(1-Cyano-2-Ethoxy-2-Oxoethylidenaminooxy)Dimethylamino-Morpholino-Carbenium Hexafluorophosphate (2-肟基-氰基乙酸乙酯)-N,N-二甲基-吗啉基脲六氟磷酸酯
CAS 1075198-30-9 MFCD11975052
化学结构图
SMILES: CCOC(=O)/C(/C#N)=N\OC(N1CCOCC1)=[N+](C)C.F[P-](F)(F)(F)(F)F
化学属性
| Mol. Formula | C12H19F6N4O4P |
|---|---|
| Mol. Weight | 428.27 |
| Melting Point | 151.4 -152.9 |
| TSCA | No |
别名和识别编码
| Chemical Name | (1-Cyano-2-Ethoxy-2-Oxoethylidenaminooxy)Dimethylamino-Morpholino-Carbenium Hexafluorophosphate |
|---|---|
| Synonym | (1-Cyano-2-ethoxy-2-oxoethylidenaminooxy)dimethylamino-morpholino-carbenium hexafluorophosphate (1-氰基-2-乙氧基-2-氧亚乙基氨基氧)二甲氨基-吗啉基-碳鎓六氟磷酸盐 COMU COMU® |
| MDL Number | MFCD11975052 |
| CAS Number | 1075198-30-9 |
| Chemical Name Translation | (2-肟基-氰基乙酸乙酯)-N,N-二甲基-吗啉基脲六氟磷酸酯 |
| Beilstein Registry Number | 19762713 |
| PubChem Substance ID | 329763117 |
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分类
- {SNA} 12 Principles Aligned Products, Chemical Biology, Chemical Synthesis, Coupling, Greener Alternative Products, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents
- {SNA} Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents
相关文献及参考
- 1. El-Faham, A.; et al., COMU: A Safer and More Effective Replacement for Benzotriazole-Based Uronium Coupling Reagents Chem. Eur. J. 15 , 9404, (2009)
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312
- P302+P352
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
