(1S,1’S,2R,2’R)-2,2’-Di-Tert-Butyl-2,2’,3,3’-Tetrahydro-1H,1’H-1,1’-Biisophosphindole (1S,1′S,2R,2′R)-2,2′-二叔丁基-2,3,2′,3′-四氢-1H,1′H(1,1′)二异磷哚
CAS 795290-34-5 MFCD11045432
化学结构图
SMILES: CC(C)(C)[P@@]1CC2C=CC=CC=2[C@H]1[C@@H]1C2C=CC=CC=2C[P@]1C(C)(C)C
化学属性
| Mol. Formula | C24H32P2 |
|---|---|
| Mol. Weight | 382.46 |
| Melting Point | 215-226 °C |
别名和识别编码
| Chemical Name | (1S,1’S,2R,2’R)-2,2’-Di-Tert-Butyl-2,2’,3,3’-Tetrahydro-1H,1’H-1,1’-Biisophosphindole |
|---|---|
| Synonym | (1S,1′S,2R,2′R)-DuanPhos (1S,1′S,2R,2′R)-2,2′-二叔丁基-2,3,2′,3′-四氢-1H,1′H(1,1′)二异磷哚 |
| CAS Number | 795290-34-5 |
| Chemical Name Translation | (1S,1′S,2R,2′R)-2,2′-二叔丁基-2,3,2′,3′-四氢-1H,1′H(1,1′)二异磷哚 |
| MDL Number | MFCD11045432 |
| PubChem Substance ID | 329761857 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Quest Ligands and Complexes, Privileged Ligands and Complexes
相关文献及参考
- 1. Phan, D. H. T.; et al., Phthalides by Rhodium-Catalyzed Ketone Hydroacylation J. Am. Chem. Soc. 131 , 15608-15609, (2009)
- 2. Zigterman, J. L.; et al., Highly Selective Rhodium-Catalyzed Conjugate Addition Reactions of 4-Oxobutenamides J. Org. Chem. 72 , 8870-8876, (2007)
- Badland, M.; et al., An enantioselective synthesis of (R)- and (S)-3-amino-7-methyl-3,4-dihydro-1H-[1,8]naphthyridin-2-one Tetrahedron Asymmetry 22 , 1328-1331, (2011)
