(11bS,11'bS)-4,4'-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (11bS,11′bS)-4,4′-(9,9-二甲基-9H-氧杂蒽-4,5-二基)双-二萘并[2,1-d:1′,2′-f][1,3,2]二噁磷杂庚英
CAS 349114-57-4 MFCD09842740
化学结构图
SMILES: CC1(C)C2C=CC=C(C=2OC2C(=CC=CC1=2)P1OC2C=CC3C=CC=CC=3C=2C2C3C=CC=CC=3C=CC=2O1)P1OC2C=CC3C=CC=CC=3C=2C2C3C=CC=CC=3C=CC=2O1
化学属性
| Mol. Formula | C55H36O5P2 |
|---|---|
| Mol. Weight | 838.82 |
| Melting Point | 195-207 °C (dec.) |
别名和识别编码
| Chemical Name | (11bS,11'bS)-4,4'-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin |
|---|---|
| Synonym | (11bS,11′bS)-4,4′-(9,9-二甲基-9H-氧杂蒽-4,5-二基)双-二萘并[2,1-d:1′,2′-f][1,3,2]二噁磷杂庚英 S,S-Reetz X-二亚磷酸酯 |
| MDL Number | MFCD09842740 |
| CAS Number | 349114-57-4 |
| Chemical Name Translation | (11bS,11′bS)-4,4′-(9,9-二甲基-9H-氧杂蒽-4,5-二基)双-二萘并[2,1-d:1′,2′-f][1,3,2]二噁磷杂庚英 |
| PubChem Substance ID | 329760513 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydrogenation, Privileged Ligands and Complexes, Reetz Ligands
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydrogenation, Privileged Ligands and Complexes, Reetz Ligands
相关文献及参考
- 1. Reetz, M. T.; Li, X., Asymmetric hydrogenation of quinolines catalyzed by iridium complexes of BINOL-derived diphosphonites Chem. Commun. , 2159-2160, (2006)
- 2. Goertz, W.; et al., Asymmetric nickel-catalyzed hydrocyanation of vinylarenes by applying homochiral xantphos ligands Chem. Eur. J. 7 , 1614-1618, (2001)
- 3. Reetz, M. T.; Li, X. J. Am. Chem. Soc. 128 , 1044, (2006) 摘要
