Hydroxy[-(S)-BINAP]-rhodium(I) Dimer 羟基[-(S)-BINAP]-铑(I) 二聚体

CAS N/A MFCD08561132

化学结构图

N/A
SMILES: O[Rh].O[Rh].C1=CC(=C(C2C(=CC=C3C=CC=CC3=2)P(C2C=CC=CC=2)C2C=CC=CC=2)C2C=CC=CC=21)P(C1C=CC=CC=1)C1C=CC=CC=1.C1=CC(=C(C2C(=CC=C3C=CC=CC3=2)P(C2C=CC=CC=2)C2C=CC=CC=2)C2C=CC=CC=21)P(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC88H66O2P4Rh2
Mol. Weight1485.17

别名和识别编码

Chemical NameHydroxy[-(S)-BINAP]-rhodium(I) Dimer
MDL NumberMFCD08561132
PubChem Substance ID24884495
Synonym 羟基[-(S)-BINAP]-铑(I) 二聚体
Chemical Name Translation羟基[-(S)-BINAP]-铑(I) 二聚体
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分类

  • {SNA} Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Conjugate Addition, Privileged Ligands and Complexes
  • Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Conjugate Addition, Privileged Ligands and Complexes

相关文献及参考

  • 1. Angew. Chem. Int. Ed. Engl. 44 , 4224, (2005) 摘要
  • 2. Chem. Rev. 103 , 2829, (2003) 摘要

安全信息

WGK Germany3
Hazard Codes Xn Xi
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
GHS Symbol
Precautionary statements
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
Signal word Warning
Hazard statements
  • H351 Suspected of causing cancer 怀疑致癌

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BINAPs - Privileged Ligands and Complexes

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