CAS 142-04-1 MFCD00012958-Aniline Hydrochloride 苯胺盐酸盐 TAO{mole}

Aniline Hydrochloride 苯胺盐酸盐

CAS 142-04-1 MFCD00012958

化学结构图

SMILES: Cl.NC1CCCCC1

化学属性

Mol. Formula	C6H8ClN
Mol. Weight	130
Vapor Density	4.46 (vs air)
Melting Point	196-198 °C(lit.)
Density	1.2215
Flash Point	193°(379°F)
TSCA	Yes
Boiling Point	245°C
Solubility	Soluble in alcohol
Stability	对湿度、光线敏感
Redox	Reduction

别名和识别编码

Chemical Name	Aniline Hydrochloride
Synonym	AnilineHydrochlorideForSynthesis phenylaminehydrochloride 苯胺,盐酸盐 nci-c03736hydrochloride Aniline chloride Benzenamine, hydrochloride Benzolamin Hydrochlorid 苯胺盐酸盐 chlorhydrated’aniline 阿尼林盐;苯胺盐酸盐 ANILINE HYDROCHLORIDE, FOR SUGAR ANALYSIS Aniliniumchlorid USAF EK-442 羟基苯胺 Benzenamine hydrochloride; C.I. 76001 Anilinechlofide Phenylaminhydrochlorid ANILINE HCL anilinechloride 盐酸苯胺 benzenamine hydrochloride Aniline salt Sul anilinova 苯胺盐酸盐 sulanilinova ANILINE HYDROCHLORIDE Chlorid anilinu Aniline HCl 苯胺鹽酸鹽 Aniline, hydrochloride chloridanilinu aniline chydrochloride ANILINE CHLORHYDRATE 阿尼林盐 ''aniline Salt'' usafek-442 NCI-C03736 Aniline hydrochloride, pure, 99% Anilinhydrochlorid Hydrochloride benzenamide 阿尼林盐,苯胺盐酸盐 NCI-C03736 hydrochloride ANILINE HYDROCHLORIDE FOR SUGAR & 羟基氯苯胺 C.I. 76001 苯胺鹽酸 phenylammoniumchloride Aniline hydrochloride Phenylammonium chloride Phenylamine hydrochloride Chlorhydrate d'aniline ANILINIUM CHLORIDE Usaf ek-442 Anilinium chloride Anilin Hydrochlorid
CAS Number	142-04-1
MDL Number	MFCD00012958
PubChem Substance ID	24846637
EC Number	205-519-8
Beilstein Registry Number	3593823
Merck Number	14,659
Chemical Name Translation	苯胺盐酸盐
Wiswesser Line Notation	ZR &GH
LabNetwork Molecule ID	LN00197472

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产品应用

糠醛的检定, 氧化剂的比色测定, 有机合成, 用于蔗糖分析。

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H317 May cause an allergic skin reaction 可能导致皮肤过敏
H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
H351 Suspected of causing cancer 怀疑致癌
H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
H318 Causes serious eye damage 严重伤害眼睛
H301+H311+H331
H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
H331 Toxic if inhaled 吸入中毒
H311 Toxic in contact with skin 皮肤接触中毒
H301 Toxic if swallowed 吞食有毒

Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

RTECSCY0875000

Precautionary statements

P305+P351+P338+P310
P302+P352+P312
P304+P340+P312
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P273 Avoid release to the environment. 避免释放到环境中。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P301+P310
P305+P351+P338
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。

Signal word Danger

Safety Statements

S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S63

Packing GroupIII

UN Number 1548 UN 1548 6.1/PG 3 UN1548

Risk Statements

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
R50 Very toxic to aquatic organisms 对水生生物极毒
R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
R48/23/24/25
R38 Irritating to skin 刺激皮肤

Storage condition Light Sensitive & Hygroscopic 充氩保存密封避光保存。 Hygroscopic

Hazard Codes T,N T;N

Hazard Class6.1

Warnings 危化品目录(2015)

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 130 gm/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Vascular - tumors
   Blood - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Vol

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 137 gm/kg/60W-C
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Liver - tumors
   Blood - tumors
REFERENCE :
   IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals
   to Man.  (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210)
   V.1-    1972-  Volume(issue)/page/year: 27,39,1982

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 238 gm/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Vascular - tumors
   Blood - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-130,1978

