CAS 2283-11-6 MFCD00009041-Tris(diethylamino)phosphine 三(二乙氨基)膦 TAO{mole}

Tris(diethylamino)phosphine 三(二乙氨基)膦

CAS 2283-11-6 MFCD00009041

化学结构图

SMILES: CCN(CC)P(N(CC)CC)N(CC)CC

化学属性

Mol. Formula	C12H30N3P
Mol. Weight	247.37
Density	0.903 g/mL at 25 °C(lit.)
Refractive index	1.4710 to 1.4750
Flash Point	59°C
TSCA	Yes
Boiling Point	206.4°C at 760 mmHg
Stability	对空气敏感

别名和识别编码

Chemical Name	Tris(diethylamino)phosphine
Synonym	N,N,N',N',N'',N''-Hexaethylphosphinetriamine {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {
MDL Number	MFCD00009041
CAS Number	2283-11-6
EC Number	218-920-8
Beilstein Registry Number	4,130
PubChem Substance ID	75292
Reaxys-RN	636187
Chemical Name Translation	三(二乙氨基)膦
InChIKey	FDIOSTIIZGWENY-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00192246
InChI	InChI=1S/C12H30N3P/c1-7-13(8-2)16(14(9-3)10-4)15(11-5)12-6/h7-12H2,1-6H3
Canonical SMILES	CCN(CC)P(N(CC)CC)N(CC)CC

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品牌质保精细包装现货库存一流品牌服务

安全信息

Packing GroupIII

UN Number 1993 UN 1993 3/PG 3 UN1993

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S37 Wear suitable gloves 戴适当手套；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；

Storage condition -20°C, protect from light, stored under nitrogen {LY} -20°C, protect from light, stored under nitrogen Air Sensitive {} {LY} -20°C, protect from light, stored under nitrogen {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from lig

GHS Symbol

WGK Germany3

Hazard statements

H226 Flammable liquid and vapour 易燃液体和蒸气
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P242 Use only non-sparking tools. 只能使用无火花工具。
P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P352
P303+P361+P353
P304+P340
P305+P351+P338
P305+P351+P338+P337+P313
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P332+P313
P332+P317
P337+P313
P337+P317
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P370+P378
P403+P233
P403+P235
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Warning

Hazard Codes Xi

Hazard Class3

其他信息

Sigma Aldrich:2283-11-6(sigmaaldrich)
图谱信息:六乙基亚磷酸胺(2283-11-6)红外图谱(IR1) 六乙基亚磷酸胺(2283-11-6)质谱(MS)
上游原料:二乙胺
用途一:用于有机合成。
Alfa Aesar:己乙基亚磷三酰胺,97% Hexaethyl phosphorous triamide, 97%(2283-11-6)
敏感性:Air Sensitive
方法一:将234g（3.2mol）二乙胺溶于500ml乙醚，在5℃搅拌下，于2h内慢慢加入55g（0.4mol）三氯化磷与150ml乙醚的溶液，将混合物搅拌加热回流4h。冷至室温，滤除二乙胺盐酸盐，滤液减压蒸馏。收集120-122℃（1.33kPa）馏分，得成品，收率68%。
F:10-23
Acros Organics:六乙基亚磷酸胺 Hexaethylphosphorus triamide, 95%(2283-11-6)
MOL 文件:2283-11-6.mol
TCI Shanghai:三(二乙胺基)膦 Tris(diethylamino)phosphine,>;90.0%(GC)(2283-11-6)
六乙基亚磷酸胺价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 T1309 三(二乙氨基)膦 Tris(diethylamino)phosphine 25ML 1380元 2014/06/02 T1309 三(二乙氨基)膦 Tris(diethylamino)phosphine 5ML 462元 2010/06/21 423080050 六乙基亚磷酸胺 Hexaethylphosphorus triamide 95% 5 GR 558元