2-Methoxypyridine 2-甲氧基吡啶

CAS 1628-89-3 MFCD00006262

化学结构图

1628-89-3
SMILES: COc1ccccn1

化学属性

Mol. FormulaC6H7NO
Mol. Weight109.13
Density1.038
Refractive index1.5000 to 1.5040
Boiling Point142.1°C at 760 mmHg
Flash Point32°C
TSCANo
Solubility不溶
Appearance 淡黄色液体。
pH:A

别名和识别编码

Chemical Name2-Methoxypyridine
Synonym 2-Methoxypyridine {LY} 2-Methoxypyridine {} {LY} 2-Methoxypyridine {} {} {LY} 2-Methoxypyridine {} {} {} {LY} 2-Methoxypyridine {} {} {} {} {LY} 2-Methoxypyridine {} {} {} {} {} {LY} 2-Methoxypyridine {} {} {} {} {} {} {LY} 2-Methoxypyridine {} {} {} {} {} {} {} {LY} 2-Methoxypyridine {} {} {} {} {} {} {} {} {LY} 2-Methoxypyridine {} {} {} {} {} {} {} {} {} {LY} 2-Methoxypyridine {} {} {} {} {} {} {} {} {} {} {LY} 2-Methoxypyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methoxypyridine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methoxypyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methoxypyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methoxypyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Methoxypyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Met
MDL NumberMFCD00006262
CAS Number1628-89-3
EC Number216-623-8
Beilstein Registry Number21,44
PubChem Substance ID87572787
Reaxys-RN108189
Chemical Name Translation2-甲氧基吡啶
LabNetwork Molecule IDLN00223127
InChIInChI=1S/C6H7NO/c1-8-6-4-2-3-5-7-6/h2-5H,1H3
Canonical SMILESCOC1=NC=CC=C1
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分类

  • {SNA} Building Blocks, C6, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines
  • {uni_hamburg} no charge; nitrogen heterocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: II/27B
  • Short: III/35B
  • Can be metallated at the 3-position with LDA at -70o: J. Org. Chem., 53, 1367 (1988). With the unimetal superbase complex formed from 2 mol of n-BuLi and I mol of 2-(Dimethyl­amino)­ethanol, B23616, in hexane, products are obtained resulting from apparent metallation at the 6-position. A radical mechanism, rather than a true 6-metallation, has been proposed for this reaction: J. Chem. Soc., Perkin 1, 3071 (1997). Analogous results have been reported with 2-chloropyridine: Org. Lett., 2, 803 (2000).

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R10 Flammable 易燃
Precautionary statements
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P337+P313
  • P302+P352+P332+P313+P362+P364
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P303+P361+P353
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P403+P235
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P305+P351+P338+P337+P313
  • P241+P242+P243
  • P233 Keep container tightly closed. ?保持容器密闭。
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupIII
UN Number UN3271 1993
Hazard Codes
Hazard Class3
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 2-甲氧基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0788 2-甲氧基吡啶 2-Methoxypyridine 25ML 312元 2010/06/21 126100050 2-甲氧基吡啶 2-Methoxypyridine 98% 5 GR 112元 2010/06/21 126100250 2-甲氧基吡啶 2-Methoxypyridine 98% 25 GR 317元
  • MSDS 信息:2-Methoxypyridine(1628-89-3).msds
  • TCI Shanghai:2-甲氧基吡啶 2-Methoxypyridine,>;96.0%(GC)(1628-89-3)
  • Acros Organics:2-甲氧基吡啶 2-Methoxypyridine, 98%(1628-89-3)
  • Sigma Aldrich:1628-89-3(sigmaaldrich)
  • MOL 文件:1628-89-3.mol
  • Alfa Aesar:2-甲氧基吡啶,98% 2-Methoxypyridine, 98%(1628-89-3)
  • 检测方法:GC,NMR
  • 图谱信息:2-甲氧基吡啶(1628-89-3)红外图谱(IR1) 2-甲氧基吡啶(1628-89-3)质谱(MS) 2-甲氧基吡啶(1628-89-3)核磁图( 13 CNMR) 2-甲氧基吡啶(1628-89-3)核磁图( 1 HNMR)
  • 下游产品:6-甲氧基-3-吡啶甲醛 --> 2-甲氧基-3-吡啶醛 --> 4-氨基-2-甲氧基吡啶 --> 2-甲氧基吡啶基-3-硼酸 --> 2-羟基吡啶-N-氧化物

系列性分类


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