1-Butyl-3-Methylimidazolium Hexafluorophosphate 1-丁基-3-甲基咪唑六氟磷酸盐

CAS 174501-64-5 MFCD03093295

化学结构图

174501-64-5
SMILES: CCCCN1C=[N+](C)C=C1.F[P-](F)(F)(F)(F)F

化学属性

Mol. FormulaC8
Mol. Weight284
Boiling Point>340
Melting PointN\/A6.5
Density1.38
Refractive index1.4090 to 1.4130
TSCANo
Stability易吸潮

别名和识别编码

Chemical Name1-Butyl-3-Methylimidazolium Hexafluorophosphate
CAS Number174501-64-5
Alfabeta NameBUTYLMETHYLIMIDAZOLIUMHEXAFLUOROPHOSPHATE 13---
MDL NumberMFCD03093295
Synonym
EC Number000-000-0
Merck Number1581
Beilstein Registry Number8026031
PubChem Substance ID87565152
Reaxys-RN8026031
Chemical Name Translation1-丁基-3-甲基咪唑六氟磷酸盐
LabNetwork Molecule IDLN00119727
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分类

  • {SNA} Chemical Synthesis, Imidazolium, Ionic Liquids, Specialty Synthesis

产品应用

  • 离子液体,用在许多环保型的反应中。

相关文献及参考

  • Heck reactions with aryl halides can be carried out with controlled microwave heating: J. Org. Chem., 67, 6243 (2002).
  • Merck: 14,1581
  • Ionic liquid.
  • For use in dihydroxylation of alkenes with Osmium(VIII)­ oxide, 12103, facilitating the reuse of the Os catalyst, see: Org. Lett., 4, 2197 (2002).
  • Recyclable medium for oxidation of alcohols, catalyzed by TEMPO, A12733, and CuCl, to give aldehydes and ketones chemoselectively under mild conditions: Org. Lett., 4, 1507 (2002).
  • A copper-free Sonogashira coupling of terminal alkynes with aryl iodides, catalyzed by trans-Dichlorobis(triphenyl­phosphine)­palladium(II)­, 10491, has been adapted to a microflow system for efficient catalyst recycling: Org. Lett., 4, 1691 (2002).

安全信息

Warnings IRRITANT
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
Signal word
GHS Symbol
WGK Germany3
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 6.1 Xi
Packing GroupIII
UN Number
Storage condition 充氩保存

系列性分类


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