2-Bromo-1-(3-Methoxyphenyl)Ethanone 2-溴-3’-甲氧基苯乙酮

CAS 5000-65-7 MFCD00000199

化学结构图

5000-65-7
SMILES: COc1cccc(C(=O)CBr)c1

化学属性

Mol. FormulaC9H9BrO2
Mol. Weight229.07
Melting Point60-62°C
TSCANo
Boiling Point278.1°C at 760 mmHg

别名和识别编码

Chemical Name2-Bromo-1-(3-Methoxyphenyl)Ethanone
CAS Number5000-65-7
Alfabeta NameBROMOMETHOXYPHENYLETHANONE 213()----
MDL NumberMFCD00000199
Synonym 2-Bromo-3'-methoxyacetophenone {LY} 2-Bromo-3'-methoxyacetophenone {} {LY} 2-Bromo-3'-methoxyacetophenone {} {} {LY} 2-Bromo-3'-methoxyacetophenone {} {} {} {LY} 2-Bromo-3'-methoxyacetophenone {} {} {} {} {LY} 2-Bromo-3'-methoxyacetophenone {} {} {} {} {} {LY} 2-Bromo-3'-methoxyacetophenone {} {} {} {} {} {} {LY} 2-Bromo-3'-methoxyacetophenone {} {} {} {} {} {} {} {LY} 2-Bromo-3'-methoxyacetophenone {} {} {} {} {} {} {} {} {LY} 2-Bromo-3'-methoxyacetophenone {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-3'-methoxyacetophenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-3'-methoxyacetophenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-3'-methoxyacetophenone {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-3'-methoxyacetophenone {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-3'-methoxyacetophenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-3'-methoxyacetophenone {} {} {} {} {} {} {} {} {}
PubChem Substance ID101294
EC Number225-666-1
Beilstein Registry Number8(4)337
Reaxys-RN510128
Chemical Name Translation2-溴-3’-甲氧基苯乙酮
InChIKeyIOOHBIFQNQQUFI-UHFFFAOYSA-N
LabNetwork Molecule IDLN00007819
InChIInChI=1S/C9H9BrO2/c1-12-8-4-2-3-7(5-8)9(11)6-10/h2-5H,6H2,1H3
Canonical SMILESC1=C(C=CC=C1OC)C(CBr)=O
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分类

  • {SNA} Building Blocks, C9, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
  • Aromatics
  • Intermediates,

产品应用

  • Derivatizing reagent.

相关文献及参考

  • Webster, S., et al.: Bioorg. Med. Chem. Lett., 20, 3265 (2010),
  • Chezal, J., et al.: Eur. J. Med. Chem., 45, 2044 (2010),

安全信息

Warnings IRRITANT
WGK Germany3
GHS Symbol
Precautionary statements
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P403+P233
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P304+P340
  • P304+P340+P310
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P301+P330+P331
  • P303+P361+P353+P310+P363
  • P405 Store locked up. 上锁保管。
  • P234 Keep only in original container. 只保留在原来的容器中。
Signal word
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Packing GroupII
UN Number UN 3261 8/PG 2 3261 UN3261
Risk Statements
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R34 Causes burns 会导致灼伤
  • R22 Harmful if swallowed 吞咽有害
Hazard Codes C
Storage condition -20°C {LY} -20°C 0-10 0-10°C 0-6°C {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -2
Hazard Class8

其他信息

  • Alfa Aesar:2-溴-3'-甲氧基苯乙酮,97% 2-Bromo-3'-methoxyacetophenone, 98%(5000-65-7)
  • MOL 文件:5000-65-7.mol
  • Sigma Aldrich:5000-65-7(sigmaaldrich)
  • 图谱信息:2-溴-3‘-甲氧基苯乙酮(5000-65-7)红外图谱(IR1) 2-溴-3‘-甲氧基苯乙酮(5000-65-7)质谱(MS) 2-溴-3‘-甲氧基苯乙酮(5000-65-7)红外图谱(IR2)
  • Acros Organics:2-溴-3'-甲氧基苯乙酮 2-Bromo-3'-methoxyacetophenone, 97%(5000-65-7)
  • TCI Shanghai:3'-甲氧基苯乙酰溴[用于高效液相色谱标记] 3'-Methoxyphenacyl Bromide [for HPLC Labeling],>;99.0%(T)(5000-65-7)
  • 2-溴-3‘-甲氧基苯乙酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0815 3'-甲氧基苯甲酰甲基溴 3'-Methoxyphenacyl Bromide 5G 520元 2014/06/02 M0815 3'-甲氧基苯甲酰甲基溴 3'-Methoxyphenacyl Bromide 25G 1580元 2014/06/02 A5505 3'-甲氧基苯乙酰溴[用于高效液相色谱标记] 3'-Methoxyphenacyl Bromide [for HPLC Labeling] 5G 1140元
  • 2-溴-3‘-甲氧基苯乙酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 M0815 3'-甲氧基苯甲酰甲基溴 3'-Methoxyphenacyl Bromide 5G 549元 2011/04/16 M0815 3'-甲氧基苯甲酰甲基溴 3'-Methoxyphenacyl Bromide 25G 1660元 2011/04/16 A5505 3'-甲氧基苯乙酰溴[用于高效液相色谱标记] 3'-Methoxyphenacyl Bromide [for HPLC Labeling] 5G 935元

系列性分类


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