CAS 7051-34-5 MFCD00001306-(Bromomethyl)cyclopropane 溴甲基环丙烷 TAO{mole}

(Bromomethyl)cyclopropane 溴甲基环丙烷

CAS 7051-34-5 MFCD00001306

化学结构图

SMILES: BrCC1CC1

化学属性

Mol. Formula	C4H7Br
Mol. Weight	135.00
Boiling Point	105-107°C at 760 mmHg
Density	1.392
Refractive index	n20/D 1.457(lit.)
Flash Point	41°C
TSCA	No
Appearance	无色透明、易燃液体，无异味。密度1.433g/ml，沸点102-108℃，折射率1.4385。溶解于乙醇，醚，丙酮，苯。
Danger-Level	乙类
Melting Point	87-90 °C

别名和识别编码

Chemical Name	Cyclopropylmethyl Bromide
CAS Number	7051-34-5
Alfabeta Name	CYCLOPROPYLMETHYLBROMIDE
MDL Number	MFCD00001306
Synonym	Cyclopropylmethyl bromide {LY} Cyclopropylmethyl bromide {} {LY} Cyclopropylmethyl bromide {} {} {LY} Cyclopropylmethyl bromide {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} { {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylmethyl bromide {} {} {} {} {} {} {} {} {} {} {
EC Number	230-331-8
Beilstein Registry Number	605296
PubChem Substance ID	81503
Chemical Name Translation	溴甲基环丙烷
InChIKey	AEILLAXRDHDKDY-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00008111
InChI	InChI=1S/C4H7Br/c5-3-4-1-2-4/h4H,1-3H2
Canonical SMILES	BrCC1CC1

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产品应用

用于有机合成中构建环丙烷甲基基团（cyclopropylmethyl- group）

安全信息

Warnings IRRITANT, KEEP COLD, FLAMMABLE

Signal word Warning

GHS Symbol

WGK Germany3

Safety Statements

S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；

Risk Statements

R10 Flammable 易燃
R22 Harmful if swallowed 吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P242 Use only non-sparking tools. 只能使用无火花工具。
P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312
P301+P317
P302+P352
P303+P361+P353
P304+P340
P305+P351+P338
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P332+P313
P332+P317
P337+P313
P337+P317
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P370+P378
P403+P233
P403+P235
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Packing GroupIII

UN Number 1993

Hazard statements

H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H226 Flammable liquid and vapour 易燃液体和蒸气
H302 Harmful if swallowed 吞食有害
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激
H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes 3 Xn

Hazard Class3

Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

其他信息

无异味。溶解于乙醇，醚，丙酮和苯。
Alfa Aesar:溴甲基环丙烷,97% (Bromomethyl)cyclopropane, 97%(7051-34-5)
检测方法:GC
图谱信息:溴甲基环丙烷(7051-34-5)核磁图( 1 HNMR) 溴甲基环丙烷(7051-34-5)质谱(MS) 溴甲基环丙烷(7051-34-5)核磁图( 13 CNMR)
MOL 文件:7051-34-5.mol
用途一:用作医药中间体
Acros Organics:环丙基溴甲烷/溴甲基环丙烷 (Bromomethyl)cyclopropane, 96%(7051-34-5)
Hazard Note:Irritant
Sigma Aldrich:7051-34-5(sigmaaldrich)
海关编码:29035990
MSDS 信息:1-(Bromomethyl)cyclopropane(7051-34-5).msds
上游原料:乙醚 --> 四氢呋喃 --> 氢化铝锂 --> 三溴化磷 --> 环丙甲酸
用途二:用于有机合成中构建环丙烷甲基基团（cyclopropylmethyl- group）
溴甲基环丙烷价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 xw010407 环丙基溴甲烷 10ml 289元 2010/06/21 RJF00467DA 溴甲基环丙烷 1-(bromomethyl)cyclopropane 1 GR 315元 2010/06/21 RJF00467EB 溴甲基环丙烷 1-(bromomethyl)cyclopropane 25 GR 4200元
下游产品:环丙乙酸 --> 西托溴铵