Palmitoyl chloride 棕榈酰氯

CAS 112-67-4 MFCD00000742

化学结构图

112-67-4
SMILES: CCCCCCCCCCCCCCCC(=O)Cl

化学属性

Mol. FormulaC16H31ClO
Mol. Weight275
Density0.906
Refractive index1.4500 to 1.4530
Boiling Point88-90
Melting Point11-13
Flash Point166°C(lit.)
TSCAYes
Solubility分解
Stability对湿度敏感,对热敏感
Appearance 无色液体。熔点11-12℃，沸点12℃，沸点199℃（2.6kPa），194.5℃（2.27kPa）。折射率1.4512。能与有机溶剂混溶，溶于乙醚。在水和乙醇中分解。

别名和识别编码

Chemical NamePalmitoyl chloride
CAS Number112-67-4
EC Number203-996-7
Beilstein Registry Number972409
MDL NumberMFCD00000742
Synonym Hexadecanoyl chloride Palmitoyl choride
PubChem Substance ID8206
Chemical Name Translation棕榈酰氯
Reaxys-RN972409
LabNetwork Molecule IDLN00223572
InChIInChI=1S/C16H31ClO/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16(17)18/h2-15H2,1H3
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分类

  • {SA} Acid Halides, Building Blocks, Carbonyl Compounds, Cell Biology, Cell Signaling and Neuroscience, Chemical Synthesis, G Protein Function, G Proteins and Cyclic Nucleotides, Organic Building Blocks, Post-translational Modification
  • {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, G Protein Function, G Proteins and Cyclic Nucleotides, Organic Building Blocks, Post-translational Modification, 细胞信号转导和神经科学, 细胞生物学
  • {uni_hamburg} no charge; carbonyl chloride; 1fragment
  • {SNA} Acid Halides, Bioactive Small Molecules, Building Blocks, Carbonyl Compounds, Cell
  • {SNA} Acid Halides,

产品应用

  • A compound which has been used as a polymeric carrier for plasmid DNA delivery to 293T cells

相关文献及参考

  • Short: EINECS
  • Beilstein:2,374
  • Short: III/38B

安全信息

Signal word Danger
GHS Symbol
WGK Germany1
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S8 Keep container dry 保持容器干燥；
Risk Statements
  • R14 Reacts violently with water 遇水会猛烈反应
  • R29 Contact with water liberates toxic gas. 遇水释放出有毒气体
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupII
UN Number 3265 UN 3265 8/PG 2 UN3265
Storage condition -20°C 0-10 0-10°C 2-8°C储存 Moisture Sensitive 储存温度2-8℃,充氩保存
Hazard Codes 8 C
Hazard Class8
Warnings 危化品目录(2015)
Restrict 危险品

其他信息

  • F:9-21
  • 下游产品:1-十六烷醇 --> 氯霉素棕榈酸酯 --> L-抗坏血酸棕榈酸酯
  • 图谱信息:棕榈酰氯(112-67-4)质谱(MS) 棕榈酰氯(112-67-4)Raman光谱 棕榈酰氯(112-67-4)红外图谱(IR1) 棕榈酰氯(112-67-4)红外图谱(IR2)
  • MOL 文件:112-67-4.mol
  • Alfa Aesar:棕榈酰氯,98% Palmitoyl chloride, 98%(112-67-4)
  • 上游原料:棕榈酸
  • 用途一:用作有机合成中间体
  • TCI Shanghai:十六酰氯 Palmitoyl Chloride,>;95.0%(T)(112-67-4)
  • 方法一:由棕榈酸与氯化亚砜反应而得。将棕榈酸、氯化亚砜及苯加入反应锅内，加热。反应温度最后达到80-85℃，保温2h。然后在90℃（21.3kPa）回收氯化亚砜及苯，得十六酰氯。原料消耗定额：棕榈酸880kg/t、氯化亚砜580kg/t、苯200kg/t。
  • Sigma Aldrich:112-67-4(sigmaaldrich)
  • 能溶于醚，在水及醇中分解，在空气中不稳定。
  • Acros Organics:Palmitoyl chloride, tech., 92%(112-67-4)
  • 棕榈酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K7615201 棕榈酰氯;十六酰氯 250ml 812元 2011/04/16 P0009 棕榈酰氯 Palmitoyl Chloride 25G 196元 2011/04/16 P0009 棕榈酰氯 Palmitoyl Chloride 500G 862元
  • 用途二:该品为有机合成中间体，在医药工业用来制取抗菌素类药氯霉素十六碳酸酯及无味氯霉素等。
  • 敏感性:Moisture Sensitive

系列性分类

  1. Life Science 生命科学
  2. Cell Biology 细胞生物学
  3. Bioactive Small Molecules - Cell Biology
  4. P - Bioactive Small Molecules
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Acid Halides 酸性卤化物(酰氯等)
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Acid Halides 酸性卤化物(酰氯等)
  1. Life Science 生命科学
  2. Cell Biology 细胞生物学
  3. Cell Signaling and Neuroscience - Cell Biology
  4. G Proteins and Cyclic Nucleotides - Cell Signaling and Neuroscience
  5. G Protein Function - G Proteins and Cyclic Nucleotides
  6. Post-translational Modification - G Protein Function
  1. Acyl halide
  2. acyl chloride
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Cell Signaling and Neuroscience
  4. G Proteins and Cyclic Nucleotides
  5. G Protein Function
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Cell Signaling and Neuroscience
  4. Peptides and Proteins
  5. G Proteins
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Proteins and Derivatives
  4. Proteins for Cell Biology
  5. G Proteins
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Cell Signaling and Neuroscience
  4. Peptides and Proteins
  5. Proteins for Cell Biology
  6. Cytoskeleton and Extracellular Matrix Proteins

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