2,4,6-Collidine 2,4,6-三甲基吡啶
CAS 108-75-8 MFCD00006338
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- {SNA} Building Blocks, C8, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines
- Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, Fixation Reagents, Fixatives, Hematology and Histology, Microscopy Reagents, Puriss p.a.,
产品应用
- 无水碘化锂裂解位阻酯的有效溶剂。
- 用作电子显微镜的组织固定剂。
相关文献及参考
- Hindered base. For use in the dehydrochlorination of ɑ-chloroketones to enones, see: Org. Synth. Coll., 4, 162 (1963). For use in combination with Trifluoromethanesulfonic anhydride, A11767 for the generation of ketenimines from olefins, see N,N-Dimethylacetamide, A10924.
- Merck:14,9718 Beilstein:20,250
- Short: II/27B
- Solvent for various O-alkyl cleavage reaction by LiI, including hindered esters: J. Org. Chem., 28, 2184 (1963), and methyl ethers of phenols: Chem. Commun., 616 (1969).
- Merck 14 ,9718
- Merck:14,9718
- Superior base for peptide coupling reactions, causing less racemization than the more commonly used N-ethyldiisopropylamine or N-methylmorpholine: J. Org. Chem., 59, 695 (1994). For comparison with other hindered bases, see: J. Org. Chem., 61, 2460 (1996). For peptide reagents, see Appendix 6.
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H311 Toxic in contact with skin 皮肤接触中毒
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H319 Causes serious eye irritation 严重刺激眼睛
- H302+H332
- H226 Flammable liquid and vapour 易燃液体和蒸气
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241+P242+P243
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312+P330
- P302+
- P302+P352+P312+P361+P364
- P303+P361+P353
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P332+P313
- P337+P313
- P370+P378
- P403+P235
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R10 Flammable 易燃
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
TYPE OF TEST : LCLo - Lowest published lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 2500 ppm/2H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,847,1986
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - guinea pig DOSE/DURATION : 1 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,847,1986
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 400 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,847,1986
其他信息
- 2,4,6-三甲基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K2769201 2.4.6-三甲基吡啶 100ml 740元 2011/04/16 T0716 2,4,6-三甲基吡啶 2,4,6-Trimethylpyridine 25ML 175元 2011/04/16 T0716 2,4,6-三甲基吡啶 2,4,6-Trimethylpyridine 500ML 1210元
- 用途一:用于有机合成
- 用途三:主要用于制造口服避孕药(甲地孕酮),维生素A、维生素D3,氢化可的松及染料和植物生长激素等。
- MOL 文件:108-75-8.mol
- 具有弱碱性,微溶于水,溶于醇或醚。
- Sigma Aldrich:108-75-8(sigmaaldrich)
- 用途二:用作色谱分析标准物质,也用作溶剂,有机合成。
- 上游原料:硫酸 --> 丙酮 --> 氨 --> 苯 --> 尿素 --> 氯化锌 --> 五氧化二磷
- TCI Shanghai:2,4,6-三甲基吡啶 2,4,6-Trimethylpyridine,>;98.0%(GC)(108-75-8)
- 外观性质:无色液体。
- Acros Organics:2,4,6-三甲基吡啶 2,4,6-Collidine, 99%(108-75-8)
- 图谱信息:2,4,6-三甲基吡啶(108-75-8)红外图谱(IR1) 2,4,6-三甲基吡啶(108-75-8)核磁图( 13 CNMR) 2,4,6-三甲基吡啶(108-75-8)质谱(MS) 2,4,6-三甲基吡啶(108-75-8)核磁图( 1 HNMR) 2,4,6-三甲基吡啶(108-75-8)红外图谱(IR2)
- 下游产品:雌酚酮 --> 2-环戊烯酮
- 检测方法:GC,NMR
- Alfa Aesar:2,4,6-三甲基吡啶,99% 2,4,6-Collidine, 99%(108-75-8)
- MSDS 信息:2,4,6-三甲基吡啶(108-75-8).msds
- 海关编码:29333999
- 敏感性:Hygroscopic