CAS 822-06-0 MFCD00002047-Hexamethylene diisocyanate 六亚甲基二异氰酸酯 TAO{mole}

Hexamethylene diisocyanate 六亚甲基二异氰酸酯

CAS 822-06-0 MFCD00002047

化学结构图

SMILES: O=C=NCCCCCCN=C=O

化学属性

Mol. Formula	C8H12N2O2
Mol. Weight	168
Refractive index	1.4510 to 1.4540
Boiling Point	255
Density	1.04
Flash Point	138°C(lit.)
TSCA	Yes
Melting Point	-67°C
Vapor Pressure	0.05 mmHg ( 25 °C)
Solubility	起反应
Stability	对湿度和热敏感

别名和识别编码

Chemical Name	Hexamethylene diisocyanate
Synonym	1,6-diisocyanato-hexane TL 78 Hexamethylen-1,6-diisocyanat 1,6-hexamethylene-diisocyanate Hexamethylene 1,6-diisocyanate 1,6-己二异氰酸酯, 六甲撑二异氰酸酯, 异氰酸六亚甲酯 1,6-亚己基二异氰酸酯 Desmodur H Isocyanic acid, hexamethylene ester desmodurh HMDI 1,6-己二异氰酸酯 {Ch 1,6-己二异氰酸酯; 二异氰酸六亚甲基酯; 1,6-二异氰酰己烷亚己基-1,6-二异氰酸酯 1,6-Hexylene diisocyanate HEXAMETHYLENE DIISOCYANATE Hexamethylene-1,6-diisocyanate 异氰酸六亚甲酯 1,6-hexylenediisocyanate Hexamethylenediisocyanate 1,6-亚已基二异氰酸酯六亚甲基二异氰酸酯 hexanediyl diisocyanate 六亚甲基二异氰酸酯
CAS Number	822-06-0
PubChem Substance ID	87570744
EC Number	212-485-8
Beilstein Registry Number	956709
MDL Number	MFCD00002047
Reaxys-RN	956709
Chemical Name Translation	六亚甲基二异氰酸酯
Wiswesser Line Notation	OCN6NCO
LabNetwork Molecule ID	LN00223697
InChI	InChI=1S/C8H12N2O2/c11-7-9-5-3-1-2-4-6-10-8-12/h1-6H2

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产品应用

HDI系是脂肪族二异氰酸酯（ADI）中最重要的单体。

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H331 Toxic if inhaled 吸入中毒
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
H335 May cause respiratory irritation 可能导致呼吸道刺激
H319 Causes serious eye irritation 严重刺激眼睛
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H302 Harmful if swallowed 吞食有害
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H330 Fatal if inhaled 吸入致命

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes T+ T

RTECSMO1740000

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P303+P361+P353
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P304+P340+P310
P305+P351+P338
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
P403+P233
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P305+P351+P338+P310
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P301+P330+P331+P310
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P305+P351+
P301+P330+P331
P308+P311
P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。

Signal word

UN Number

Storage condition Moisture Sensitive 储存温度2-8℃，充氩保存 2-8°C 0-10°C 0-10 储存温度2-8°C

Risk Statements

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时，佩带适当的呼吸器；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；

Packing GroupII

Hazard Class6.1

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 710 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 30 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,74,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 350 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TAKHAA Takeda Kenkyusho Ho.  Journal of the Takeda Research Laboratories.
   (Takeda Yakuhin Kogyo K.K., 2-17-85 Jusohon-machi, Yodogawa-ku, Osaka 532,
   Japan)  V.29-    1970-  Volume(issue)/page/year: 39,202,1980

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 60 mg/m3/4H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Lungs, Thorax, or Respiration - dyspnea
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdun

其他信息

图谱信息:1,6-己二异氰酸酯(822-06-0)质谱(MS) 1,6-己二异氰酸酯(822-06-0)核磁图( 13 CNMR) 1,6-己二异氰酸酯(822-06-0)核磁图( 1 HNMR) 1,6-己二异氰酸酯(822-06-0)红外图谱(IR1) 1,6-己二异氰酸酯(822-06-0)Raman光谱 1,6-己二异氰酸酯(822-06-0)红外图谱(IR2)
用途一:用作生产聚氨酯涂料的原料，同时也用作干性醇酸树脂交联剂和合成纤维的原料
Acros Organics:六亚甲基二异氰酸酯 1,6-Diisocyanatohexane, 99+%(822-06-0)
Sigma Aldrich:822-06-0(sigmaaldrich)
蒸气压:0.05 mm Hg ( 25 °C)
敏感性:Moisture Sensitive
方法一:1.己二胺与二氧化碳或盐酸反应生成己二胺碳酸盐或盐酸盐，再经光化反应，然后经蒸馏除去溶液，经精馏得HDI。HDI与水和催化剂反应合成HDI缩二脲，然后经薄膜蒸发器蒸发，脱除残余HDI，加入溶纤剂配制成固含量75%的溶液，即得HDI缩二脲作为高档油漆用原料。每吨产品消耗已二胺（95%）约1280kg、光气4700kg。2.利用己二酸副产物己二酸盐酸盐与光气在溶剂氯苯中反应生成六亚甲基-1,6-二异氰酸酯，再经蒸馏脱溶剂及减压分馏制得成品。
外观性质:无色透明液体, 具有刺激性。
上游原料:乙醚 --> 四氢呋喃 --> 氨 --> 己二酸 --> 叠氮磷酸二苯酯 --> 1,6-已烷二胺 --> 薄膜蒸发器 --> 油漆 --> 缩二脲 --> 辛二酸 --> 1,8-双二甲氨基萘
F:10-19-21
TCI Shanghai:1,6-二异氰酰己烷 Hexamethylene Diisocyanate,>;98.0%(GC)(822-06-0)
稍有刺激性臭味，易燃。不溶于冷水，溶于苯、甲苯、氯苯等有机溶剂，与醇、酸、胺能反应，遇水、碱会分解。在铜、铁等金属氯化物存在下能聚合
1,6-己二异氰酸酯价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 H0324 二异氰酸六亚甲基酯 Hexamethylene Diisocyanate 25ML 137元 2014/06/02 H0324 二异氰酸六亚甲基酯 Hexamethylene Diisocyanate 500ML 574元 2010/06/21 115190250 1,6-己二异氰酸酯 1,6-Diisocyanatohexane 99+% 25 GR 300元
MSDS 信息:六甲撑二异氰酸酯(822-06-0).msds
海关编码:29291090
下游产品:二异氰酸酯改性的EAM树脂用作口腔正畸胶粘剂 --> CC-2SH胶粘剂前牙复合树脂
用途三:HDI系是脂肪族二异氰酸酯（ADI）中最重要的单体。
用途二:HDI系是脂肪族二异氰酸酯（ADI）中最重要的单体，约占ADI总需求量的60%。大部分HDI被制备成HDI缩二脲或HDI三聚体。HDI及HDI缩二脲、三聚体是生产聚氨酯涂料及聚氨酯弹性体的重要原料。以HDI 、HDI缩二脲或三聚体为原料生产的聚氨酯涂料，具有不泛黄、耐候性强等特点，广泛用于航空、汽车、建筑、木器、塑料、皮革等方面。该产品也用作干性醇酸树脂交联剂和合成纤维的原料
MOL 文件:822-06-0.mol
Alfa Aesar:1,6-二异氰酰基己烷,98+% 1,6-Diisocyanatohexane, 98+%(822-06-0)