CAS 103-33-3 MFCD00003022-1,2-Diphenyldiazene 1,2-二苯基二氮烯 TAO{mole}

1,2-Diphenyldiazene 1,2-二苯基二氮烯

CAS 103-33-3 MFCD00003022

化学结构图

SMILES: c1ccc(/N=N/c2ccccc2)cc1

化学属性

Mol. Formula	C12H10N2
Mol. Weight	182.23
Boiling Point	293
Density	1.090
Melting Point	65-68
TSCA	Yes
Autoignition Point	890 °F
Vapor Pressure	1 mmHg ( 104 °C)
Flash Point	100 °C
Refractive index	1.6266
Solubility	不溶于水，溶于醇、醚。
Stability	对湿度敏感

别名和识别编码

Chemical Name	1,2-Diphenyldiazene
CAS Number	103-33-3
Synonym	benzeneazobenzene, trans- {uni_hamburg} Diphenyldiimide A 15073 Azofume trans-Azobenzol Azobenzol 1,2-DIPHENYLDIAZENE ENT 14,611 trans-diphenyldiazene (E)-Azobenzene DIPHENYLDIAZENE Diazobenzol 二苯二亞胺 N,N'-diphenylhydrazine Azodibenzeneazofume NSC 2102 Benzene, azodi 偶氮苯 Azobenzene, (E)- Diazene, diphenyl-, (E)- Diazene, diphenyl- Benzene, azobis- trans-diphenyl-diazene Azobisbenzene BENZENEAZOBENZENE Phenylazobenzene 1,2-Diphenyldiazene azobis-benzen Usaf ek-704 Diphenyl diimid TRANS-AZOBENZE
PubChem Substance ID	2272
EC Number	203-102-5
Beilstein Registry Number	1819138
MDL Number	MFCD00003022
Reaxys-RN	742610
Merck Number	917
Chemical Name Translation	1,2-二苯基二氮烯
Wiswesser Line Notation	RNUNR
InChI	InChI=1S/C12H10N2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10H

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产品应用

有机合成。杀螨剂。制造联苯染料。橡胶促进剂。

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H332 Harmful if inhaled 吸入有害
H302 Harmful if swallowed 吞食有害
H350 May cause cancer 可能致癌
H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
H302+H332

Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Gloves, type P2 (EN 143) respirator cartridges

Hazard Codes T,N

RTECSCN1400000

Precautionary statements

P304+P340+P312
P501 Dispose of contents/container to..… 处理内容物/容器.....
P308+P313
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P273 Avoid release to the environment. 避免释放到环境中。
P201 Obtain special instructions before use. 使用前获取专门指示。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P308+
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P405 Store locked up. 上锁保管。
P301+P312+P330
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。

Signal word

UN Number UN3077 UN 3077 9/PG 3

Safety Statements

S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；

Risk Statements

R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
R45 May cause cancer 可能致癌
R48/22
R50/53
R11 Highly flammable 非常易燃
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
R62 Possible risk of impaired fertility 有削弱生殖能力的危险
R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
R51/53
R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
R38 Irritating to skin 刺激皮肤
R48/20

Packing GroupIII

Hazard Class9

Storage condition 密封保存。密封保存;充氩保存 2-8°C

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 15 gm/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Blood - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-154,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 17 gm/kg/2Y-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Sense Organs and Special Senses (Ear) - effect, not otherwise specified
REFERENCE :
   CANCAR Cancer (Philadelphia).  (Lippincott/Harper, Journal Fulfillment
   Dept., 2350 Virginia Ave., Hagerstown, MD 21740)  V.1-    1948-
   Volume(issue)/page/year: 3,789,1950

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 7280 mg/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Blood - tumors
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   25,619,1987

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 300 mg/kg/8W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   82,19,1986

TYPE OF TEST

{hazard_

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BESAAT Bulletin of the Entomological Society of America.  (Entomological
   Soc. of America, 4603 Calvert Rd., College Park, MD 20740)  V.1-    1955-
   Volume(issue)/page/year: 12,117,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARSIM* Agricultural Research Service, USDA Information Memorandum.
   (Beltsville, MD 20705)  Volume(issue)/page/year: 20,2,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 250 ug/L
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7,1,1985

{hazard_c

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 142 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 272,145,1992

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 12400 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 192,239,1987

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 375 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 234,129,1990

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 300 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 113,357,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 25 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 5(Suppl
   1),3,1983

其他信息

可燃性危险特性:燃烧产生有毒氮氧化物气体
毒性分级:中毒
上游原料:锌粉 --> 苄醇
用途二:有机合成。杀螨剂。制造联苯染料。橡胶促进剂。
灭火剂:干粉、泡沫、砂土
偶氮苯价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 30015860 偶氮苯 25g 37元 2011/04/16 A0565 偶氮苯 Azobenzene 500G 3690元 2011/04/16 A0565 偶氮苯 Azobenzene 25G 393元
下游产品:分散橙 29 --> 光致变色偶氮苯聚合物 --> 4-N-苯基苯酰胺
不溶于水，溶于乙醇、醚、冰醋酸、丙酮和苯。低毒，半数致死量(大鼠，经口)1000mg/kg。有致癌可能性。
Alfa Aesar:偶氮苯,98% Azobenzene, 98%(103-33-3)
Sigma Aldrich:103-33-3(sigmaaldrich)
方法一:由硝基苯按下面反应而得。将硝基苯、甲醇及氢氧化钠溶液加热保持76℃，在搅拌下慢慢加锌粉，保温搅拌16h；再加入锌粉，保温反应48h。趁热过滤，冷却，在粗品中加入20%盐酸在70℃下溶化后，冷却过滤，将结晶物在水浴中加热70-80℃，放冷过滤，最后经用乙醇重结晶、干燥而得。
储运特性:库房通风低温干燥; 与食品原料分开储运
TCI Shanghai:偶氮苯 Azobenzene,>;98.0%(GC)(103-33-3)
类别:农药
MOL 文件:103-33-3.mol
外观性质:橙色片状晶体。
用途一:用于联苯染料的制造，也用作橡胶促进剂
图谱信息:偶氮苯(103-33-3)核磁图( 13 CNMR) 偶氮苯(103-33-3)红外图谱(IR3) 偶氮苯(103-33-3)质谱(MS) 偶氮苯(103-33-3)核磁图( 1 HNMR) 偶氮苯(103-33-3)红外图谱(IR2) 偶氮苯(103-33-3)红外图谱(IR1)
Acros Organics:偶氮苯 Azobenzene, 95%(103-33-3)
急性毒性:口服- 大鼠 LD50: 1000 毫克/ 公斤;腹腔-小鼠 LD50: 500 毫克/公斤
MSDS 信息:偶氮苯(103-33-3).msds
蒸气压:1 mm Hg ( 104 °C)