(R)-Ru(OAc)2(DM-SEGPHOS®)
CAS N/A MFCD09753025
化学结构图
SMILES: CC(=O)O[Ru]OC(C)=O.CC1=CC(C)=CC(=C1)P(C1C=CC2OCOC=2C=1C1C2OCOC=2C=CC=1P(C1=CC(C)=CC(C)=C1)C1=CC(C)=CC(C)=C1)C1=CC(C)=CC(C)=C1
化学属性
| Mol. Formula | C50H50O8P2Ru |
|---|---|
| Mol. Weight | 941.94 |
别名和识别编码
| Chemical Name | (R)-Ru(OAc)2(DM-SEGPHOS®) |
|---|---|
| Synonym | 二乙酸根[(R)-5,5′-双[二(3,5-二甲苯基)膦基]-4,4′-二-1,3-苯并二噁茂]钌(II) (S)-Ru(OAc)2(DM-SEGPHOS®) |
| MDL Number | MFCD09753025 |
| CAS Number | 944450-50-4 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, SEGPHOS
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, SEGPHOS
相关文献及参考
- Steinhuebel, D.; et al., Direct Asymmetric Reductive Amination J. Am. Chem. Soc. 131 , 11316-11317, (2009)
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
