CAS 542-69-8 MFCD00001098-1-Iodobutane 1-碘丁烷 TAO{mole}

1-Iodobutane 1-碘丁烷

CAS 542-69-8 MFCD00001098

化学结构图

SMILES: CCCCI

化学属性

Mol. Formula	C4 H9 I
Mol. Weight	184.02
Refractive index	1.4970 to 1.5010
Vapor Density	~5 (vs air)
Boiling Point
Density	1.617
Melting Point	No Data Available
Flash Point	-
TSCA	Yes
Solubility	不溶于水，溶于醇、醚。
Stability	对光敏感, 对空气敏感

别名和识别编码

Chemical Name	1-Iodobutane
Synonym	1-BUTYLIODIDE 1-Butyljodid 1-IODOBUTANE 1-IODOBUTANE, STAB. 1-Iodbutan 1-Iodobutane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL Number	-
CAS Number	542-69-8
PubChem Substance ID	10962
EC Number	208-824-4
Beilstein Registry Number	1,123
Merck Number	1573
Chemical Name Translation	1-碘丁烷
Reaxys-RN	1420755
Wiswesser Line Notation	I4
LabNetwork Molecule ID	LN00222867
InChI	InChI=1S/C4H9I/c1-2-3-4-5/h2-4H2,1H3
Canonical SMILES	-

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

溶剂。有机合成。

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H226 Flammable liquid and vapour 易燃液体和蒸气
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H331 Toxic if inhaled 吸入中毒

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSEK4400000

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P241+P242+P243
P242 Use only non-sparking tools. 只能使用无火花工具。
P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312
P302+P352
P302+P352+P332+P313+P362+P364
P303+P361+P353
P304+P340
P304+P340+P312
P305+P351+P338
P305+P351+P338+P337+P313
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P316
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P332+P313
P332+P317
P337+P313
P337+P317
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P370+P378
P403+P233
P403+P235
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Packing GroupIII

UN Number 1993

Risk Statements

Safety Statements

S36 Wear suitable protective clothing 穿戴适当的防护服；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；

Storage condition +4°C 4 4°C 4℃ Flammables area Light Sensitive 对光敏感，密封避光保存。

Hazard Codes

Hazard Class3

Warnings 危化品目录(2015)

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 480 mg/kg/8W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   35,1411,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 101 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,30,1982

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 6100 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,756,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 692 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,30,1982

Restrict 危险品

其他信息

海关编码:29033080
毒性分级:中毒
急性毒性:腹腔- 大鼠 LD50: 692 毫克/ 公斤; 腹腔- 小鼠 LD50: 101 毫克/ 公斤
储运特性:库房通风低温干燥; 与氧化剂分开存放
Hazard Note:Harmful
敏感性:Light Sensitive
MSDS 信息:碘代正丁烷(542-69-8).msds
类别:易燃液体
蒸气密度:~5 (vs air)
可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生有毒碘化物烟雾
用途二:用于有机合成或用作分析试剂、溶剂和杀菌剂。
图谱信息:碘丁烷(542-69-8)红外图谱(IR2) 碘丁烷(542-69-8)红外图谱(IR1) 碘丁烷(542-69-8)质谱(MS) 碘丁烷(542-69-8)核磁图( 13 CNMR) 碘丁烷(542-69-8)核磁图( 1 HNMR)
Sigma Aldrich:542-69-8(sigmaaldrich)
下游产品:正丁基二(1-金刚烷基)膦 --> 四丁基硫酸氢铵 --> 光学活性硫代乙酸胺 --> 1-丁烷磺酸钠
方法一:由正丁醇与碘在磷存在下反应而得。将赤磷与正丁醇混合，加热使其微微回流，缓缓加入碘。加完后继续回流4h，蒸馏，得粗品。依次用水、浓盐酸、水、10%碳酸钠溶液和含少量硫代硫酸钠和水洗涤。然后以无水氯化钙干燥，蒸馏，收集129-131℃馏分，即为1-碘丁烷。收率90%。
用途一:用作溶剂
碘丁烷价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80025826 碘代正丁烷 100ml 223元 2011/04/16 I0055 1-碘丁烷(含稳定剂铜屑) 1-Iodobutane (stabilized with Copper chip) 25G 180元 2011/04/16 I0055 1-碘丁烷(含稳定剂铜屑) 1-Iodobutane (stabilized with Copper chip) 500G 1480元
Acros Organics:1-碘丁烷 1-Iodobutane, stabilized, 98%(542-69-8)
TCI Shanghai:1-碘丁烷(含稳定剂铜屑) 1-Iodobutane (stabilized with Copper chip),>;98.0%(GC)(542-69-8)
Alfa Aesar:1-碘丁烷,99%,stab.withcopper 1-Iodobutane, 99%, stab. with copper(542-69-8)
灭火剂:干粉、二氧化碳、泡沫、1211灭火剂
MOL 文件:542-69-8.mol
F:8
外观性质:无色液体。
能与乙醇和乙醚混溶，几乎不溶于水，见光或久置变色。易燃。有刺激性。