(3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN (1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE
CAS N/A MFCD07782007
化学结构图
SMILES: [Rh+].CC(C)(C)P1CC2C=CC3C=CC=CC=3C=2C2C3C=CC=CC=3C=CC=2[C@H]1[C@@H]1C2C=CC3C=CC=CC=3C=2C2C3C=CC=CC=3C=CC=2CP1C(C)(C)C.F[B-](F)(F)F.C1CC=CCCC=C1
化学属性
| Mol. Formula | C52H48P2.C8H12.BF4.Rh |
|---|---|
| Mol. Weight | 1032.78 |
| Melting Point | >;300 °C |
别名和识别编码
| Chemical Name | (3S,3'S,4S,4'S,11BS,11'BS)-(+)-4,4'-DI-T-BUTYL-4,4',5,5'-TETRAHYDRO-3,3'-BI-3H-DINAPHTHO[2,1-C:1',2'-E]PHOSPHEPIN (1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE |
|---|---|
| Synonym | [(S)-二叔丁基四氢联二萘磷(环辛二烯)铑(I)]四氟硼酸盐 |
| MDL Number | MFCD07782007 |
| PubChem Substance ID | 24884435 |
| CAS Number | 1046806-02-3 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Quest Ligands and Complexes, Privileged Ligands and Complexes
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Quest Ligands and Complexes, Privileged Ligands and Complexes
相关文献及参考
- 1. Tang, W. et al Angew. Chem. Int. Ed. Engl. 42 , 3509, (2003)