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4326 gm/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Blood - tumors
REFERENCE :
   IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals
   to Man.  (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210)
   V.1-    1972-  Volume(issue)/page/year: 27,39,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 460 mg/kg
TOXIC EFFECTS :
   Blood - methemoglobinemia-carboxyhemoglobin
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 80,31,1944

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 841 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB214-270

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 840 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   42,417,1977

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Fibroblast
DOSE/DURATION           : 10 umol/L
REFERENCE :
   JNCIAM Journal of the National Cancer Institute.  (Washington, DC)  V.1-60,
   1940-78.  For publisher information, see JJIND8.  Volume(issue)/page/year:
   58,1635,1977

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - rat Embryo
DOSE/DURATION           : 79500 ng/plate
REFERENCE :
   JJATDK JAT, Journal of Applied Toxicology.  (John Wiley & Sons Ltd., Baffins
   Lane, Chichester, W. Sussex PO19 1UD, UK)  V.1-    1981-
   Volume(issue)/page/year: 1,190,1981

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 50 umol/L
REFERENCE :
   BLFSBY Basic Life Sciences.  (Plenum Pub. Corp., 223 Spring St., New York,
   NY 10003)  V.1-    1973-  Volume(issue)/page/year: 29B,561,1984

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 1 gm/kg
REFERENCE :
   CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House,
   Southfield Road, Eynsham, Oxford OX8 1JJ, UK)  V.1-    1980-
   Volume(issue)/page/year: 12,1057,1991

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1400 mg/kg
SEX/DURATION            : female 7-20 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - blood and lymphatic
   systems (including spleen and marrow)
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   77,465,1985

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 780 mg/kg
SEX/DURATION            : female 19-21 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Maternal Effects - other effects
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 52,14B,1995

Restrict 危险品

其他信息

毒性分级:中毒
刺激数据:皮肤-兔子 500 毫克/24小时中度; 眼睛-兔子 20 毫克/24小时中度
盐酸苯胺价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80009917 苯胺盐酸盐;阿尼林盐;盐酸苯胺 250g 23.8元 2011/08/23 80009927 苯胺盐酸盐;阿尼林盐;盐酸苯胺 250g 19.9元 2010/05/25 A13024 苯胺.盐酸盐, 99% Aniline hydrochloride, 99% 500g 724元
MSDS 信息:盐酸苯胺(142-04-1).msds
爆炸物危险特性:在240℃, 7.6 巴时与苯厂反应爆炸; 与氧化剂反应强烈
F:3-9
类别:有毒物品
图谱信息:盐酸苯胺(142-04-1)红外图谱(IR1) 盐酸苯胺(142-04-1)红外图谱(IR2)
Alfa Aesar:苯胺.盐酸盐,99% Aniline hydrochloride, 99%(142-04-1)
海关编码:29214100
灭火剂:二氧化碳、砂土、干粉
急性毒性:口服-大鼠 LD50: 840 毫克/公斤; 口服-小鼠 LD50: 841 毫克/公斤
Sigma Aldrich:142-04-1(sigmaaldrich)
敏感性:Hygroscopic
The acute toxicity of aniline involves its activation in vivo to 4-hydroxyaniline and the formation of adducts with hemoglobin. In erythrocytes, this is associated with the release of iron and accumulation of methemoglobin as well as the development of hemolytic anemia and inflammation of the spleen. Tumor formation is often observed in the spleen on prolonged administration.
可燃性危险特性:明火, 受热较易燃; 燃烧或遇碱分解放出有毒苯胺和氯化物气体
上游原料:盐酸 --> 氨基苯
储运特性:库房通风低温干燥; 与食品原料和氧化剂分开储运
下游产品:磺胺 --> 碘苯 --> 4-癸基苯胺
用途二:糠醛的检定, 氧化剂的比色测定, 有机合成, 苯胺黑的制造,制造中间体和其它染料。
用途一:用作检定糠醛和比色测定氧化物的试剂，也用于有机合成
MOL 文件:142-04-1.mol
微有吸湿性, 见光及遇空气，在空气中可升华；逐渐被氧化面呈浅黄或浅灰色，溶于水和乙醇，溶于乙醚和氯仿。有毒。
蒸气密度:4.46 (vs air)
外观性质:片状结晶。