CAS 86-73-7 MFCD00001111-Fluorene 芴 TAO{mole} - 淘摩尔专家级采购助手

Fluorene 芴

CAS 86-73-7 MFCD00001111

化学结构图

SMILES: c1ccc2c(c1)Cc1ccccc1-2

化学属性

Mol. Formula	C13H10
Mol. Weight	166.223
Density	1.2
Flash Point	151°(303°F)
TSCA	Yes
Melting Point	111-114 °C
Boiling Point	298 °C at 760 mmHg
Solubility	Soluble in hot alcohol, ether, benzene, and glacial acetic acid. Insoluble in water.
Appearance	白色小片状结晶，不纯时有荧光。不溶于水，溶于乙醇、乙醚、苯、二硫化碳等有机溶剂。

别名和识别编码

Chemical Name	Fluorene
CAS Number	86-73-7
Synonym	Fluorene {LY} Fluorene {} {LY} Fluorene {} {} {LY} Fluorene {} {} {} {LY} Fluorene {} {} {} {} {LY} Fluorene {} {} {} {} {} {LY} Fluorene {} {} {} {} {} {} {LY} Fluorene {} {} {} {} {} {} {} {LY} Fluorene {} {} {} {} {} {} {} {} {LY} Fluorene {} {} {} {} {} {} {} {} {} {LY} Fluorene {} {} {} {} {} {} {} {} {} {} {LY} Fluorene {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorene {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
EC Number	201-695-5
Beilstein Registry Number	5(4)2142
MDL Number	MFCD00001111
Merck Number	4155
PubChem Substance ID	6853
Reaxys-RN	1363491
Chemical Name Translation	芴
LabNetwork Molecule ID	LN00192876
InChI	InChI=1S/C13H10/c1-3-7-12-10(5-1)9-11-6-2-4-8-13(11)12/h1-8H,9H2
Canonical SMILES	C1(C=CC=C2)=C2CC3=C1C=CC=C3

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分类

{SNA} Alphabetical Index of Analytical Standards, All PAH Standards, Alpha Sort, Analytical Standards, Analytical/Chromatography, Chromatography, E-L, En
{SNA} All PAH Standards, Analytical Standards, Analytical/Chromatography, CRMs, Certified Reference Materials (CRMs), Chromatography, Environmental Standards, Fluka CRM for chromatography (neats), Organic CRMs Alphabetical, Organic CRMs TraceCERT, PAHs, Polyaromatic Hydrocarbons (PAHs), Volatiles/ Semivolatiles, neat
{SNA} Arenes, Building Blocks, Chemical Synthesis, Organic Building Blocks

产品应用

制医药，染料及芳香聚酰胺等。

安全信息

Signal word Danger

GHS Symbol

WGK Germany3

Safety Statements

S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S7 Keep container tightly closed 保存在严格密闭容器中；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S33 Take precautionary measures against static discharges 对静电采取预防措施；
S22 Do not breathe dust 不要吸入粉尘；
S24 Avoid contact with skin 避免皮肤接触；
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
S25 Avoid contact with eyes 避免眼睛接触；
S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R50/53

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P302+P352
P304+P340
P305+P351+P338
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P332+P313
P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H301 Toxic if swallowed 吞食有毒
H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
H311 Toxic in contact with skin 皮肤接触中毒
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H331 Toxic if inhaled 吸入中毒
H335 May cause respiratory irritation 可能导致呼吸道刺激
H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
H370 Causes damage to organs 导致器官损伤
H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

RTECSLL5670000

Packing GroupIII

UN Number 3077 UN 3077 9/PG 3 UN3077

Hazard Codes F,T

Storage condition RT, protect from light {LY} RT, protect from light {} {LY} RT, protect from light {} {} {LY} RT, protect from light {} {} {} {LY} RT, protect from light {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect

Hazard Class9

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PCJOAU Pharmaceutical Chemistry Journal (English Translation).  Translation
   of KHFZAN. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013)  No.1-
   1967-  Volume(issue)/page/year: 19,326,1985

