1-Bromo-2-fluorobenzene 邻氟溴苯
CAS 1072-85-1 MFCD00000282
信息真实价格透明
资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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现货库存
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分类
- {SNA} Aryl, Aryl Fluorinated Building Blocks, Building Blocks, C6, Chemical Synthesis, Fluorinated Building Blocks, Halogenated Hydrocarbons, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
产品应用
- 医药、农药、液晶材料中间体。
相关文献及参考
- On treatment with Mg: J. Org. Chem., 49, 4518 (1984), or n-BuLi: Tetrahedron, 48, 4379 (1992), benzyne is generated, which undergoes [4+2] cycloadditions with furans or pyrroles.
- Short: III/35D2
- Short: III/38B
- Whereas n-BuLi effects bromine-metal exchange, lithiation with LDA at -75o results in deprotonation ortho to F; subsequent reaction with electrophiles provides access to mixed dihalo derivatives such as 3-bromo-2-fluorobenzoic acid: Tetrahedron Lett., 36, 881 (1995). Improved yields are obtained by the use of lithium 2,2,6,6-tetramethylpiperidide (LTMP) as base: Tetrahedron Lett., 37, 6551 (1996).
- Beilstein: 5,IV,678
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- R10 Flammable 易燃
- R22 Harmful if swallowed 吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312+P330
- P303+P361+P353
- P305+P351+P338
- P332+P313
- P337+P313
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
其他信息
- MSDS 信息:1-Bromo-2-fluorobenzene(1072-85-1).msds
- TCI Shanghai:1-氟-2-溴苯 2-Bromofluorobenzene,>;99.0%(GC)(1072-85-1)
- MOL 文件:1072-85-1.mol
- 用途一:用作医药、农药中间体
- TSCA:T
- 下游产品:1,4-环氧-1,4-二氢萘
- Alfa Aesar:1-溴-2-氟苯,98% 1-Bromo-2-fluorobenzene, 99%(1072-85-1)
- 图谱信息:邻溴氟苯(1072-85-1)质谱(MS) 邻溴氟苯(1072-85-1)红外图谱(IR1) 邻溴氟苯(1072-85-1)核磁图( 13 CNMR) 邻溴氟苯(1072-85-1)核磁图( 1 HNMR)
- 海关编码:29036990
- 邻溴氟苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010066 邻氟溴苯 100g 880元 2011/04/16 B0883 2-溴氟苯 2-Bromofluorobenzene 500G 4900元 2011/04/16 B0883 2-溴氟苯 2-Bromofluorobenzene 25G 460元
- Acros Organics:2-Bromofluorobenzene, 99%(1072-85-1)
- Hazard Note:Flammable/Irritant
- Sigma Aldrich:1072-85-1(sigmaaldrich)
- 用途二:医药、农药、液晶材料中间体。