CAS 109-76-2 MFCD00008228-1,3-Diaminopropane 1,3-丙二胺 TAO{mole}

1,3-Diaminopropane 1,3-丙二胺

CAS 109-76-2 MFCD00008228

化学结构图

SMILES: NCCCN

化学属性

Mol. Formula	C3H10N2
Mol. Weight	74.13
Refractive index	1.4560 to 1.4600
Boiling Point	133°C(lit.)
Density	0.888 g/mL at 25 °C(lit.)
Melting Point	-12 °C(lit.)
Flash Point	48.89°C
TSCA	Yes
Autoignition Point	662 °F
Vapor Pressure	<;8 mmHg ( 20 °C)
Solubility	易溶于水，溶于甲醇、乙醚。
Stability	对光线和空气敏感,易吸湿

别名和识别编码

Chemical Name	1,3-Diaminopropane
Synonym	1,3-Diaminopropane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number	109-76-2
PubChem Substance ID	428
EC Number	203-702-7
Beilstein Registry Number	4,261
MDL Number	MFCD00008228
Reaxys-RN	605277
Chemical Name Translation	1,3-丙二胺
Wiswesser Line Notation	Z3Z
LabNetwork Molecule ID	LN00193032
InChI	InChI=1S/C3H10N2/c4-2-1-3-5/h1-5H2
Canonical SMILES	NCCCN

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

溶剂。净化剂。有机合成中间体，KAPA制备的起始材料，分子末端异构化用强碱基。

安全信息

GHS Symbol

WGK Germany2

Hazard Codes T;C T,C

Hazard statements

H226 Flammable liquid and vapour 易燃液体和蒸气
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H310 Fatal in contact with skin 皮肤接触致命
H302 Harmful if swallowed 吞食有害

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSTX6825000

Precautionary statements

P501 Dispose of contents/container to..… 处理内容物/容器.....
P304+P340+P310
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338+P310
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P301+P330+P331+P310
P303+P361+P353
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P304+P340
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P403+P235
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P273 Avoid release to the environment. 避免释放到环境中。
P241+P242+P243
P303+P361+P353+P310+P363
P405 Store locked up. 上锁保管。
P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
P233 Keep container tightly closed. ?保持容器密闭。

Signal word Danger {} {} {} {} {} {} {TCI}

UN Number UN 2922 8/PG 2 2734 UN2734 2258/2922

Risk Statements

R35 Causes severe burns 会导致严重灼伤
R24 Toxic in contact with skin 与皮肤接触有毒
R22 Harmful if swallowed 吞咽有害
R10 Flammable 易燃

Safety Statements

S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S25 Avoid contact with eyes 避免眼睛接触；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {Chemicalbook} Flammables area {} {} {} {} {} {} {} {} {} {ALF} Air Sensitive {} {} {} {} {} {} {} {} {} {} {LY} 20℃ {} {} {} {} {} {} {} {} {} {} {} {LY} 20 {} {} {} {} {} {} {} {} {} {} {} {} {LY} +20°C 密封阴凉干燥避光保存。

Packing GroupII

Hazard Class8/3

Warnings 危化品目录(2015)

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 200 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 296 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   YKKZAJ Yakugaku Zasshi.  Journal of Pharmacy.  (Nippon Yakugakkai, 2-12-15
   Shibuya, Shibuya-ku, Tokyo 150, Japan)  No.1-    1881-
   Volume(issue)/page/year: 97,1117,1977

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 350 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 264 mg/kg
SEX/DURATION            : female 12 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Effects on Embryo or Fetus - other effects to embryo
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 28,237,1983

Restrict 危险品

其他信息

上游原料:乙醇溶液 --> 1,2-二溴丙烷
图谱信息:1,3-丙二胺(109-76-2)Raman光谱 1,3-丙二胺(109-76-2)核磁图( 13 CNMR) 1,3-丙二胺(109-76-2)质谱(MS) 1,3-丙二胺(109-76-2)核磁图( 1 HNMR) 1,3-丙二胺(109-76-2)红外图谱(IR1)
1,3-丙二胺价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 AD2360201 1,3-丙二胺;1,3-二氨基丙烷; 三亚甲二胺; 1,3-亚丙基二胺 25g 325元 2011/08/23 AD2360202 1,3-丙二胺;1,3-二氨基丙烷; 三亚甲二胺; 1,3-亚丙基二胺 500g 865元 2011/08/23 K3325001 1.3-丙二胺 100ml 290元
灭火剂:泡沫、干粉、二氧化碳、砂土
用途一:用于医药、农药的合成，是造纸、纺织、皮革工业的辅助原料，还用于环氧树脂固化剂的合成
F:34
下游产品:高哌嗪 --> 环庚草醚 --> N-叔丁氧羰基-1,2-乙二胺 --> N-叔丁氧羰基-1,3-丙二胺 --> 椰油酰胺基丙基甜菜碱 --> N,N-二羟乙基,N-对十八烷基苯磺酰胺丙基铵基丙磺酸盐
可燃性危险特性:遇明火、高温、强氧化剂可燃; 受热分解出有毒氧化氮气体
Acros Organics:1,3-二氨基丙烷 1,3-Diaminopropane, 99%(109-76-2)
MSDS 信息:1,3-丙二胺(109-76-2).msds
有氨的气味。有吸湿性。易吸收二氧化碳。能与水、乙醇、乙醚、氯仿、苯混溶，溶于甲醇。
急性毒性:口服- 大鼠 LD50: 350 毫克/ 公斤; 腹注- 小鼠 LD50: 296 毫克/ 公斤
类别:可燃物品
刺激数据:皮肤- 兔子 50 毫克重度; 眼- 兔子 1 毫克重度
TCI Shanghai:1,3-丙二胺 1,3-Diaminopropane,>;98.0%(GC)(109-76-2)
用途三:溶剂。净化剂。有机合成中间体，KAPA制备的起始材料，分子末端异构化用强碱基。
Alfa Aesar:1，3-二氨基丙烷,98% 1,3-Diaminopropane, 98%(109-76-2)
MOL 文件:109-76-2.mol
Sigma Aldrich:109-76-2(sigmaaldrich)
方法一:将1份二溴丙烷与8-9份在0℃饱和氨和乙醇溶液混溶，放置3-4d。蒸干，剩余物加碱液后蒸馏。馏出物用盐酸中和。蒸浓，冷却，将浓缩液干燥使盐酸盐结晶析出。用碱分解盐酸盐，蒸馏出1,3-丙二胺。
毒性分级:高毒
敏感性:Air Sensitive
用途二:用作净化剂、有机合成中间体。
外观性质:水白色液体，有氨的气味。
储运特性:包装完整、轻装轻卸; 库房通风、远离明火、高温、与氧化剂、酸分开存放
蒸气压:<;8 mm Hg ( 20 °C)
海关编码:29212900