CAS 624-84-0 MFCD00007589-Formylhydrazine 甲酰肼 TAO{mole}

Formylhydrazine 甲酰肼

CAS 624-84-0 MFCD00007589

化学结构图

SMILES: NNC=O

化学属性

Mol. Formula	HCONHNH2
Mol. Weight	60
Melting Point	52-57
Flash Point	>110°(230°F)
TSCA	Yes
Density	1.325
Solubility	可溶
Stability	易吸潮
Appearance	黄色叶状体或针状体结晶。熔点54℃。溶于苯，乙醇，乙醚，氯仿。
Boiling Point	90°C/0.7mmHg(lit.)

别名和识别编码

Chemical Name	Formylhydrazine
Synonym	Ameisensäurehydrazid FORMIC HYDRAZIDE FORMOHYDRAZIDE Formhydrazide Formic acid hydrazide Formic hydrazide Formylhydrazine Hydrazinecarboxaldehyde- N-Formylhydrazine formyl-hydrazin hydrazinecarboxaldehyde 甲酰肼
CAS Number	624-84-0
PubChem Substance ID	12229
EC Number	210-867-9
Beilstein Registry Number	635759
MDL Number	MFCD00007589
Chemical Name Translation	甲酰肼
Wiswesser Line Notation	ZMVH
LabNetwork Molecule ID	LN00005809
Reaxys-RN	635759
InChI	InChI=1S/CH4N2O/c2-3-1-4/h1H,2H2,(H,3,4)

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安全信息

GHS Symbol

WGK Germany3

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes Xn Xi Xi,Xn

RTECSLQ8615000

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P305+P351+P338
P305+P351+P338+P337+P313

Signal word Warning

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S37 Wear suitable gloves 戴适当手套；

Risk Statements

R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Storage condition Hygroscopic 易吸潮 0-10°C 2-8°C

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 73 gm/kg/43W-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   BJCAAI British Journal of Cancer.  (Macmillan Press Ltd., Houndmills,
   Basingstoke, Hants. RG21 2XS, UK)  V.1-    1947-  Volume(issue)/page/year:
   37,960,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 65 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JMPCAS Journal of Medicinal and Pharmaceutical Chemistry.  (Washington, DC)
   V.1-5, 1959-62.  For publisher information, see JMCMAR.
   Volume(issue)/page/year: 4,259,1961

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 120 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARZNAD Arzneimittel-Forschung. Drug Research.  (Editio Cantor Verlag,
   Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.)  V.1-    1951-
   Volume(issue)/page/year: 18,645,1968

其他信息

用途一:用于有机合成。
图谱信息:甲酰肼(624-84-0)核磁图( 13 CNMR) 甲酰肼(624-84-0)红外图谱(IR2) 甲酰肼(624-84-0)红外图谱(IR1) 甲酰肼(624-84-0)核磁图( 1 HNMR) 甲酰肼(624-84-0)红外图谱(IR3)
下游产品:硫代卡巴肼 --> 4-氨基-1,2,4-三氮唑
MSDS 信息:Formic acid hydrazide(624-84-0).msds
甲酰肼价格(试剂级):更新日期产品编号产品名称包装价格 2010/06/21 376060250 甲酰肼 Formic acid hydrazide 90% 25 GR 471元 2010/06/21 376061000 甲酰肼 Formic acid hydrazide 90% 100 GR 1484元 2010/05/25 A14901 甲酸肼, 98% Formic acid hydrazide, 98% 25g 491元
F:3-8-10
方法一:由甲酸乙酯与水合肼反应则得。将85%水合肼小心地加入甲酸乙酯和95%乙醇的溶液中，搅拌10min。当反应缓和后，将反应液加热回流18h，减压蒸出大部分水分和乙醇，即得糖浆状物粗品，进一步精制得到甲酰肼成品。
溶于水
敏感性:Hygroscopic
Alfa Aesar:甲酸肼,98% Formic acid hydrazide, 98%(624-84-0)
上游原料:乙醇 --> 糖浆
Sigma Aldrich:624-84-0(sigmaaldrich)
MOL 文件:624-84-0.mol
Acros Organics:甲酸肼 Formic acid hydrazide, 95%(624-84-0)