2-Bromo-4-methylphenol 2-溴-4-甲基苯酚

CAS 6627-55-0 MFCD00002151

化学结构图

6627-55-0
SMILES: Cc1ccc(O)c(Br)c1

化学属性

Mol. FormulaC7H7BrO
Mol. Weight187.03
Density1.547
Refractive index1.5760 to 1.5820
Flash Point>110°(230°F)
TSCAYes
Boiling Point213-214°C at 760 mmHg
Melting Point54-55 °C
Stability对空气敏感

别名和识别编码

Chemical Name2-Bromo-4-methylphenol
CAS Number6627-55-0
Alfabeta NameBROMOMETHYLPHENOL 24---
MDL NumberMFCD00002151
Synonym 2-Bromo-4-methylphenol {LY} 2-Bromo-4-methylphenol {} {LY} 2-Bromo-4-methylphenol {} {} {LY} 2-Bromo-4-methylphenol {} {} {} {LY} 2-Bromo-4-methylphenol {} {} {} {} {LY} 2-Bromo-4-methylphenol {} {} {} {} {} {LY} 2-Bromo-4-methylphenol {} {} {} {} {} {} {LY} 2-Bromo-4-methylphenol {} {} {} {} {} {} {} {LY} 2-Bromo-4-methylphenol {} {} {} {} {} {} {} {} {LY} 2-Bromo-4-methylphenol {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-4-methylphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-4-methylphenol {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-4-methylphenol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-4-methylphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-4-methylphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-4-methylphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-4-methylphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromo-4-methyl
EC Number229-595-7
PubChem Substance ID23109
Reaxys-RN1859036
Beilstein Registry Number6,405
Chemical Name Translation2-溴-4-甲基苯酚
InChIKeyMTIDYGLTAOZOGU-UHFFFAOYSA-N
LabNetwork Molecule IDLN00011250
InChIInChI=1S/C7H7BrO/c1-5-2-3-7(9)6(8)4-5/h2-4,9H,1H3
Canonical SMILESCC1=CC(Br)=C(O)C=C1
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分类

  • {SNA} Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; alcohol; 1fragment

相关文献及参考

  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.

安全信息

Warnings IRRITANT
RTECSGO6868200
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
Signal word
Hazard Codes Xn Xi Xi,Xn
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 195 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JMCMAR Journal of Medicinal Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC
   20037)  V.6-    1963-  Volume(issue)/page/year: 18,868,1975

其他信息

  • 上游原料:稀硫酸 --> 4-甲基苯酚 --> 2-溴-4-甲基苯胺
  • 2-溴-4-甲基苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0808 2-溴对甲基苯酚 2-Bromo-p-cresol 500G 6900元 2014/06/02 B0808 2-溴对甲基苯酚 2-Bromo-p-cresol 25G 991元 2010/06/21 107140250 2-溴-4-甲基苯酚 2-Bromo-4-methylphenol 96% 25 GR 1119元
  • MOL 文件:6627-55-0.mol
  • MSDS 信息:2-Bromo-4-methylphenol(6627-55-0).msds
  • Sigma Aldrich:6627-55-0(sigmaaldrich)
  • Alfa Aesar:2-溴-4-甲基苯酚,97% 2-Bromo-4-methylphenol, 97%(6627-55-0)
  • 方法一:由2-溴-4-甲基苯胺重氮化、水解而得。将稀硫酸加到2-溴-4-甲基苯胺中,搅拌冷却,在5℃以下加入亚硝酸钠水溶液,温度保持在5℃以下,然后再加冷水、尿素和碎冰,得重氮盐溶液。再将无水硫酸钠、浓硫酸和水加热,在130-135℃分批加入重氮盐溶液,然后分批加入水进行蒸馏,所得馏出液用乙醚萃取,用10%碳酸氢钠溶液洗涤,再经无水硫酸钠干燥,过滤,滤液蒸去乙醚而得成品。另一种方法是由对甲苯酚在氯仿溶剂中直接溴化。
  • 用途一:有机合成中间体。
  • TCI Shanghai:2-溴-4-甲基苯酚 2-Bromo-p-cresol,>;98.0%(GC)(6627-55-0)
  • Hazard Note:Irritant
  • 图谱信息:2-溴-4-甲基苯酚(6627-55-0)Raman光谱 2-溴-4-甲基苯酚(6627-55-0)核磁图( 1 HNMR) 2-溴-4-甲基苯酚(6627-55-0)质谱(MS) 2-溴-4-甲基苯酚(6627-55-0)红外图谱(IR1) 2-溴-4-甲基苯酚(6627-55-0)核磁图( 13 CNMR)
  • Acros Organics:2-溴-4-甲基苯酚 2-Bromo-4-methylphenol, 96%(6627-55-0)

系列性分类


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