Benzoylhydrazine 苯甲酰肼
CAS 613-94-5 MFCD00007596
信息真实价格透明
资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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现货库存
一流品牌服务
分类
- {SNA} Building Blocks, Carbonyl Compounds, Chemical Synthesis, Hydrazides, Organic Building Blocks
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; amide; 1fragment
- Building Blocks, Carbonyl Compounds, Chemical Synthesis, Hydrazides, Organic Building Blocks
产品应用
- 有机合成。
相关文献及参考
- Short: III/35E
- Bolann, B., et al.: Bio. Chem. J., 243, 55 (1987),
- Short: III/20a
- Metwally, K., et al.: Bio. Med. Chem., 14, 8675 (2006),
- Reacts with aldehydes to form benzoylhydrazones. These have been reported as useful, stable surrogates of unstable imines in allylation, Mannich-type and cyanide addition reactions: J. Org. Chem., 64, 8054 (1999).
- Hydrazides can be reduced to aldehydes with NaBH4 in the presence of CuCl2. For benzhydrazide, an 82% yield was reported: Org. Prep. Proced. Int., 20, 405 (1988).
- Beilstein:9,319
- Mishra, L., et al.: Bio. Med. Chem., 3, 1241 (1995),
安全信息
GHS Symbol
- H301 Toxic if swallowed 吞食有毒
- H302 Harmful if swallowed 吞食有害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310
- P301+P312+P330
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- R25 Toxic if swallowed 吞咽有毒
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 15 gm/kg/77W-C TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Lungs, Thorax, or Respiration - tumors Blood - lymphoma, including Hodgkin's disease REFERENCE : EJCAAH European Journal of Cancer. (Oxford, UK) V.1-17(6), 1965-1981. For publisher information, see EJCODS. Volume(issue)/page/year: 8,341,1972
TYPE OF TEST : TD - Toxic dose (other than lowest) ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 13 gm/kg/30W-I TOXIC EFFECTS : Tumorigenic - neoplastic by RTECS criteria Lungs, Thorax, or Respiration - tumors REFERENCE : 34ZRA9 "Proceedings of the Quadrennial Conference on Cancer, 3rd, 1965," Severi, L., ed., Perugia, Italy, Univ. of Perugia, 1966 Volume(issue)/page/year: -,869,1965
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 122 mg/kg TOXIC EFFECTS : Behavioral - convulsions or effect on seizure threshold REFERENCE : JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 122,110,1958
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Subcutaneous SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 102 mg/kg TOXIC EFFECTS : Endocrine - hypoglycemia REFERENCE : JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 30,87,1927
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 100 mg/kg TOXIC EFFECTS : Behavioral - altered sleep time (including change in righting reflex) Behavioral - somnolence (general depressed activity) Behavioral - tremor REFERENCE : BJPCAL British Journal of Pharmacology and Chemotherapy. (London, UK) V.1-33, 1946-68. For publisher information, see BJPCBM. Volume(issue)/page/year: 11,417,1956
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Subcutaneous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 122 mg/kg TOXIC EFFECTS : Behavioral - convulsions or effect on seizure threshold REFERENCE : YKKZAJ Yakugaku Zasshi. Journal of Pharmacy. (Nippon Yakugakkai, 2-12-15 Shibuya, Shibuya-ku, Tokyo 150, Japan) No.1- 1881- Volume(issue)/page/year: 81,1225,1961
其他信息
- 储运特性:通风低温干燥; 与库房食品原料分开存放
- 急性毒性:皮下-小鼠 LD50: 122 毫克/公斤; 皮下-兔子 LDL0: 102 毫克/公斤
- 用途一:用于有机合成
- 可燃性危险特性:可燃; 燃烧产生有毒氮氧化物烟雾
- Alfa Aesar:苯酰肼,98% Benzhydrazide, 98%(613-94-5)
- 毒性分级:高毒
- MOL 文件:613-94-5.mol
- Sigma Aldrich:613-94-5(sigmaaldrich)
- 爆炸物危险特性:与苯硒酸反应激烈
- Acros Organics:苯甲酰肼 Benzoylhydrazine, 98%(613-94-5)
- TCI Shanghai:苯甲酰肼 Benzoylhydrazine,>;98.0%(GC)(T)(613-94-5)
- MSDS 信息:Benzoyl hydrazine(613-94-5).msds
- 下游产品:2-(4-溴苯基)-5-苯基-1,3,4-恶二唑 --> 2-(4-联苯基)-5-苯基恶二唑 --> 5-苯基-1,3,4-恶二唑-2-硫醇 --> 盐酸佐柔比星
- 图谱信息:苯甲酰肼(613-94-5)红外图谱(IR2) 苯甲酰肼(613-94-5)核磁图( 1 HNMR) 苯甲酰肼(613-94-5)核磁图( 13 CNMR) 苯甲酰肼(613-94-5)红外图谱(IR1) 苯甲酰肼(613-94-5)Raman光谱 苯甲酰肼(613-94-5)质谱(MS)
- 苯甲酰肼价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0205 苯甲酰肼 Benzoylhydrazine 500G 1980元 2014/06/02 B0205 苯甲酰肼 Benzoylhydrazine 25G 247元 2010/06/21 105771000 苯甲酰肼 Benzoylhydrazine 98% 100 GR 636元
- 海关编码:29280090
- 溶于水和醇,微溶于醚、氯仿、苯、三氯甲烷和丙酮。有毒。
- 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
- 类别:有毒物品