1,1-Dimethoxy-N,N-dimethylethanamine N,N-二甲基乙酰胺二甲缩醛
CAS 18871-66-4 MFCD00008476
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- {SNA} Acetals/Ketals/Ortho Esters, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds
- {SA} Acetals/Ketals/Ortho Esters, Alphabetic, Analytical Standards, Analytical/Chromatography, Building Blocks, Chemical Synthesis, D, DID - DIN, Organic Building Blocks, Oxygen Compounds
- {SNA} Alphabetical Index of Analytical Standards, Acetals/Ketals/Ortho Esters, Analytical Standards, Analytical/Chromatography, Building Blocks, Chemical Synthesis, D, DID - DIN, Organic Building Blocks, Oxygen Compounds
相关文献及参考
- Reacts with active methylene compounds to give the (dimethylamino)ethylidene derivatives: Liebigs Ann. Chem., 641, 1 (1961), compare N,N-Dimethylformamide dimethyl acetal, A15350.
- For use in the N-acetylation of amides to give diacylamines (imides) in high yield, see: Synthesis, 119 (1980).
- Reacts with 1,2-diols, e.g. sugars, to form 1-(dimethylamino)ethylidene cyclic acetals which can be cleaved with aqueous AcOH, giving the monoacetate of the less hindered OH, thus providing a method for selective monoprotection of the diol: Can. J. Chem., 50, 233 (1972).
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H331 Toxic if inhaled 吸入中毒
- H311 Toxic in contact with skin 皮肤接触中毒
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H319 Causes serious eye irritation 严重刺激眼睛
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H371 May cause damage to organs 可能导致器官损伤
- H302 Harmful if swallowed 吞食有害
- H311+H331
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P304+P340+P312
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P370+P378
- P302+P352+P312
- P403+P235
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P337+P313
- P403+P233
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P303+P361+P353
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P304+P340
- P308+P313
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
- P233 Keep container tightly closed. ?保持容器密闭。
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S33 Take precautionary measures against static discharges 对静电采取预防措施;
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R68/20/21/22
- R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R11 Highly flammable 非常易燃
其他信息
- F:8-10-21
- 1,1-二甲氧基-N,N-二甲基乙胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D1652 N,N-二甲基乙酰胺二甲基缩醛(含稳定剂5-10%的甲醇) N,N-Dimethylacetamide Dimethyl Acetal (stabilized with 5-10% Methanol) 25ML 731元 2010/06/21 407940050 1,1-二甲氧基-N,N-二甲基乙胺 N,N-Dimethylacetamide dimethyl acetal 85%, tech. 5 GR 564元 2010/06/21 264130250 1,1-二甲氧基-N,N-二甲基乙胺 N,N-Dimethylacetamide dimethyl acetal 98% 25 GR 1569元
- TCI Shanghai:N,N-二甲基乙酰胺二甲基缩醛 N,N-Dimethylacetamide Dimethyl Acetal (stabilized with 5-10% Methanol),>;90.0%(T)(18871-66-4)
- MOL 文件:18871-66-4.mol
- Sigma Aldrich:18871-66-4(sigmaaldrich)
- 存储注意事项:湿度敏感
- MSDS 信息:1,1-Dimethoxyethyl(dimethyl)amine(18871-66-4).msds
- Acros Organics:N,N-二甲基乙酰胺二甲缩醛 N,N-Dimethylacetamide dimethyl acetal, 98%(18871-66-4)
- 检测方法:T
- 敏感性:Moisture Sensitive
- 用途一:用作药物扎来普隆中间体
- Alfa Aesar:N,N-二甲基胺乙酰缩二甲醇,tech.90%,stab.with5-10%methanol N,N-Dimethylacetamide dimethyl acetal, tech. 90%, stab with 5-10% methanol(18871-66-4)