2-Thioxothiazolidin-4-one 2-硫代噻唑烷-4-酮

CAS 141-84-4 MFCD00005488

化学结构图

141-84-4
SMILES: O=C1CSC(=S)N1

化学属性

Mol. FormulaC3H3NOS2
Mol. Weight133.19
Density1.59
Melting Point165-169°C
TSCAYes
Solubility溶于热水
Stability对湿度敏感

别名和识别编码

Chemical Name2-Thioxothiazolidin-4-one
CAS Number141-84-4
Alfabeta NameTHIOXOTHIAZOLIDINONE 2134-----,
MDL NumberMFCD00005488
Synonym Rhodanine {LY} Rhodanine {} {LY} Rhodanine {} {} {LY} Rhodanine {} {} {} {LY} Rhodanine {} {} {} {} {LY} Rhodanine {} {} {} {} {} {LY} Rhodanine {} {} {} {} {} {} {LY} Rhodanine {} {} {} {} {} {} {} {LY} Rhodanine {} {} {} {} {} {} {} {} {LY} Rhodanine {} {} {} {} {} {} {} {} {} {LY} Rhodanine {} {} {} {} {} {} {} {} {} {} {LY} Rhodanine {} {} {} {} {} {} {} {} {} {} {} {LY} Rhodanine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Rhodanine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Rhodanine {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Rhodanine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Rhodanine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Rhodanine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Rhodanine {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number205-505-1
Beilstein Registry Number27,242
PubChem Substance ID87575596
Merck Number8184
Reaxys-RN110701
Chemical Name Translation2-硫代噻唑烷-4-酮
Wiswesser Line NotationT5SYMV EHJ BUS
LabNetwork Molecule IDLN00139069
InChIInChI=1S/C3H3NOS2/c5-2-1-7-3(6)4-2/h1H2,(H,4,5,6)
Canonical SMILESO=C1NC(SC1)=S
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分类

  • {SNA} Building Blocks, C3 to C7, Chemical Synthesis, Heterocyclic Building Blocks, Thiazoles
  • {SNA} Gravimetric Reagents, Spectroscopy, UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy, 分析/色谱, 分析试剂
  • {SNA} Analytical Reagents, Analytical/Chromatography, Gravimetric Reagents, Spectroscopy, UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy
  • {uni_hamburg} no charge; sulfur heterocycle; nitrogen heterocycle; alicycle; 5ring; amide; lactame; 1fragment

产品应用

  • 检定和重量分析测定银,光谱测定没食子酸。有机合成,制造苯丙氨酸。

相关文献及参考

  • Reagent for Ag and Au.
  • Merck: 14,8184
  • Short: EINECS
  • Short: III/5a
  • Merck: 14,8184 Beilstein:27,242

安全信息

Warnings IRRITANT
Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P301+P312
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P332+P313
  • P301+P312+P330
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P305+P351+P338+P310
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H318 Causes serious eye damage 严重伤害眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RTECSVI7700000
Hazard Codes Xn
Storage condition -20°C {LY} -20°C {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Packing GroupIII
Hazard Class6.1(a)
UN Number
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 32 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#04798

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 225 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FRZKAP Farmatsevtichnii Zhurnal (Kiev).  (V/O Mezhdunarodnaya Kniga, 113095
   Moscow, USSR) V.3-    1930-  Volume(issue)/page/year: 17(1),36,1962

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 320 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1093,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        :

其他信息

  • TCI Shanghai:绕丹宁 Rhodanine,>;99.0%(T)(141-84-4)
  • 外观性质:浅黄色结晶。易溶于沸水、乙醇、乙醚、甲醇、氨、二甲基甲酰胺和热乙酸。中等毒,半数致死量(大鼠,经口)326mg/kg。有刺激性。熔点:165-169 °C
  • 易溶于沸水、乙醇、乙醚、甲醇、氨、二甲基甲酰胺和热乙酸。中等毒,半数致死量(大鼠,经口)326mg/kg。有刺激性。
  • MOL 文件:141-84-4.mol
  • Sigma Aldrich:141-84-4(sigmaaldrich)
  • MSDS 信息:2-Thio-2,4-thiazolidinedione(141-84-4).msds
  • 海关编码:29341000
  • Acros Organics:罗丹宁 Rhodanine, 99%(141-84-4)
  • Alfa Aesar:罗丹宁,98+% Rhodanine, 98+%(141-84-4)
  • 图谱信息:罗丹宁(141-84-4)质谱(MS) 罗丹宁(141-84-4)红外图谱(IR1) 罗丹宁(141-84-4)红外图谱(IR2)
  • 罗丹宁价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30162660 罗丹宁;银试剂;罗丹酸;2-硫代-4-噻唑烷酮 25g 29.3元 2011/04/16 R0017 绕丹宁 Rhodanine 500G 6030元 2011/04/16 R0017 绕丹宁 Rhodanine 25G 603元
  • 用途一:检定和重量分析测定银。有机合成,制造苯丙氨酸。

系列性分类