CAS 137-07-5 MFCD00007702-2-Aminobenzenethiol 2-氨基苯硫醇 TAO{mole}

2-Aminobenzenethiol 2-氨基苯硫醇

CAS 137-07-5 MFCD00007702

化学结构图

SMILES: Nc1ccccc1S

化学属性

Mol. Formula	C6H7NS
Mol. Weight	125.19
Density	1.17
Refractive index	1.6400 to 1.6450
Boiling Point
Melting Point	No Data Available
Flash Point	79.44°C
TSCA	Yes
Solubility	不溶
Stability	对空气敏感

别名和识别编码

Chemical Name	2-Aminobenzenethiol
CAS Number	137-07-5
Synonym	2-Aminothiophenol 90% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number	205-277-3
Beilstein Registry Number	606076
MDL Number	MFCD00007702
PubChem Substance ID	87561922
Reaxys-RN	606076
Chemical Name Translation	2-氨基苯硫醇
InChIKey	VRVRGVPWCUEOGV-UHFFFAOYSA-N
Wiswesser Line Notation	ZR BSH
LabNetwork Molecule ID	LN00008094
Canonical SMILES	SC1=CC=CC=C1N

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产品应用

磷地尔的中间体。

安全信息

Signal word Danger

GHS Symbol

WGK Germany3

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Risk Statements

R22 Harmful if swallowed 吞咽有害
R34 Causes burns 会导致灼伤
R50/53

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P330+P331+P310
P303+P361+P353
P305+P351+P338
P305+P351+P338+P310
P308+P313
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H302 Harmful if swallowed 吞食有害
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSDC0600000

Packing GroupIII

UN Number 1760 3267

Storage condition -20 -20°C -20℃ Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

Hazard Codes 8 C,N

Hazard Class8

Warnings 危化品目录(2015)

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Blood - methemoglobinemia-carboxyhemoglobin
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,90,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 25 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02532

Restrict 危险品

其他信息

2-氨基苯硫醇价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 A0267 2-氨基苯硫酚 2-Aminobenzenethiol 500ML 1600元 2014/06/02 A0267 2-氨基苯硫酚 2-Aminobenzenethiol 25ML 284元 2010/06/21 153901000 2-氨基苯硫醇 2-Aminothiophenol 98% 100 GR 449元
Hazard Note:Corrosive/Stench
储运特性:库房通风低温干燥; 与食品、酸类、氧化剂分开储运
2-氨基苯硫醇价格(试剂级):更新日期产品编号产品名称包装价格 2011/04/16 A0267 2-氨基苯硫酚 2-Aminobenzenethiol 500ML 1310元 2011/04/16 A0267 2-氨基苯硫酚 2-Aminobenzenethiol 25ML 234元 2010/06/21 153901000 2-氨基苯硫醇 2-Aminothiophenol 98% 100 GR 449元
敏感性:Stench
灭火剂:泡沫、干粉、二氧化碳
类别:有毒物品
Alfa Aesar:2-氨基硫代苯酚,98% 2-Aminothiophenol, 98%(137-07-5)
下游产品:2-巯基苯并噻唑 --> C545T --> 香豆素 6 --> 1,3-苯并噻唑-2-羰酰氯 --> 溶剂黄 98 --> 2-(4-甲基苯基)苯并噻唑 --> 盐酸地尔硫卓 --> 溶剂橙 63 --> 1,3-苯并噻唑-2-羧酸乙酯
海关编码:29309070
不溶于水，溶于大多数有机溶剂。
上游原料:硫化钠 --> 邻氯硝基苯 --> 二硫化钼
急性毒性:口服-大鼠 LDL0: 500 毫克/ 公斤; 腹腔- 小鼠 LD50: 25 毫克/ 公斤
F:9-13-23
MSDS 信息:邻氨基苯硫酚(137-07-5).msds
MOL 文件:137-07-5.mol
方法一:用邻硝基氯苯与硫化钠反应，生成的二硫化物经还原制得该品。
毒性分级:高毒
TCI Shanghai:2-氨基苯硫酚 2-Aminobenzenethiol,>;95.0%(GC)(137-07-5)
用途一:磷地尔的中间体。
Sigma Aldrich:137-07-5(sigmaaldrich)
图谱信息:2-氨基苯硫醇(137-07-5)核磁图( 13 CNMR) 2-氨基苯硫醇(137-07-5)质谱(MS) 2-氨基苯硫醇(137-07-5)红外图谱(IR1) 2-氨基苯硫醇(137-07-5)核磁图( 1 HNMR)
Acros Organics:邻氨基硫代苯酚 2-Aminothiophenol, 98%(137-07-5)
外观性质:淡黄色液体或固体，有恶臭味。
可燃性危险特性:明火可燃; 遇热放出有毒氧化硫、氧化氮气体