CAS 75-27-4 MFCD00000824-Bromodichloromethane 溴代二氯甲烷 TAO{mole}

Bromodichloromethane 溴代二氯甲烷

CAS 75-27-4 MFCD00000824

化学结构图

SMILES: ClC(Cl)Br

化学属性

Mol. Formula	CHBrCl2
Mol. Weight	163.83
Refractive index	1.4940 to 1.4980
Boiling Point	87 °C at 760 mmHg
Density	1.98 g/mL at 25 °C(lit.)
Melting Point	-55 °C
TSCA	Yes
Flash Point	87-89°C
Stability	对光敏感

别名和识别编码

Chemical Name	Bromodichloromethane
CAS Number	75-27-4
Synonym	Bromodichloromethane {LY} Bromodichloromethane {} {LY} Bromodichloromethane {} {} {LY} Bromodichloromethane {} {} {} {LY} Bromodichloromethane {} {} {} {} {LY} Bromodichloromethane {} {} {} {} {} {LY} Bromodichloromethane {} {} {} {} {} {} {LY} Bromodichloromethane {} {} {} {} {} {} {} {LY} Bromodichloromethane {} {} {} {} {} {} {} {} {LY} Bromodichloromethane {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} Bromodichloromethane {} {} {} {} {} {} {} {} {} {} {LY} Bromodichloromethane {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Bromodichloromethane {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromodichloromethane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromodichloromethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromodichloromethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromo
MDL Number	MFCD00000824
PubChem Substance ID	6359
EC Number	200-856-7
Beilstein Registry Number	1,67
Merck Number	1417
Reaxys-RN	1697005
Chemical Name Translation	溴代二氯甲烷
Wiswesser Line Notation	GYGE
LabNetwork Molecule ID	LN01284299
InChI	InChI=1S/CHBrCl2/c2-1(3)4/h1H
Canonical SMILES	ClC(Cl)Br

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分类

Mutagenesis Research Chemicals
{SNA} A-B, Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Applications, B, BI - BZ, Bromo, Chemical Class, Chloro, Chromatography, Disinfection Byproducts, Disinfection Product Residues and Solvents, Environmental Standards, Food & Beverage Analysis, Halogenated, Processing/Packaging Contaminants, Volatiles/ Semivolatiles, Waste water
{SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
{uni_hamburg} no charge; 1fragment
Miscellaneous Reagents

产品应用

Usually used to investigate the in vivo genotoxicity of chlorodibromomethane, bromodichloromethane and bromoform in mice.

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H351 Suspected of causing cancer 怀疑致癌
H318 Causes serious eye damage 严重伤害眼睛
H302 Harmful if swallowed 吞食有害
H335 May cause respiratory irritation 可能导致呼吸道刺激
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSPA5310000

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P301+P312
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P305+P351+P338
P302+P352
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P308+P313
P501 Dispose of contents/container to..… 处理内容物/容器.....
P301+P312+P330
P337+P313
P403+P233
P303+P361+P353
P201 Obtain special instructions before use. 使用前获取专门指示。

Signal word Danger

Risk Statements

R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R22 Harmful if swallowed 吞咽有害
R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R11 Highly flammable 非常易燃

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S36/39 Wear suitable protective clothing and eye/face protection 穿戴适当的防护服和眼睛/面保护；
S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；

Hazard Codes Xn Xn,T,F

Storage condition 0-10 0-10°C 0-6°C 2-8℃避光保存。储存温度2-8℃ 储存温度2-8℃,充氩保存

UN Number 2810 1230

Packing GroupII

Hazard Class3/6.1

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 25500 mg/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Kidney, Ureter, Bladder - Kidney tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-321,1987

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 25500 mg/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Gastrointestinal - tumors
   Kidney, Ureter, Bladder - Kidney tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-321,1987

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 51 gm/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Gastrointestinal - tumors
   Kidney, Ureter, Bladder - Kidney tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-321,1987

