1-Bromo-3-Fluorobenzene 间溴氟苯

CAS 1073-06-9 MFCD00000326

化学结构图

1073-06-9
SMILES: Fc1cccc(Br)c1

化学属性

Mol. FormulaC6H4BrF
Mol. Weight175.00
Density1.567
Refractive index1.5250 to 1.5290
Boiling Point149-151°C at 760 mmHg
Flash Point46°C
TSCAYes
Melting Point-8 °C
Solubility不溶
Appearance 无色透明液体。熔点148-150℃,沸点:149℃-151℃。闪点:38℃,比重: 1.567,折光率:1.5260。
Stability对光线敏感
pH:A

别名和识别编码

Chemical Name1-Bromo-3-Fluorobenzene
Synonym 3-Bromofluorobenzene {LY} 3-Bromofluorobenzene {} {LY} 3-Bromofluorobenzene {} {} {LY} 3-Bromofluorobenzene {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromofluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromofluo
MDL NumberMFCD00000326
CAS Number1073-06-9
EC Number214-023-0
Beilstein Registry Number1853969
PubChem Substance ID14082
Reaxys-RN1853969
Chemical Name Translation间溴氟苯
InChIKeyQDFKKJYEIFBEFC-UHFFFAOYSA-N
Wiswesser Line NotationFR CE
LabNetwork Molecule IDLN00195149
InChIInChI=1S/C6H4BrF/c7-5-2-1-3-6(8)4-5/h1-4H
Canonical SMILESFC1=CC(Br)=CC=C1
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Aryl, Aryl Fluorinated Building Blocks, Building Blocks, C6, Chemical Synthesis, Fluorinated Building Blocks, Halogenated Hydrocarbons, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

产品应用

  • 医药、农药、液晶材料中间体。

相关文献及参考

  • Short: III/35D2
  • Short: III/20b
  • Lithiation with Li 2,2,6,6-tetramethylpiperidide (LTMP) at -75o occurs at the 2-position. The yield of 2-bromo-6-fluorobenzoic acid obtained after carboxylation can be increased to 93% by the use of a base consisting of a 9:1 mixture of LTMP and LDA: Tetrahedron Lett., 37, 6551 (1996).
  • Beilstein: 5,IV,678

安全信息

Signal word Warning
GHS Symbol
WGK Germany2
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Risk Statements
  • R10 Flammable 易燃
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P303+P361+P353
  • P305+P351+P338
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSDA1225000
Packing GroupIII
UN Number 1993
Hazard Codes 3 Xn,F,Xi
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard Class3

其他信息

  • 间溴氟苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010063 间溴氟苯 100g 940元 2011/04/16 B0882 3-溴氟苯 3-Bromofluorobenzene 250G 2440元 2011/04/16 B0882 3-溴氟苯 3-Bromofluorobenzene 25G 480元
  • Hazard Note:Flammable/Irritant
  • 用途一:用作医药、农药中间体
  • TCI Shanghai:1-氟-3-溴苯 3-Bromofluorobenzene,>;98.0%(GC)(1073-06-9)
  • MOL 文件:1073-06-9.mol
  • 不溶于水,和大多数有机溶剂混溶。
  • 下游产品:2,6-二甲基苯甲醛 --> 2-溴-6-氟苯甲酸
  • 检测方法:HPLC
  • 海关编码:29036990
  • Sigma Aldrich:1073-06-9(sigmaaldrich)
  • Acros Organics:3-溴氟苯 3-Bromofluorobenzene, 99%(1073-06-9)
  • MSDS 信息:1-Bromo-3-fluorobenzene(1073-06-9).msds
  • Alfa Aesar:1-溴-3-氟苯,99% 1-Bromo-3-fluorobenzene, 99%(1073-06-9)
  • 图谱信息:间溴氟苯(1073-06-9)质谱(MS) 间溴氟苯(1073-06-9)核磁图( 1 HNMR) 间溴氟苯(1073-06-9)红外图谱(IR1)
  • 用途二:医药、农药、液晶材料中间体。

系列性分类