[Bis{((R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)palladium(II)}bis(μ-hydroxo)] bis(triflate) [双{((S)-(-)-2,2′-双(二苯基膦基)-1,1′-联萘)钯(II)}双(μ-氢氧基)] 双(三氟甲磺酸酯)

CAS N/A MFCD15144770

化学结构图

N/A
SMILES:

化学属性

Mol. Weight1790.34
Melting Point201-211 °C
Mol. FormulaC90H66F6O8P4Pd2S2

别名和识别编码

MDL NumberMFCD15144770
Chemical Name[Bis{((S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)palladium(II)}bis(μ-hydroxo)] bis(triflate)
Synonym [双{((S)-(-)-2,2′-双(二苯基膦基)-1,1′-联萘)钯(II)}双(μ-氢氧基)] 双(三氟甲磺酸酯) [双{((R)-(+)-2,2′-双(二苯基膦基)-1,1′-联萘)钯(II)}双(μ-氢氧基)]双(三氟甲磺酸酯)
Chemical Name Translation[双{((S)-(-)-2,2′-双(二苯基膦基)-1,1′-联萘)钯(II)}双(μ-氢氧基)] 双(三氟甲磺酸酯)
PubChem Substance ID329762586
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分类

  • {SNA} Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Hazard Codes Xn Xi
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害

系列性分类


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