Triisopropylsilyl trifluoromethanesulfonate 三异丙基甲硅烷基三氟甲烷磺酸盐
CAS 80522-42-5 MFCD00009913
化学结构图
SMILES: CC(C)[Si](OS(=O)(=O)C(F)(F)F)(C(C)C)C(C)C
化学属性
| Mol. Formula | C10H21F3O3SSi |
|---|---|
| Mol. Weight | 306 |
| Density | 1.14 |
| Refractive index | 1.4130 to 1.4160 |
| Flash Point | 100°C(lit.) |
| TSCA | No |
| Boiling Point | 45-46 |
| pH | :A |
别名和识别编码
| Chemical Name | Triisopropylsilyl trifluoromethanesulfonate |
|---|---|
| MDL Number | MFCD00009913 |
| Synonym | TRI ISOPROPYLSILYL TRIFLUOROMETHANESULPHONATE 98% TRIISOPROPYLSILYL TRIFLATE TIPS-OTF TRIISOPROPYLSILYL TRIFLUOROMETHANESULFONATE 97% TRIISOPROPYLSILYL TRIFLUOROMETHANESULFONATE TIPS TRIFLATE TIPS triflate, Trifluoromethanesulfonic acid triisopropylsilyl ester, Triisopropylsilyl triflate, Wacker Silane IP3-triflate TRIFLUOROMETHANESULFONIC ACID TRIISOPROPYLSILYL ESTER TRIISOPROPYLSILYL TRIFLUOROMETHANESULPHONATE TIPS 三氟甲磺酸酯 三异丙基甲硅烷基三氟甲磺酸酯 三氟甲磺酸三异丙基硅基酯 TIPS-OTf Triisopropyl(trifluoromethylsulfonyloxy)silane WACKER SILANE IP3-TRIFLATE TIPS triflate, Trifluoromethanesulfonic acid triisopropylsilyl ester, Triisopropylsilyl triflate 三异丙基硅基三氟甲磺酸酯 SILANE IP3-TRIFLATE |
| EC Number | 000-000-0 |
| CAS Number | 80522-42-5 |
| Beilstein Registry Number | 3591541 |
| PubChem Substance ID | 87577345 |
| Reaxys-RN | 3591541 |
| Chemical Name Translation | 三异丙基甲硅烷基三氟甲烷磺酸盐 |
| LabNetwork Molecule ID | LN00009591 |
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分类
- {SNA} Chemical Synthesis, Protecting and Derivatizing Reagents, Protection and Derivatization, Silicon-Based, Synthetic Reagents
相关文献及参考
- A method for protecting both H atoms of a primary amine consists of formation of the succinimide, followed by enolsilylation with TIPS-OTf, to form the 2,5-bis(triisopropylsiloxy)pyrroles. Deprotection can be effected by desilylation with dilute HCl, followed by hydrazinolysis: Tetrahedron Lett., 38, 2617 (1997).
- For a comprehensive review of the TIPS group in organic chemistry, see: Chem. Rev., 95, 1009 (1995).
- Reagent for introduction of the triisopropylsilyl (TIPS) group: Tetrahedron Lett., 22, 3455 (1981); compare Chlorotriisopropylsilane, A17376, and Appendix 4. For general reactions of silyl triflates, see Trimethylsilyl trifluoromethanesulfonate, A12535.
- For use in the synthesis of 2-substituted benzothiopyran-4-ones, see: Synlett, 182 (1996):
安全信息
- R34 Causes burns 会导致灼伤
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P303+P361+P353+P310+P363
- P304+P340
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
其他信息
- Sigma Aldrich:80522-42-5(sigmaaldrich)
