CAS 80-15-9 MFCD00002129-Cumene hydroperoxide 过氧化氢异丙苯 TAO{mole}

Cumene hydroperoxide 过氧化氢异丙苯

CAS 80-15-9 MFCD00002129

化学结构图

SMILES: CC(C)(OO)c1ccccc1

化学属性

Mol. Formula	C9H12O2
Mol. Weight	152.19
Refractive index	n20/D 1.5210
Boiling Point
Density	1.03
Flash Point	-
TSCA	Yes
Melting Point	No Data Available
Vapor Density	5.4 (vs air)
Vapor Pressure	<;0.03 mmHg ( 20 °C)
Solubility	略溶于水

别名和识别编码

Chemical Name	Cumene hydroperoxide
Synonym	1-Methyl-1-phenylethyl hydroperoxide 1-Mmethyl-1-phenylethylhydroperoxide; alpha,alpha-Dimethylbenzylhydroperoxide; Cumene hydroperoxide 1-methy 1-mmethyl-1-phenylethylhydroperoxide 2-Phenyl-2-propyl hydroperoxide 3(2h)isoxazolone,5-(aminomethyl)- 7-Cumyl hydroperoxide 7-Hydroperoxykumen A,A-DIMETHYLBENZYL HYDROPEROXIDE A,A-Dimethylbenzylhydroperoxid ALPHA,ALPHA-DIMETHYLBENZYL HYDROPEROXIDE Alpha,α-dimethylbenzyl hydroperoxide Aztec CHP-80 CUMYL HYDROPEROXIDE Cumene Hydroperoxide (80%, Technical grade) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number	80-15-9
PubChem Substance ID	87560369
EC Number	201-254-7
Beilstein Registry Number	1908117
MDL Number	-
Reaxys-RN	1908117
Chemical Name Translation	过氧化氢异丙苯
Wiswesser Line Notation	QOX1&1&R
LabNetwork Molecule ID	LN00194604
Canonical SMILES	-

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安全信息

GHS Symbol

WGK Germany3

Hazard statements

H227 Combustible liquid 可燃液体
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H331 Toxic if inhaled 吸入中毒
H335 May cause respiratory irritation 可能导致呼吸道刺激
H242 Heating may cause a fire 加热可能会引起火灾
H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
H302+H312
H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
H226 Flammable liquid and vapour 易燃液体和蒸气
H302 Harmful if swallowed 吞食有害
H312 Harmful in contact with skin 皮肤接触有害

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes 5.2 O,T,N O;T;N

RTECSMX2450000

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
P234 Keep only in original container. 只保留在原来的容器中。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P301+P330+P331+P310
P303+P361+P353
P305+P351+P338
P305+P351+P338+P310
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P403+P233
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger Warning {} {} {} {} {} {} {} {TCI}

Safety Statements

S14 Keep away from ... (incompatible materials to be indicated by the manufacturer) 远离（生产厂家指定的不相容物质）保存；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S3/7 Keep container tightly closed in a cool place 将容器严格密闭保存在阴凉处；
S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S50 Do not mix with ... (to be specified by the manufacturer) 不要与……（由生产厂家指定）混合；
S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；

Risk Statements

R10 Flammable 易燃
R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
R23 Toxic by inhalation 吸入有毒
R34 Causes burns 会导致灼伤
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R37 Irritating to respiratory system 刺激呼吸道
R48/20/22
R51/53
R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
R7 May cause fire 会导致起火

Storage condition -20 -20°C -20°C, Light sensitive, Light sensitive -20℃ 0-10 0-10°C 2-8°C 储存温度2-8°C

UN Number 2116/3109 3109 UN 3109 5.2 UN3109

Packing GroupII

Hazard Class5.2/8

Warnings 危化品目录(2015)

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 8844 mg/kg/67W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   JNCIAM Journal of the National Cancer Institute.  (Washington, DC)  V.1-60,
   1940-78.  For publisher information, see JJIND8.  Volume(issue)/page/year:
   37,825,1966

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 304 mg/kg
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Blood - lymphoma, including Hodgkin's disease
   Skin and Appendages - tumors
REFERENCE :
   RARSAM Radiation Research, Supplement.  (New York, NY)  No.1-7, 1959-67.
   Discontinued.  Volume(issue)/page/year: 3,193,1963

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 382 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,242,1986

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1200 mg/kg
TOXIC EFFECTS :
   Cardiac - pulse rate increase, without fall in BP
   Blood - changes in erythrocyte (RBC) count
   Nutritional and Gross Metabolic - body temperature decrease
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 8(8),12,1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 270 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 26(12),22,1961

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION

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TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   ABCHA6 Agricultural and Biological Chemistry.  (Maruzen Co. Ltd., POB 5050,
   Tokyo International, Tokyo 100-31, Japan)  V.25-    1961-
   Volume(issue)/page/year: 44,1989,1980

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   PNASA6 Proceedings of the National Academy of Sciences of the United States
   of America.  (National Academy of Sciences, Printing & Pub. Office, 2101
   Constitution Ave., Washington, DC 20418) V.1-    1915-
   Volume(issue)/page/year: 79,7445,1982

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 47 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 308,159,1994

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 10 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 203,81,1988

Restrict 危险品

其他信息

类别:氧化剂
用途一:用于乙烯裂解汽油脱砷和ABS接枝聚合引发剂
毒性分级:中毒
Acros Organics:过氧化氢异丙苯 Cumyl hydroperoxide, 80%(80-15-9)
蒸气压:<;0.03 mm Hg ( 20 °C)
刺激数据:皮肤-兔子 500 毫克轻度; 眼睛-兔子 1 毫克
Sigma Aldrich:80-15-9(sigmaaldrich)
急性毒性:口服-大鼠 LD50 382 毫克/公斤; 腹注-小鼠 LD50: 270 毫克/公斤
过氧化氢异丙苯价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80039227 过氧化氢异丙苯（*） 250ml 39元 2011/04/16 C2223 过氧化氢异丙苯(含约20%的芳香烃) Cumene Hydroperoxide (contains ca. 20% Aromatic Hydrocarbon) 100G 225元 2010/06/21 349960050 过氧化氢异丙苯 Cumyl hydroperoxide 80% 5 GR 264元
MSDS 信息:过氧化羟基异丙苯(80-15-9).msds
TCI Shanghai:过氧化氢异丙苯(含约20%的芳香烃) Cumene Hydroperoxide (contains ca. 20% Aromatic Hydrocarbon)(80-15-9)
外观性质:无色至淡黄色液体。
职业标准:STEL 1 毫克/立方米
上游原料:异丙基苯
可燃性危险特性:易燃; 遇还原剂、铵、有机物、酸、易燃物混合易燃
MOL 文件:80-15-9.mol
下游产品:丙酮 --> 苯酚 --> 环氧丙烷 --> 过氧化二异丙苯
Alfa Aesar:过氧化羟基异丙苯,tech.80% Cumene hydroperoxide, tech. 80%(80-15-9)
蒸气密度:5.4 (vs air)
储运特性:库房通风低温干燥; 与有机物、还原物、易燃物、强酸分开存放
爆炸物危险特性:与还原剂、硫、磷等混合可爆; 受热、撞击可爆
微溶于水
灭火剂:砂土、二氧化碳、泡沫、化学干粉