红外图谱(IR1) 3-甲基-2-丁酮(563-80-4)质谱(MS) 3-甲基-2-丁酮(563-80-4)红外图谱(IR2) 3-甲基-2-丁酮(563-80-4)核磁图( 13 CNMR) 3-甲基-2-丁酮(563-80-4)核磁图( 1 HNMR) 3-甲基-2-丁酮(563-80-4)Raman光谱
下游产品:灭草喹 --> 螺[1,3,3-三甲基吲哚-苯并二氢吡喃] --> 2,6-二甲基-3,5-庚二酮 --> 1,2,5-氧恶唑-3-羧酸 --> 3-甲基-1,2,5-噁二唑 --> 甲氧咪草烟 --> 2-氨基-2,3-二甲基丁腈
用途三:溶剂。有机合成。塑料工业。