CAS 917-61-3 MFCD00011121-Sodium Cyanate 氰酸钠 TAO{mole}

Sodium Cyanate 氰酸钠

CAS 917-61-3 MFCD00011121

化学结构图

SMILES: N#C[O-].[Na+]

化学属性

Mol. Formula	CNNaO
Mol. Weight	65.01
Density	1.93
Melting Point	550°C
TSCA	Yes
Solubility	110 G/L (20 ºC)
Stability	对湿度敏感

别名和识别编码

Chemical Name	Sodium Cyanate
MDL Number	MFCD00011121
CAS Number	917-61-3
EC Number	213-030-6
Beilstein Registry Number	3655041
Merck Number	14,8604
Synonym	Sodiumcyanate {LY} Sodiumcyanate {} {LY} Sodiumcyanate {} {} {LY} Sodiumcyanate {} {} {} {LY} Sodiumcyanate {} {} {} {} {LY} Sodiumcyanate {} {} {} {} {} {LY} Sodiumcyanate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodiumcyanate {} {} {} {} {} {} {} {LY} Sodiumcyanate {} {} {} {} {} {} {} {} {LY} Sodiumcyanate {} {} {} {} {} {} {} {} {} {LY} Sodiumcyanate {} {} {} {} {} {} {} {} {} {} {LY} Sodiumcyanate {} {} {} {} {} {} {} {} {} {} {} {LY} Sodiumcyanate {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodiumcyanate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodiumcyanate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodiumcyanate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodiumcyanate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodiumcyanate {} {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID	517096
Chemical Name Translation	氰酸钠
Wiswesser Line Notation	NA OCN
LabNetwork Molecule ID	LN00198780
InChI	InChI=1S/CHNO.Na/c2-1-3;/h3H;/q;+1/p-1
Canonical SMILES	[Na]OC#N

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

用于有机合成等

安全信息

Signal word

GHS Symbol

WGK Germany1

Safety Statements

Risk Statements

R52/53
R22 Harmful if swallowed 吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

RTECSGS7000000

Hazard statements

H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
H302 Harmful if swallowed 吞食有害

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes Xn

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human
DOSE/DURATION           : 5400 mg/kg/24W
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - visual field changes
   Sense Organs and Special Senses (Eye) - effect, not otherwise specified
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   AROPAW Archives of Ophthalmology (Chicago).  (AMA, 535 N. Dearborn St.,
   Chicago, IL 60610)  New series: V.1-44(3), 1929-50; V.64-    1960-
   Volume(issue)/page/year: 94,927,1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intramuscular
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 310 mg/kg
TOXIC EFFECTS :
   Behavioral - altered sleep time (including change in righting reflex)
   Behavioral - convulsions or effect on seizure threshold
   Kidney, Ureter, Bladder - urine volume increased
REFERENCE :
   BJPCAL British Journal of Pharmacology and Chemotherapy.  (London, UK)
   V.1-33, 1946-68.  For publisher information, see BJPCBM.
   Volume(issue)/page/year: 1,186,1946

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 400 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - excitement
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 55(8),30,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 260 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depresse

Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store

其他信息

急性毒性:腹腔- 小鼠 LD50: 260 毫克/ 公斤; 口服- 小鼠 LDL0: 4 毫克/ 公斤
{C
Alfa Aesar:氰酸钠,97% Sodium cyanate, 97%(917-61-3)
用途六:用于有机合成等
储运特性:库房通风低温干燥; 与酸类、食品添加剂分开存放
具有吸湿性，易溶于水；微溶于苯、醚等溶剂。溶解度:110 g/l水 (20°C)，0.22 g/100g 醇(0°C)
方法三:由尿素与碳酸钠一起加热熔融制得。
MOL 文件:917-61-3.mol
可燃性危险特性:不可燃烧; 遇酸分解出剧毒、易燃气体;受热产生有毒氰化物和氧化钠烟雾
毒性分级:剧毒
用途五:用于有机合成、钢铁热处理，用作药物中间体。
所属类别一:农药中间体: 杀虫剂中间体: 苯甲酰脲类杀虫剂
上游原料:尿素 --> 二氧化碳 --> 焦炭(煤) --> 混合机
Sigma Aldrich:917-61-3(sigmaaldrich)
用途四:氰酸钠作为一种无机化工原料，用于有机合成、制药工业、钢铁的热处理等，在农药上可用于合成杀虫剂灭幼脲的中间体对氯苯基脲。
海关编码:28380000
{Che
MSDS 信息:氰酸钠(917-61-3).msds
类别:农药
方法一:尿素法将尿素与碳酸钠按尿素：碳酸钠=2.47：1(mol比)的配比，加入粉碎混合机中，经5～10 min搅拌混合后，放入存料桶。在搅拌下将混合物加入预先加热至微红的铸铁圆筒式反应器中，外用焦炭鼓风炉直接火加热，使反应生成氰酸钠。反应产生的氨气和二氧化碳经水吸收塔排空，反应物在550～600℃下搅拌15 min，使全部熔融，立即倾入铁盘中迅速冷却，使固化为8～10 mm薄片块状，再经粉碎，制得成品。其 2(NH2)2CO+Na2CO3→2NaOCN+2NH3↑+H2O+CO2↑
用途一:用作有机合成原料，用于医药、除草剂及钢的热处理
用途三:用作有机合成(氨甲丙二酯)原料、制药原料和除草剂等。也用于钢铁的热处理。
下游产品:异氰酸甲酯 --> 氨基脲 --> 灭幼脲 --> 氨基甲酸叔丁酯 --> 杀草隆 --> 卡巴胂 --> 苯丙氨酯 --> 甲丙氨酯 --> 4-溴苯基脲 --> 三氯乙酰异氰酸酯 --> 4-氯苯基脲
毒性:本品对人、畜、鱼类毒性较小，不产生典型的氰化物毒性作用。慢性中毒为破坏了氧化磷酸化作用，具有血红蛋白含量及红细胞数增加的现象。防护措施可参见氰化钾。
方法二:其制备方法是采用尿素法合成氰酸钠。反应方程式：2(NH 2 ) 2 CO+Na 2 CO 2 →2NaOCN+2NH 3 ↑+H 2 O+CO 2 ↑ 将尿素和碳酸钠按2.47∶1(mol)的配比加入粉碎混合机中，搅拌混合10min，再在搅拌下将混合物加入预先加热至微红的铸铁圆筒式反应器中，外用焦炭鼓风炉直接火加热，使反应生成氰酸钠。氨气和CO 2 经水吸收塔排空，反应物在550～600℃搅拌15min，使全部熔融，立即倾入铁盘中迅速冷却，使固化为8～10mm 薄片块状，再经粉碎制得成品。
Acros Organics:氰酸钠 Sodium cyanate, pure, 85%(917-61-3)
灭火剂:砂土、泡
参考质
氰酸钠价格(试剂级):更新日期产品编号产品名称包装价格 2010/06/21 180562500 氰酸钠 Sodium cyanate 85%, pure 250 GR 482元 2010/05/25 A12413 氰酸钠, 97% Sodium cyanate, 97% 500g 564元 2010/05/25 A12413 氰酸钠, 97% Sodium cyanate, 97% 2.5kg 2338元