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 584 umol/L
REFERENCE :
   MUTAEX Mutagenesis. (Oxford Univ. Press, Pinkhill House, Southfield Road,
   Eynsham, Oxford OX8 1JJ, UK) V.1- 1986-  Volume(issue)/page/year: 3,193,1988

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 19500 nmol/L
REFERENCE :
   MUTAEX Mutagenesis. (Oxford Univ. Press, Pinkhill House, Southfield Road,
   Eynsham, Oxford OX8 1JJ, UK) V.1- 1986-  Volume(issue)/page/year: 3,193,1988

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 150 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 203,155,1988

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 25 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 259,103,1991

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - mouse Mammary gland
DOSE/DURATION           : 1 ug/L
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   39,1784,1979

其他信息

多环芳烃(PAHs)单组分标准液
图谱信息:芴(86-73-7)红外图谱(IR1) 芴(86-73-7)Raman光谱芴(86-73-7)核磁图( 13 CNMR) 芴(86-73-7)红外图谱(IR2) 芴(86-73-7)质谱(MS) 芴(86-73-7)核磁图( 1 HNMR) 芴(86-73-7)红外图谱(IR3)
上游原料:发光油 --> 塔板 --> 精密分馏 --> 工业芴
用途一:是合成医药、农药、染料、工程塑料的原料
用途二:用于有机合成
MOL 文件:86-73-7.mol
Sigma Aldrich:86-73-7(sigmaaldrich)
TCI Shanghai:芴(区域精制法精制,熔段数:70) Fluorene Zone Refined (number of passes:70),>;99.5%(GC)(86-73-7)
用途四:制医药，染料及芳香聚酰胺等。
用途三:用作有机合成原料。可制成三硝基芴酮，用于静电复印；合成芳基透明尼龙；可代替蒽醌合成阴丹士林染料；用于制造抗痉挛药、镇静药，镇痛药，降血压药；合成杀虫剂，除草剂；制备抗冲击有机玻璃和芴醛树脂；亦可用作湿润剂，洗涤剂，液体闪光剂，消毒剂等。
Alfa Aesar:芴,98+% Fluorene, 98+%(86-73-7)
方法一:在高温焦油中的芴约含1.0-2.0%。从洗油馏分中切取290-310℃的芴馏分段，用相当于115块理论塔板的蒸馏塔进行精密分馏，回流比为15：1，切取292-302℃窄馏分。通过冷却，结晶，离心分离，得到粗芴，再用1：25的苯或二甲苯重结晶，则得工业芴。将工业芴溶于苯中，用40%的硫酸洗涤，再经中和水洗，脱溶，将芴重新蒸馏，馏出物用汽油和乙醇重结晶，得纯度为95%的纯芴。
溶于水，溶于醇、乙醚、苯和二硫化碳，易溶于冰醋酸。
Acros Organics:芴 Fluorene, 98%(86-73-7)
Hazard Note:Harmful
芴价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 C156130250 芴;二苯并五环;甲基联苯;2,2′-亚甲基联苯;邻亚联苯基甲烷 25g 285元 2011/08/23 K4688001 芴;二苯并五环;甲基联苯;2,2′-亚甲基联苯;邻亚联苯基甲烷 100g 608元 2011/08/23 xp400158 芴;二苯并五环;甲基联苯;2,2′-亚甲基联苯;邻亚联苯基甲烷 5g 130元
下游产品:9,9-二甲基-2-溴芴 --> 2-氨基-9,9-二甲基芴 --> 厄贝沙坦 --> 2-硝基芴 --> Fmoc-O-叔丁基-L-酪氨酸 --> 2-乙酰芴 --> FMOC-O-叔丁基-L-丝氨酸 --> N-芴甲氧羰基-L-天冬氨酸-4-叔丁酯 --> Fmoc-O-叔丁基-L-苏氨酸 --> Fmoc-L-天冬酰胺 --> Fmoc-O-叔丁基-L-谷氨酸
海关编码:29029080
MSDS 信息:o-Biphenylenemethane(86-73-7).msds