1-iodo-2-methylpropane 碘代异丁烷
CAS 513-38-2 MFCD00001084
化学结构图
SMILES: CC(C)CI
化学属性
| Mol. Formula | C4H9I |
|---|---|
| Mol. Weight | 184.02 |
| Refractive index | 1.4930 to 1.4970 |
| Vapor Density | 6 (vs air) |
| Boiling Point | 121°C(lit.) |
| Vapor Pressure | 20 mmHg ( 20 °C) |
| Density | 1.599 g/mL at 25 °C(lit.) |
| Flash Point | 0°C(lit.) |
| TSCA | Yes |
| Melting Point | -93° |
| Solubility | 不溶 |
别名和识别编码
| Chemical Name | 1-iodo-2-methylpropane |
|---|---|
| Synonym | 1-iodo-2-methyl-propan 1-Iodo-2-methylpropane isobutyl iodide 1-Iod-2-methylpropan primaryisobutyliodide 2-methylpropyliodide 1-碘异丁烷 二氮杂18-冠醚-6 1-碘-2-甲基丙烷 propane, 1-iodo-2-methyl- iso-C4H9I iodo-1 methyl-2 propane 1-IODO-2-METHYLPROPANE 1-iodo-2-methylpropane Isobutyliodid 1-碘-2-甲基丙烷, 98%, STAB. WITH COPPER Isobutyl iodine 1-iodo-2-methyl-propane 1-Iodo-2-methylpropane, stabilized, 97% Isobutyljodid 2-methyl-1-iodopropane 1-IODO-2-METHYLPROPANE STAB. sec-butyl iodide Isobutyl-iodid 异丁基碘 1-Iodo-iso-butane 2-Methylpropyl iodide 1-Jod-2-methylpropan Propane,1-iodo-2-methyl- 碘代异丁烷 1-Iodo-2-methylpropane (stabilized with Copper chip) 1-IODOMETHYLPROPANE 碘化异丁烷 碘異丁烷 iodomethylpropanes Isobutyl iodide ISOBUTYL IODIDE Primary isobutyl iodide ISOBUTYL IODIDE pure 1-Iodo-2-methylpropane, 98%, stab. with copper 1-碘代异丁烷 ISO-BUTANEIODIDE |
| MDL Number | MFCD00001084 |
| CAS Number | 513-38-2 |
| PubChem Substance ID | 10556 |
| EC Number | 208-160-5 |
| Beilstein Registry Number | 1730927 |
| Merck Number | 5144 |
| Reaxys-RN | 1730927 |
| Chemical Name Translation | 碘代异丁烷 |
| Wiswesser Line Notation | I1Y1&1 |
| LabNetwork Molecule ID | LN00007954 |
| InChI | InChI=1S/C4H9I/c1-4(2)3-5/h4H,3H2,1-2H3 |
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分类
- {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
- {uni_hamburg} no charge; 1fragment
相关文献及参考
- Short: II/24B Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24B Year: 2000 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-65345-7 ISBN: 978-3-540-65345-5 Internet Resource: DOI:10.1007/b58835 RefComment: VIII, 525 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24B contains an introduction and tables of rotational and centrifugal distortion constants of asymmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
- Short: II/24C Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Interaction Constants of Diamagnetic Molecules Author: Demaison, J.; Hübner, H.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24C Year: 2002 Keyword: Atoms; Molecules and Cluster; Physical Chemistry; asZeeman effect parameters; electric dipole moments; hind
安全信息
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R20 Harmful by inhalation 吸入有害
- R11 Highly flammable 非常易燃
- R53 May cause long-term adverse effects in the aquatic environment 对水生环境有长期的有害作用
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
- S33 Take precautionary measures against static discharges 对静电采取预防措施；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭，置于通风良好的场所；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
GHS Symbol
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H331 Toxic if inhaled 吸入中毒
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P241+P242+P243
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P303+P361+P353
- P304+P340+P312
- P305+P351+P338+P337+P313
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P370+P378
- P403+P233
- P403+P235
- P501 Dispose of contents/container to..… 处理内容物/容器.....
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1241 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,756,1969
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 594 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,756,1969
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 6700 mg/m3/4H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,756,1969
其他信息
- 海关编码:29033080
- 毒性分级:中毒
- Alfa Aesar:1-碘-2-甲基丙烷,98%,stab.withcopper 1-Iodo-2-methylpropane, 98%, stab. with copper(513-38-2)
- 蒸气密度:6 (vs air)
- 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
- 急性毒性:腹腔- 大鼠 LD50: 1241 毫克/ 公斤; 腹腔- 小鼠 LD50: 594 毫克/ 公斤
- 用途二:用作溶剂、分析试剂、有机合成原料。
- MSDS 信息:1-碘-2-甲基丙烷(513-38-2).msds
- 类别:易燃液体
- 用途一:用作有机溶剂，也用于有机合成
- 外观性质:无色或微黄色液体，见光变成棕色。
- Sigma Aldrich:513-38-2(sigmaaldrich)
- 蒸气压:20 mm Hg ( 20 °C)
- 上游原料:异丁醇
- Acros Organics:1-碘-2-甲基丙烷 1-Iodo-2-methylpropane, stabilized, 97%(513-38-2)
- 图谱信息:碘代异丁烷(513-38-2)核磁图( 13 CNMR) 碘代异丁烷(513-38-2)质谱(MS) 碘代异丁烷(513-38-2)红外图谱(IR2) 碘代异丁烷(513-38-2)红外图谱(IR1) 碘代异丁烷(513-38-2)核磁图( 1 HNMR)
- 敏感性:Light Sensitive
- F:8-10-23
- TCI Shanghai:1-碘-2-甲基丙烷(含稳定剂铜屑) 1-Iodo-2-methylpropane (stabilized with Copper chip),>;97.0%(GC)(513-38-2)
- 可燃性危险特性:遇明火、高温、氧化剂易燃; 遇热产生有毒碘化物气体
- 方法一:由异丁醇与三碘化磷反应而得。先将赤磷和异丁醇混合，在水浴上加热，慢慢加入碘，加完后继续反应4h，蒸馏粗品，再进行分馏，收集119-122℃馏分即为成品。
- 储运特性:库房通风低温干燥避光; 与氧化剂分开存放
- 碘代异丁烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80025980 碘代异丁烷 25ml 141.9元 2011/04/16 I0322 1-碘-2-甲基丙烷(含稳定剂铜屑) 1-Iodo-2-methylpropane (stabilized with Copper chip) 250ML 2000元 2011/04/16 I0322 1-碘-2-甲基丙烷(含稳定剂铜屑) 1-Iodo-2-methylpropane (stabilized with Copper chip) 25ML 356元
- MOL 文件:513-38-2.mol
