CAS 81-64-1 MFCD00001209-Quinizarin 醌茜 TAO{mole}

Quinizarin 醌茜

CAS 81-64-1 MFCD00001209

化学结构图

SMILES: O=C1c2ccccc2C(=O)c2c(O)ccc(O)c21

化学属性

Mol. Formula	C14H8O4
Mol. Weight	240.21
Melting Point	195-200 °C
Flash Point	222°(431°F)
TSCA	Yes
Boiling Point	198-199°C at 760 mmHg
Vapor Density	8.3 (vs air)
Vapor Pressure	1 mmHg ( 196.7 °C)
Solubility	<1 G/L (20 ºC)
Density	1.54
Appearance	从醋酸中析出者为橙色结晶。适量溶于乙醇呈红色，溶于乙醚呈棕色及黄色荧光，溶于苛性碱液和氨呈紫色。 powder

别名和识别编码

Chemical Name	Quinizarin
Synonym	Quinizarin {LY} Quinizarin {} {LY} Quinizarin {} {} {LY} Quinizarin {} {} {} {LY} Quinizarin {} {} {} {} {LY} Quinizarin {} {} {} {} {} {LY} Quinizarin {} {} {} {} {} {} {LY} Quinizarin {} {} {} {} {} {} {} {LY} Quinizarin {} {} {} {} {} {} {} {} {LY} Quinizarin {} {} {} {} {} {} {} {} {} {LY} Quinizarin {} {} {} {} {} {} {} {} {} {} {LY} Quinizarin {} {} {} {} {} {} {} {} {} {} {} {LY} Quinizarin {} {} {} {} {} {} {} {} {} {} {} {} {LY} Quinizarin {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Quinizarin {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Quinizarin {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Quinizarin {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Quinizarin {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Quinizarin {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Quinizarin {} {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number	81-64-1
PubChem Substance ID	6688
EC Number	201-368-7
Beilstein Registry Number	1914036
MDL Number	MFCD00001209
Reaxys-RN	1914036
Merck Number	8064
Chemical Name Translation	1,4-二羟基蒽醌
Wiswesser Line Notation	L C666 BV IVJ DQ GQ
InChI	InChI=1S/C14H8O4/c15-9-5-6-10(16)12-11(9)13(17)7-3-1-2-4-8(7)14(12)18/h1-6,15-16H
LabNetwork Molecule ID	LN00224682
Canonical SMILES	O=C1C2=C(C=CC=C2)C(C3=C(O)C=CC(O)=C13)=O

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品牌质保精细包装现货库存一流品牌服务

产品应用

有机合成，制造蒽醌还原染料及其他中间体。本身为分散棕GL（C.I.58050）。

安全信息

GHS Symbol

WGK Germany2

Hazard statements

H320 Causes eye irritation 刺激眼睛
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。

Personal Protective Equipment Eyeshields, Faceshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

RTECSCB6600000

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P305+P351+P338+P337+P313
P308+P313
P337+P313
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Warning

Safety Statements

S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Hazard Codes 9

Risk Statements

R50/53

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C,

Packing GroupIII

UN Number 3077

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >10 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 55(7),93,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 320 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03274

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD-A067-313

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 21(12),27,1977

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 40,203,1976

其他信息

上游原料:硫酸 --> 苯酐 --> 1,4-苯二酚 --> 硼酸 --> 4-氯苯酚
常规方法:用铁桶内衬塑料袋包装。每桶净重20～50kg。贮存在干燥、通风处。应防晒、防潮。按危险物品规定贮运。
MOL 文件:81-64-1.mol
方法二:苯酐和对苯二酚在硼酸存在下于浓硫酸中缩合，再经稀释、水洗、中和、氧化、压滤，得成品。原料消耗定额：对苯二酚550kg/t、苯酐1280kg/t、硼酸550kg/t、硫酸4300kg/t。
下游产品:1,4-二氨基蒽醌 --> 酸性蓝80 --> 1,4-二氨基蒽醌隐色体 --> 酸性媒介灰 BS --> 弱酸嫩黄G --> 分散蓝 3 --> 弱酸绿GS --> 酸性绿 25 --> 透明蓝 --> 溶剂蓝 36 --> 溶剂蓝 104 --> 溶剂绿 3 --> 溶剂蓝 35 --> 溶剂紫 13 --> 溶剂蓝 97 --> C.I.酸性绿27 --> 溶剂蓝 122 --> 溶剂蓝 59 --> 酸性紫43 --> 分散蓝 14 --> 分散染料
方法一:以苯酐和对氯苯酚为原料，将两者缩合、闭环，经水解得产物。经过滤、干燥、粉碎得成品。也可以苯酐和对苯二酚为原料，经缩合、闭环得产物。经过滤、干燥、粉碎得成品。
在高真空中升华。1g溶于13g的沸冰乙酸。溶于乙醇呈红色，溶于乙醚呈棕色并显黄色荧光，溶于碱和氨水呈紫色。遇二氧化碳生成黑色沉淀。有刺激性。
用途二:透明橙 2G 主要用于油品着色。也可用于各种塑料，树脂及其制品着色。
MSDS 信息:1,4-Dihydroxy-9,10-anthracenedione(81-64-1).msds
TCI Shanghai:1,4-二羟基蒽醌 Quinizarin,>;95.0%(LC)(81-64-1)
Alfa Aesar:1,4-二羟基蒽醌,96% 1,4-Dihydroxyanthraquinone, 96%(81-64-1)
用途四:有机合成，制造蒽醌还原染料及其他中间体。本身为分散棕GL（C.I.58050）。
1,4-二羟基蒽醌价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 30062780 1，4-二羟基蒽醌;1,4-二羟基-9,10-蒽二酮 25g 52元 2011/08/23 30062781 1，4-二羟基蒽醌;1,4-二羟基-9,10-蒽二酮 25g 49元 2011/04/16 D0243 醌茜 Quinizarin 25G 146元
用途一:用于制造还原染料、分散染料及活性染料的中间体
图谱信息:1,4-二羟基蒽醌(81-64-1)质谱(MS) 1,4-二羟基蒽醌(81-64-1)核磁图( 13 CNMR) 1,4-二羟基蒽醌(81-64-1)红外图谱(IR1) 1,4-二羟基蒽醌(81-64-1)核磁图( 1 HNMR) 1,4-二羟基蒽醌(81-64-1)红外图谱(IR2)
用途三:该品是重要的染料中间体。本身为分散棕GL（C.I.58050）。用来制造分散蓝HSR、分散蓝5R、分散蓝B、分散深蓝RB、酸性蒽醌蓝R、弱酸艳蓝RAW弱酸绿GS、还原灰BG、还原棕BR等；以及用来生产中间体1,4-二氨基蒽醌。由1,4-二羟基醌经磺化可得1,4-二羟基蒽醌-2-磺酸。
Sigma Aldrich:81-64-1(sigmaaldrich)
color:red-brown
蒸气密度:8.3 (vs air)
蒸气压:1 mm Hg ( 196.7 °C)
防护措施:毒性和蒽醌相似。燃烧时火焰带有腐蚀性。对皮肤能引起过敏。操作人员应穿戴防护用具。当皮肤与之接触时需用大量水冲洗。参见“蒽醌”。
Acros Organics:1,4-二羟基蒽醌 1,4-Dihydroxyanthraquinone, 96%(81-64-1)
色指数:58050