2,2,2-Trifluoroethylamine 2,2,2-三氟乙基胺

CAS 753-90-2 MFCD00008132

化学结构图

753-90-2
SMILES: NCC(F)(F)F

化学属性

Mol. FormulaC2H4F3N
Mol. Weight99
Boiling Point37°C
TSCAT
Density1.26
Refractive index1.3000 to 1.3020
Flash Point-17°C(lit.)
Vapor Pressure~7.6 psi ( 20 °C)
Appearance 无色透明液体,密度 1.24,沸点 37-38℃,折射率 1.3-1.302,闪点 -16℃

别名和识别编码

Chemical Name2,2,2-Trifluoroethylamine
CAS Number753-90-2
Alfabeta NameTRIFLUOROETHYLAMINE 222-,,
MDL NumberMFCD00008132
Synonym 1-trifluoro-2-amino-ethane 2,2,2-TRIFLUOROETHANAMINE 2,2,2-TRIFLUOROETHYLAMINE 2,2,2-Trifluoro-1-ethanamine 2,2,2-Trifluoroethanamine 2,2,2-Trifluoroethyl amine 2,2,2-Trifluoroethylamine, 99.50% 2,2,2-Trifluoroethylamine99% 2,2,2-trifluoro-ethanamin 2,2,2-trifluoro-ethylamine 2,2,2-trifluoroethylamine 2,2,2-三氟乙胺 2-氨基-1,1,1-三氟乙烷 2,2,2-三氟乙基胺 AURORA KA-7828 CF3CH2NH2 Ethanamine, 2,2,2-trifluoro- RARECHEM AL BW 0451 Trifluoroethylamine beta,beta,beta-Trifluoroethylamine trifluoroethylamine 三氟乙胺
EC Number212-041-3
Beilstein Registry Number1733204
PubChem Substance ID9773
Reaxys-RN1733204
Chemical Name Translation2,2,2-三氟乙基胺
InChIKeyKIPSRYDSZQRPEA-UHFFFAOYSA-N
Wiswesser Line NotationZ1XFFF
LabNetwork Molecule IDLN00008843
InChIInChI=1S/C2H4F3N/c3-2(4,5)1-6/h1,6H2
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分类

  • {SNA} Amines, Building Blocks, C2 to C5, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: II/24C
  • Highly effective catalyst for the isomerization of ß-unsaturated ketones to ɑß-unsaturated ketones: J. Am. Chem. Soc., 97, 952 (1975).
  • Beilstein: 4,IV,442
  • Short: II/24B

安全信息

Warnings IRRITANT-HARMFUL, FLAMMABLE, CORROSIVE
Signal word
GHS Symbol
WGK Germany3
Safety Statements
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R11 Highly flammable 非常易燃
  • R52/53
  • R22 Harmful if swallowed 吞咽有害
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSKS0175000
Packing GroupII
UN Number UN 2733 3/PG 2 UN2733 2733
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
Hazard Codes F,C
Storage condition 0-10 0-10°C 2-8°C
Hazard Class3/8
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 4170 mg/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,606,1986

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >250 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 2,184,1950

其他信息

  • 上游原料:氢氧化钠 --> 盐酸 --> 乙醚 --> 氢化铝锂 --> 2,2,2-三氟乙酰胺
  • 检测方法:GC
  • F:3-10-13
  • TSCA:T
  • TCI Shanghai:2,2,2-三氟乙胺 2,2,2-Trifluoroethylamine,>;97.0%(GC)(753-90-2)
  • Acros Organics:2,2,2-三氟乙胺 2,2,2-Trifluoroethylamine, 99.50%(753-90-2)
  • Alfa Aesar:2,2,2-三氟乙胺,98% 2,2,2-Trifluoroethylamine, 98%(753-90-2)
  • 蒸气压:~7.6 psi ( 20 °C)
  • Hazard Note:Corrosive/Toxic/Flammable
  • MOL 文件:753-90-2.mol
  • 存储注意事项:氮气保护
  • Sigma Aldrich:753-90-2(sigmaaldrich)
  • 2,2,2-三氟乙基胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1169 2,2,2-三氟乙胺 2,2,2-Trifluoroethylamine 25G 3700元 2014/06/02 T1169 2,2,2-三氟乙胺 2,2,2-Trifluoroethylamine 5G 1130元 2010/06/21 303500500 2,2,2-三氟乙基胺 2,2,2-Trifluoroethylamine 99.5% 50 GR 11188元

系列性分类