CAS 74-94-2 MFCD00051068-Dimethylaminoborane 硼烷二甲胺络合物 TAO{mole}

Dimethylaminoborane 硼烷二甲胺络合物

CAS 74-94-2 MFCD00051068

化学结构图

SMILES: [BH3-][NH+](C)C

化学属性

Mol. Formula	C2H7N.BH3
Mol. Weight	58.92 g/mol
Melting Point	36 °C
Density	0.69
TSCA	Yes
Boiling Point	59-65 °C at 12 mmHg
Flash Point	43°C
Solubility	125 G/L (20 ºC)
Stability	对湿度敏感;热和空气敏感

别名和识别编码

Chemical Name	Dimethylaminoborane
Synonym	Borane dimethylamine complex Dimethylamine Borane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number	74-94-2
PubChem Substance ID	87568308
EC Number	200-823-7
MDL Number	MFCD00051068
Reaxys-RN	4132650
Beilstein Registry Number	4132650
Chemical Name Translation	硼烷二甲胺络合物
InChIKey	FTDUHBOCJSQEKS-UHFFFAOYSA-N
LabNetwork Molecule ID	LN01330569
Canonical SMILES	[H-][B+3]([H-])(N(C)C)[H-]

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产品应用

用于镍催化的缺电子芳基甲苯磺酸盐的还原反应，催化剂由Ni(PPh3)2Cl2和 PCy3组成。
二甲胺硼烷是一个良好的还原剂，是蛋白质的烷化还原试剂；与硼氢化钠相比，有以下优点：还原作用温和，可在广泛的pH值范围内应用，且能较好的溶于水及有机溶剂。

安全信息

GHS Symbol

WGK Germany2

Hazard Codes 4.1 F,T F;T

Hazard statements

H228 Flammable solid 易燃固体
H301+H311

Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

RTECSIP9450000

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P301+P330+P331+P310
P303+P361+P353
P304+P340
P305+P351+P338+P310
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

UN Number 2926

Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture Store at room temperature, keep dry and cool {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed sto

Safety Statements

S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S20 When using do not eat or drink 使用时，不得进食，饮水；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S4 Keep away from living quarters 远离生活区；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；

Risk Statements

R11 Highly flammable 非常易燃
R20 Harmful by inhalation 吸入有害
R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Packing GroupII

Hazard Class4.1/6.1

其他信息

MOL 文件:74-94-2.mol
二甲胺基甲硼烷价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 D1842 二甲氨基甲硼烷 Dimethylamine Borane 500G 1520元 2014/06/02 D1842 二甲氨基甲硼烷 Dimethylamine Borane 25G 180元 2010/06/21 177311000 二甲胺基甲硼烷 Borane-dimethylamine complex 98+% 100 GR 1765元
敏感性:Air & Moisture Sensitive
外观性质:白色结晶，略有氨气味。易吸潮。水中溶解度:125 G/L (20°C)，溶于甲醇、乙醇、２－丙醇、THF、苯、甲苯、N-HEX、氯苯和二甘醇二甲醚（DIGLYME）。沸点：59-65°/1-2mmHg熔点：36℃闪点：65℃
MSDS 信息:Borane-dimethylamine complex(74-94-2).msds
TCI Shanghai:二甲胺基甲硼烷 Dimethylamine Borane,>;95.0%(T)(74-94-2)
F:10
Sigma Aldrich:74-94-2(sigmaaldrich)
略有氨气味。易吸潮。水中溶解度:125 G/L (20°C)，溶于甲醇、乙醇、２－丙醇、THF、苯、甲苯、N-HEX、氯苯和二甘醇二甲醚（DIGLYME）。
Acros Organics:二甲基胺基硼烷 Borane-dimethylamine complex, 98+%(74-94-2)
海关编码:29420000
Alfa Aesar:Borane-dimethylamine complex, 97%(74-94-2)
用途一:用于镍催化的缺电子芳基甲苯磺酸盐的还原反应，催化剂由Ni(PPh3)2Cl2和 PCy3组成。二甲胺硼烷是一个良好的还原剂，是蛋白质的烷化还原试剂；与硼氢化钠相比，有以下优点：还原作用温和，可在广泛的pH值范围内应用，且能较好的溶于水及有机溶剂。