Aluminium Tribromide 溴化铝
CAS 7727-15-3 MFCD00003421
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分类
- {SA} Al, Aluminum, Aluminum Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Crystal Grade Inorganics, Lewis Acids, Materials Science, Metal and Ceramic Science, Salts, Synthetic Reagents, Ultra-High Purity Materials
- {SNA} Acids, Acids & Bases, Al, Aluminum, Aluminum Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Crystal Grade Inorganics, Essential Chemicals, Lewis Acids, Materials Science, Metal and Ceramic Science, Research Essentials,
- {SNA} Acids, Ac
产品应用
- 用作分析试剂、有机合成异构化的催化剂
相关文献及参考
- Merck: 14,332
- Short: III/20a
- Short: III/20b
- Short: III/31b
安全信息
GHS Symbol
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
- R14 Reacts violently with water 遇水会猛烈反应
- R22 Harmful if swallowed 吞咽有害
- R34 Causes burns 会导致灼伤
- R11 Highly flammable 非常易燃
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
- R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
- R50/53
- P303+P361+P353+P310+P363
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P301+P330+P331
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P405 Store locked up. 上锁保管。
- P304+P340
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P304+P340+P310
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H332 Harmful if inhaled 吸入有害
- H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
- H302 Harmful if swallowed 吞食有害
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1598 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : PHTOEH Pharmacology and Toxicology (Copenhagen). (Munksgaard International Pub., POB 2148, DK-1016 Copenhagen K, Denmark) V.60- 1987- Volume(issue)/page/year: 60,280,1987
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 815 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : PHTOEH Pharmacology and Toxicology (Copenhagen). (Munksgaard International Pub., POB 2148, DK-1016 Copenhagen K, Denmark) V.60- 1987- Volume(issue)/page/year: 60,280,1987
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1068 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : PHTOEH Pharmacology and Toxicology (Copenhagen). (Munksgaard International Pub., POB 2148, DK-1016 Copenhagen K, Denmark) V.60- 1987- Volume(issue)/page/year: 60,280,1987
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1623 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : PHTOEH Pharmacology and Toxicology (Copenhagen). (Munksgaard International Pub., POB 2148, DK-1016 Copenhagen K, Denmark) V.60- 1987- Volume(issue)/page/year: 60,280,1987
其他信息
- 用途四:用作分析试剂、有机合成异构化的催化剂
- 上游原料:氢氧化铝
- 毒性分级:中毒
- 爆炸物危险特性:遇水可爆
- Hazard Note:Irritant
- 用途一:用作分析试剂、异构化的催化剂
- 用途二:用作橡胶的热软化剂、有机合成异构化催化剂,可用于生产氢化铝锂
- 外观性质:白色或淡黄色片状或块状固体,易潮解。
- 灭火剂:干砂、干石粉; 禁止用水
- 用途三:用作有机合成催化剂。溴化剂。分析试剂,异构化的催化剂。用于橡胶工业。
- 海关编码:28275900
- 三溴化铝价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 198410250 三溴化铝 Aluminium bromide 98+%, extra pure, anhydrous 25 GR 388元 2010/06/21 198411000 三溴化铝 Aluminium bromide 98+%, extra pure, anhydrous 100 GR 1048元 2010/05/25 89065 Aluminum bromide, 99.997% (metals basis) 5g 461元
- 易潮解。和水反应,易溶于乙醇、乙醚、二硫化碳、苯、甲苯、硝基苯和二甲苯
- 参考质量标准:企业标准 沪Q/HG 22-674-67 指标名称 指标(试剂级) 溴化铝含量/%≥ 95 水不溶物/%≤ 0.05 铁(Fe)/%\≤ 0.01 硫酸盐(SO4 2- )/%≤ 0.1 重金属(Pb)/%≤ 0.005 碱土金属/%≤ 0.5 酸度/%≤ 0.4
- 类别:腐蚀物品
- 储运特性:库房通风低温干燥; 与碱类、易燃物分开存放
- 职业标准:TLV-TWA 2 毫克(铝)/立方米
- 下游产品:4-硝基儿茶酚
- 蒸气压:1 mm Hg ( 81.3 °C)
- 可燃性危险特性:在湿气中冒烟; 遇水发热至爆炸; 受热分解有毒溴化物和氧化铝烟雾
- 毒性:有毒性及腐蚀性。经口或吸人会中毒。与水剧烈反应释出刺激性和腐蚀性的气体,能严重刺激眼睛、黏膜、皮肤和呼吸系统。应使吸人蒸气的患者脱离污染区,安置休息并保暖。眼睛受刺激用水冲洗,皮肤接触用水冲洗;误服立即漱口,急送医院救治。操作人员必须穿戴全身耐酸防护用品。对泄漏物处理,用干砂混合,送到空旷地方,分批逐渐倒入水中经稀释的污水放入废水系统。
- F:21
- Sigma Aldrich:7727-15-3(sigmaaldrich)
- Alfa Aesar:溴化铝,半干,99.999%(metalsbasis) Aluminum bromide, ultra dry, 99.999% (metals basis)(7727-15-3)
- Acros Organics:无水溴化铝 Aluminium bromide, anhydrous, extra pure, 98+%(7727-15-3)
- MOL 文件:7727-15-3.mol
- 急性毒性:口服-大鼠 LD50: 1598 毫克/公斤; 口服-小鼠 LD50: 1623 毫克/公斤
- MSDS 信息:三溴化铝(无水)(7727-15-3).msds
- 方法一:可用金属铝或铝化合物法制造。 金属铝法将铝加入反应器中,加入溴素进行反应,生成溴化铝,经减压蒸馏制得三溴化铝,其 2A1+3Br2→2AIBr3 氢氧化铝法 将氢氧化铝加入反应器中,加氢溴酸溶解反应,生成溴化铝。其 Al(OH)3+3HBr→A1Br3+3H2O
- 敏感性:Moisture Sensitive