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 38250 mg/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-321,1987

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 430 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - tremor
   Liver - other changes
REFERENCE :
   SRTCAC Science Reports of the Research Institutes, Tohoku University, Series
   C: Medicine. (Tohoku University, Research Institute for Tuberculosis and
   Cancer, 4-1 Seiryo-machi, Sendai, Japan)  V.1-   1949-
   Volume(issue)/page/year: 36(1-4),10,1989

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 450 mg/kg
TOXIC EFFECTS :
   Brain and Coverings - changes in circulation (hemorrhage, thrombosis, etc.)
   Liver - fatty liver degeneration
   Blood - hemorrhage
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   44,213,1978

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   TECSDY Toxicological and Environmental Chemistry.  (Gordon & Breach Science
   Pub. Inc., 1 Park Ave., New York, NY 10016)  V.3(3/4)-    1981-
   Volume(issue)/page/year: 13,205,1987

TYPE OF TEST            : Sister chromatid exchange
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 200 mg/kg/4D (Intermittent)
REFERENCE :
   ENVRAL Environmental Research.  (Academic Press, Inc., 1 E. First St.,
   Duluth, MN 55802) V.1-    1967-  Volume(issue)/page/year: 32,72,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 180 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   11,91,1988

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 400 umol/L
REFERENCE :
   ENVRAL Environmental Research.  (Academic Press, Inc., 1 E. First St.,
   Duluth, MN 55802) V.1-

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 50 mg/plate
REFERENCE :
   DHEFDK HEW Publication (FDA. United States).  (Washington, DC)  ?-1979(?).
   For publisher information, see HPFSDS.  Volume(issue)/page/year:
   FDA-78-1046,1978

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 164 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(iss

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 750 mg/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   40,30,1997

其他信息

一溴二氯甲烷价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 B1011 溴代二氯甲烷(含稳定剂乙醇) Bromodichloromethane (stabilized with Ethanol) 25G 680元 2014/06/02 S0635 一溴二氯甲烷(1mg/ml的甲醇溶液)[用于水分析] Bromodichloromethane (1mg/ml in Methanol) [for Water Analysis] 1ML 240元 2010/06/21 160700500 一溴二氯甲烷 Bromodichloromethane 98+%, stabilized 50 ML 1396元
类别:有毒物质
Sigma Aldrich:75-27-4(sigmaaldrich)
毒性分级:中毒
挥发性有机化合物(VOCs)单组分标准液 US EPA方法:502.2,524.2,8021,8021A,8021B,624,8240B,8260B
图谱信息:一溴二氯甲烷(75-27-4)质谱(MS) 一溴二氯甲烷(75-27-4)核磁图( 1 HNMR) 一溴二氯甲烷(75-27-4)Raman光谱一溴二氯甲烷(75-27-4)核磁图( 13 CNMR) 一溴二氯甲烷(75-27-4)红外图谱(IR1)
F:8
难溶于水，溶于乙醇、丙酮、苯、氯仿、DMSO和乙醚等有机溶剂。
MOL 文件:75-27-4.mol
TCI Shanghai:一溴二氯甲烷(1mg/ml的甲醇溶液)[用于水分析] Bromodichloromethane (1mg/ml in Methanol) [for Water Analysis](75-27-4)
外观性质:无色液体。难溶于水，溶于醇、苯、醚等有机溶剂。折光率：1.497熔点：-55 °C沸点：87 °C密度：1.98
挥发性有机化合物(VOCs)单组分标准液
急性毒性:口服-大鼠 LD50: 916 毫克/公斤
灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
储运特性:库房通风低温干燥
Acros Organics:一溴二氯甲烷 Bromodichloromethane, stabilized, 98+%(75-27-4)
可燃性危险特性:热分解有毒溴化物和氯化物烟雾
Alfa Aesar:溴二氯代甲烷,98%,碳酸钾做稳定剂 Bromodichloromethane, 98%, stab. with potassium carbonate(75-27-4)