Lithium thioethoxide 硫代乙氧基锂

CAS 30383-01-8 MFCD16621449

化学结构图

30383-01-8
SMILES:

化学属性

Mol. Weight68.07
Melting Point316-333 °C
Mol. FormulaC2H5LiS

别名和识别编码

Synonym Lithium ethylmercaptide Lithium ethanethiolate Lithium ethyl sulfide Lithium ethyl thiolate Lithium ethylmercaptide 硫代乙氧基锂 Lithium ethyl thiolate Lithium ethanethiolate Lithium ethyl sulfide
MDL NumberMFCD16621449
CAS Number30383-01-8
Chemical NameLithium thioethoxide
Chemical Name Translation硫代乙氧基锂
PubChem Substance ID329763541
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分类

  • {SA} Chemical Synthesis, Deprotecting Reagents, Others, Protection and Derivatization, Synthetic Reagents
  • {SNA} Chemical Synthesis, Deprotecting Reagents, Other Deprotecting Reagents, Protection and Derivatization, Synthetic Reagents

相关文献及参考

  • 1. Cvengros, J.; et al. Synlett , 1993, (2008)
  • 2. Chen, Y.; et al. Organometallics 27 , 666, (2008)
  • 3. Arnold, M. A.; et al. J. Am. Chem. Soc. 128 , 13255, (2006)

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Danger
Hazard statements
  • H228 Flammable solid 易燃固体
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Hazard Codes F,C
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Deprotecting Reagents - Protection and Derivatization
  5. Others - Deprotecting Reagents

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